Organic Chemistry
11th Edition
ISBN: 9781118147399
Author: Solomons, T. W.
Publisher: John Wiley & Sons Inc
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Chapter 4, Problem 4LGP
Interpretation Introduction
Interpretation:
The type of stereoisomer of the product formed and the mode of addition of chlorine to the double bond, when
Concept introduction:
The compounds having the same molecular formula but different spatial arrangements are known as stereoisomers.
Syn addition is the reaction in which two substituents groups are added to the same side of the double bond.
Anti-addition is the reaction in which two substituents groups are added to the opposite side of the double bond.
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TRUE OR FALSE
(a) Both ethylene and acetylene are planar molecules.
(b) An alkene in which each carbon of the double bond has two different groups bonded to it will show cis-trans isomerism.
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(d) Cis-2-butene and trans -2-butene can be interconverted by rotation about the carbon–carbon double bond.
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(f) Both 2-hexene and 3-hexene can exist as pairs of cis-trans isomers.
(g) Cyclohexene can exist as a pair of cis-trans isomers.
(h) 1-Chloropropene can exist as a pair of cis-trans isomers.
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Chapter 4 Solutions
Organic Chemistry
Ch. 4 - Prob. 1PPCh. 4 - Which structure does not represent...Ch. 4 - Prob. 3PPCh. 4 - Draw bond-line formulas for all of the isomers of...Ch. 4 - Prob. 5PPCh. 4 - Draw bond-line formulas and give IUPAC...Ch. 4 - Draw bond-line formulas and give IUPAC...Ch. 4 - Practice Problem 4.8 Give names for the following...Ch. 4 - Prob. 9PPCh. 4 - Prob. 10PP
Ch. 4 - Prob. 11PPCh. 4 - Give the structures and IUPAC names for all the...Ch. 4 - Prob. 13PPCh. 4 - Practice Problem 4.14 Show by a calculation (using...Ch. 4 - Practice Problem 4.15 Write structures for the cis...Ch. 4 - Practice Problem 4.16
(a) Write structural...Ch. 4 - Practice Problem 4.17 Write a conformational...Ch. 4 - Practice Problem 4.18
(a) Write the two...Ch. 4 - Prob. 19PPCh. 4 - Practice Problem 4.20 (a) What is the index of...Ch. 4 - Practice Problem 4.21
Zingiberene, a fragrant...Ch. 4 - Practice Problem 4.22 Carbonyl groups also count...Ch. 4 - Prob. 23PCh. 4 - Give systematic IUPAC names for each of the...Ch. 4 - Prob. 25PCh. 4 - Write the structure and give the IUPAC systema.tic...Ch. 4 - 4.27. Write the structure(s) of the simplest...Ch. 4 - Prob. 28PCh. 4 - 4.29. Write structures for the following...Ch. 4 - Prob. 30PCh. 4 - A spiro ring junction is one where two rings that...Ch. 4 - 4.32. Tell what is meant by a homologous series...Ch. 4 - Four different cycloalkenes will all yield...Ch. 4 - 4.34. (a) Three different alkenes yield...Ch. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - 4.37. Write the structures of two chair...Ch. 4 - Prob. 38PCh. 4 - Without referring to tables, decide which member...Ch. 4 - Prob. 40PCh. 4 - 4.41. Which compound would you expect to be the...Ch. 4 - Prob. 42PCh. 4 - 4.43. Write the two chair conformations of each of...Ch. 4 - Provide an explanation for the surprising fact...Ch. 4 - Prob. 45PCh. 4 - 4.46. Specify the missing compounds and/or...Ch. 4 - Consider the cis and trans isomers of...Ch. 4 - Prob. 48PCh. 4 - Open the energy-minimized 3D Molecular Models on...Ch. 4 - 4.50. Open the 3D Molecular Models on the book’s...Ch. 4 - 4.51. Open the 3D Molecular Model on the book’s...Ch. 4 - 1. The predominant conformation for D-glucose is...Ch. 4 - Prob. 2LGPCh. 4 - When 1,2-dimethylcyclohexene is allowed to react...Ch. 4 - Prob. 4LGPCh. 4 - Prob. 1QCh. 4 - Select the correct name of the compound whose...Ch. 4 - Select the correct name of the compound whose...Ch. 4 - Prob. 4QCh. 4 - 4.5 How many isomers are possible for C3H7Br?
(a)...Ch. 4 - 4.6 Which isomer of 1,3-dimethylcyclohexane is...Ch. 4 - 4.7. Which is the lowest energy conformation of...Ch. 4 - Supply the missing structuresCh. 4 - Supply the missing reagents in the box:Ch. 4 - The most stable conformation of...
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