Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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(a) Draw C in its more stable chair conformation. (b) Convert D to a hexagon with substituents on wedges and dashed wedges.
(a) Convert each chair cyclohexane to a hexagon with wedges and dashed wedges. (b) Draw a stereoisomer of each compound in its more stable chair conformation.
(a) Draw the most stable chair conformers of trans-1,3-diisopropylcyclohexane and trans-1,4-diisopropylcyclohexane.
(b) Which is more stable: trans-1,3-diisopropylcyclohexane or trans-1,4-diisopropylcyclohexane?
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- 3) Draw a cyclohexane chair with 3 substituents in the most stable conformation. Explain why the conformation you've chosen is the most stable.arrow_forwardProblem 4.30 (a) Draw C in its more stable chair conformation. (b) Convert D to a hexagon with substituents on wedges and dashed wedges. Н | CH3 CH3 CH2CH2CH3 нarrow_forward4. (a) Draw a skeletal (line-bond) structure for 3,4-dimethylhexane. (b) Draw a sawhorse representation of any staggered conformation of this molecule looking down the carbon-3 to carbon-4 bond. (c) Draw a Newman projection looking down the carbon-3 to carbon-4 bond of the same conformation that you drew as a sawhorse representation.arrow_forward
- 3)) Draw the most stable chair conformation of a 1,2,4-trimethylcyclohexane (Show all the hydrogens and indicate if the bond is axial or equatorial at the substitution).arrow_forwarddraw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexanearrow_forwardThere are three distinct chair conformations for cyclohexylcyclohexane. (a) Draw all three and (b) determine which one is the most stable. Cyclohexylcyclohexanearrow_forward
- Consider 1-bromopropane, CH3CH2CH2Br. (a) Draw a Newman projection for the conformation in which CH3 and -Br are anti (dihedral angle 180°). (b) Draw Newman projections for the conformations in which - CH3 and -Br are gauche (dihedral angles 60° and 300°). (c) Which of these is the lowest energy conformation? (d) Which of these conformations, if any, are related by reflection?arrow_forwardTake a look at the butane conformers below. Identify: (a)Which is an anti conformation in Newman? (b)Which is a Gauche conformation? (c)Which is the more stable Sawhorse conformer? (d)Which has the same potential energy/strain with ALS?arrow_forwardDraw each of the following. (a) Draw a Newman Projection of the following molecule, looking down the C3-C4 bond. Draw C3 in the front. CI Br H (b) Draw a Newman Projection of the most stable and the least stable conformation of the following molecule. Label each H H. CI H CI Harrow_forward
- (c)Conformational isomer is the different spatial arrangement of the atoms that resulted from rotation about a single bond. (i) Differentiate anti conformers and gauche conformers (ii) Using a newman projection, draw the anti conformer and gauche conformers of 3,3-dimethylheptane (viewed along the C3-C4 bond)arrow_forwardDraw the two chair conformations of the following substituted cyclohexanes. In each case, label the more stable conformation.(a) trans-1-ethyl-4-methylcyclohexanearrow_forwardDraw each compound in its most stable conformation(s). Then draw it in its most symmetric conformation, and determine whether it is chiral.(a) 2-methylbutanearrow_forward
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