The compound that exhibits weaker intermolecular forces has to be given. Concept introduction: London Dispersion forces: London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds. Hydrogen Bonding: A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule. Dipole-dipole interactions: Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

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Answer 1

Question

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

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Which of these compounds have the higher boiling point? Why? a) top two compounds b) bottom two compounds

Which has a higher boiling point? Explain using london dispersion forces, dipole dipole, or hydrogen bonding. (a) CH3CH3 or CH3CH2OH (b) CH3CH2CH2CH2CH2CH2CH3 or (CH3)3C-CH(CH3)2

Based on the following data below, what type of intermolecular forces exist for Methyl-benzene, 2-Acetyltoluene, and 4-Acetyltoluene? In which are intermolecular forces strongest? Why? The boiling point of Methyl-benzene is 110°C. The boiling point of 2-Acetyltoluene is 214°C. The boiling point of 4-Acetyltoluene is 226°C.

Answer 2

Question

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

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Answer 3

Question

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

Expert Solution & Answer

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Answer 4

Question

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

Expert Solution & Answer

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Answer 5

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

Answer 6

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

Answer 7

Chapter 4, Problem 4.59AP

(a)

Interpretation Introduction

Interpretation:

The compound that exhibits weaker intermolecular forces has to be given.

Concept introduction:

London Dispersion forces:

London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule. All covalent compound exhibits London dispersion forces. These intermolecular forces are the only intermolecular forces present in nonpolar compounds.

Hydrogen Bonding:

A chemical bond in which a hydrogen atom of one molecule is attracted to an electronegative atom especially a nitrogen, oxygen, or fluorine atom, usually of another molecule.

Dipole-dipole interactions:

Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles. This interaction is stronger than the London forces but is weaker than ion-ion interaction because only partial charges are involved positive end of a polar molecule will attract the negative end of the other molecule and influence its position

Answer 8

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The compound, which has higher boiling point, has to be given.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The compound, which has higher melting point, has to be given.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4.1 - Prob. 4.1P Ch. 4.1 - Prob. 4.2P Ch. 4.1 - Prob. 4.3P Ch. 4.1 - Prob. 4.4P Ch. 4.2 - Prob. 4.5P Ch. 4.2 - Prob. 4.6P Ch. 4.3 - Prob. 4.7P Ch. 4.3 - Prob. 4.8P Ch. 4.3 - Prob. 4.9P Ch. 4.3 - Prob. 4.10P

Solution Summary: The author explains that London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule.

Interpretation:

The compound, which has higher boiling point, has to be given.

Interpretation:

The compound, which has higher melting point, has to be given.

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Chapter 4 Solutions

Solution Summary: The author explains that London dispersion forces are weak interactions due to the temporary changes in electron density in a molecule.

Interpretation: The compound, which has higher boiling point, has to be given.

Interpretation: The compound, which has higher melting point, has to be given.

Want to see the full answer?

Chapter 4 Solutions

Interpretation:

The compound, which has higher boiling point, has to be given.

Interpretation:

The compound, which has higher melting point, has to be given.