CHEMISTRY VOL. 2 W/MASTERING CHEM. >IC<
19th Edition
ISBN: 9781323849996
Author: Brown
Publisher: Pearson Custom Publishing
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 5.2, Problem 5.1.2PE
Practice Exercise 2
Calculate the change in the internal energy for a process in which a system absorbs 140 J of heat from the surroundings and does 85 J of work on the surroundings.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Exercise 97 has a heat capacity of 6.66 KJ/ degree C.
Practice Exercise 1The coinage metals (Group 1B) copper, silver, and gold havespecific heats of 0.385, 0.233, and 0.129 J/g-K, respectively.Among this group, the specific heat capacity andthe molar heat capacity as the atomic weightincreases. (a) increases, increases (b) increases, decreases(c) decreases, increases (d) decreases, decreases
A calorimeter was filled with 50 g of water with an initial temperature of 10 °C then hot water weighing 100 g and a temperature of 99 °C was introduced. The system was allowed to reach equilibrium and the final temperature was 68 °C. What is the specific heat of the calorimeter in J/g °C? Report answer with three significant figures.
Chapter 5 Solutions
CHEMISTRY VOL. 2 W/MASTERING CHEM. >IC<
Ch. 5.2 - A mixture of gases A2 and B2 are introduced to a...Ch. 5.2 - Practice Exercise 2 Calculate the change in the...Ch. 5.3 - A solid sample of Zn(OH)2 is added to 0.350 L of...Ch. 5.3 -
Practice Exercise 2
Calculate the work, in J, if...Ch. 5.3 - Practice Exercise 1 A chemical reaction that gives...Ch. 5.3 - Prob. 5.3.2PECh. 5.4 - Prob. 5.4.1PECh. 5.4 - Prob. 5.4.2PECh. 5.5 - The coinage metals (Group 1B) copper, silver, and...Ch. 5.5 - Prob. 5.5.2PE
Ch. 5.5 - Practice Exercise 1 When 0.243 g of Mg metal is...Ch. 5.5 - Practical exercise 2 When 50.0 mL of 0.100MAgNO3...Ch. 5.5 - Prob. 5.7.1PECh. 5.5 - Practice Exercise 2 A 0.5865-g sample of lactic...Ch. 5.6 - Prob. 5.8.1PECh. 5.6 - Prob. 5.8.2PECh. 5.6 - Calculate H for the reaction C(s)+...Ch. 5.6 - Prob. 5.9.2PECh. 5.7 - Prob. 5.10.1PECh. 5.7 - Prob. 5.10.2PECh. 5.7 - Prob. 5.11.1PECh. 5.7 - Prob. 5.11.2PECh. 5.7 -
Practice Exercise 1
Given 2SO2(g) + 02(g) —>...Ch. 5.7 - Prob. 5.12.2PECh. 5.8 - Use the average bond enthalpies in Table 5.41to...Ch. 5.8 -
Use the average bond enthalpies in Table 5.4 to...Ch. 5.9 - Prob. 5.14.1PECh. 5.9 - Prob. 5.14.2PECh. 5 - One of the important ideas of thermodynamics is...Ch. 5 - Two positively charged spheres, each with a charge...Ch. 5 - SI The accompanying photo shows a pipevine...Ch. 5 - Consider the accompanying energy diagram. Does...Ch. 5 - The contents of the closed box in each of the...Ch. 5 - Imagine that you are climbing a mountain. Is the...Ch. 5 - The diagram shows four states of a system, each...Ch. 5 - You may have noticed that when you compress the...Ch. 5 - Imagine a container placed in a tub of water, as...Ch. 5 - In the accompanying cylinder diagram, a chemical...Ch. 5 - Prob. 10ECh. 5 - Consider the two diagrams that follow. Based on...Ch. 5 - Consider the conversion of compound A into...Ch. 5 - What is the electrostatic potential energy (in...Ch. 5 - What is the electrostatic potential energy (in...Ch. 5 - The electrostatic force (not energy) of attraction...Ch. 5 - Use the equations given in Problem 5.15 to...Ch. 5 - A sodium ion, Na+, with a charge of 1.6 x 10-19 C...Ch. 5 - A magnesium ion, Mg2+, with a charge of 3.2 x...Ch. 5 - Identify the force present and explain whether...Ch. 5 - Identify the force present and explain whether...Ch. 5 - Which of the following cannot leave or enter a...Ch. 5 - Prob. 22ECh. 5 - According to the first law of thermodynamics, what...Ch. 5 - Write an equation that expresses the first law of...Ch. 5 - Calculate AB and determine whether the process is...Ch. 5 - For the following processes, calculate the change...Ch. 5 - A gas is confined to a cylinder fitted with a...Ch. 5 - Consider a system consisting of two oppositely...Ch. 5 - What is meant by the term state function? Give an...Ch. 5 - Indicate which of the following is independent of...Ch. 5 - During a normal breath, our lungs expand about...Ch. 5 - How much work (in J) is involved in a chemical...Ch. 5 - Why is the change in enthalpy usually easier to...Ch. 5 - Under what condition will the enthalpy change of a...Ch. 5 - Assume that the following reaction occurs at...Ch. 5 - Suppose that the gas-phase reaction 2NO(g) + 02(g)...Ch. 5 - A gas is confined to a cylinder under constant...Ch. 5 - A gas is confined to a cylinder under constant...Ch. 5 - The complete combustion of ethanol, C2H5OH(l), to...Ch. 5 - The decomposition of Ca(OH)2(s) into CaO(s) and...Ch. 5 - Ozone, 03(9), is a form of elemental oxygen that...Ch. 5 -
5.42 Without referring to tables, predict which...Ch. 5 - Consider the following reaction: 2 Mg(s) + 02(g)2...Ch. 5 -
544 Consider the following reaction:
2...Ch. 5 - When solutions containing silver ions and chloride...Ch. 5 - At one time, a common means of forming small...Ch. 5 -
5.47 Consider the combustion of liquid methanol,...Ch. 5 -
5.48 Consider the decomposition of liquid...Ch. 5 - 5.49
a What are the units of molar heat...Ch. 5 - Two solid objects, A and B, are placed in boiling...Ch. 5 - What is the specific heat of liquid water? What is...Ch. 5 -
5.52
a. Which substance in Table 5.2 requires...Ch. 5 - The specific heat of octane, C8H18(l), is 2.22...Ch. 5 -
6.54 Consider the data about gold metal in...Ch. 5 - When a 6-50-g sample of solid sodium hydroxide...Ch. 5 -
5.56
a. When a 4 25-g sample of solid ammonium...Ch. 5 - A 2.200-g sample of quinone (C5H402) is burned in...Ch. 5 -
8.68 A 1.800-g sample of phenol (C6H5OH) was...Ch. 5 - Under constant-volume conditions, the heat of...Ch. 5 -
5.60 Under constant-volume conditions, the heat...Ch. 5 -
5.61 Can you use an approach similar to Hess's...Ch. 5 -
5.62 Consider the following hypothetical...Ch. 5 - Calculate the enthalpy change for the reaction...Ch. 5 - From the enthalpies of reaction calculate H for...Ch. 5 - From the enthalpies of reaction Calculate H for...Ch. 5 - Given the data use Hess's law to calculate H for...Ch. 5 -
5.67
What is meant by the term standard...Ch. 5 - S
5.68
What is the value of the standard enthalpy...Ch. 5 - For each of the following compounds, write a...Ch. 5 - Write balanced equations that describe the...Ch. 5 - The following is known as the thermite reaction:...Ch. 5 -
5.72 Many portable gas heaters and grills use...Ch. 5 - Using values from Appendix C , calculate the...Ch. 5 -
5.74 Using values from Appendix C, calculate the...Ch. 5 - Complete combustion of 1 mol of acetone (C2H6O)...Ch. 5 - Calcium carbide (CaC2) reacts with water to form...Ch. 5 -
5.77 Gasoline is composed primarily of...Ch. 5 - Prob. 78ECh. 5 - Ethanol (C2H5OH) is blended with gasoline as an...Ch. 5 -
5.80 Methanol (CH3OH) is used as a fuel in race...Ch. 5 -
5.81 Without doing any calculations, predict the...Ch. 5 -
5.82 Without doing any calculations, predict...Ch. 5 - Use bond enthalpies in Table 5.4 Q to estimate for...Ch. 5 - Use bond enthalpies in Table 5.40 to estimate for...Ch. 5 - Use enthalpies of formation given in Appendix C to...Ch. 5 -
5.86
The nitrogen atoms in an N2 molecule are...Ch. 5 -
5.87 Consider the reaction 2H(g) + O2(g) ...Ch. 5 -
5.88 Consider the reaction H2(g) + I2(s) ...Ch. 5 -
5.89
What is meant by the term fuel value?
Which...Ch. 5 -
5.90
Which releases the most energy when...Ch. 5 -
5.91
A serving of a particular ready-to-serve...Ch. 5 -
5.92 A pound of plain M&M® candies contains 96 g...Ch. 5 -
5.93 The heat of combustion of fructose,...Ch. 5 -
5.94 The heat of combustion of ethanol,...Ch. 5 -
5.95 The standard enthalpies of formation of...Ch. 5 -
5.98 It is interesting to compare the ‘fuel...Ch. 5 - At the end of 2012, global population was about...Ch. 5 -
5.98 The automobile fuel called E85 consists of...Ch. 5 - The air bags that provide protection in...Ch. 5 -
5.100 An aluminum can of a soft drink is placed...Ch. 5 -
5.101 Consider a system consisting of the...Ch. 5 - A sample of gas is contained in a...Ch. 5 - Limestone stalactites and stalagmites are formed...Ch. 5 - Consider the systems shown in Figure 5.10. In one...Ch. 5 -
5.105 A house is designed to have passive solar...Ch. 5 -
5.108 A coffee-cup calorimeter of the type shown...Ch. 5 -
5.107
When a 0.235-9 sample of benzoic acid is...Ch. 5 -
5.108 Meals-ready-to-eat (MREs) are military...Ch. 5 - 5.109 Burning methane in oxygen can produce three...Ch. 5 - Prob. 110AECh. 5 -
5.111 From the following data for three...Ch. 5 - The hydrocarbons acetylene (C2H2) and benzene...Ch. 5 - Ammonia (NH3) boils at -33 °C; at this temperature...Ch. 5 -
5.114 Three common hydrocarbons that contain four...Ch. 5 -
5.115 A 201-lb man decides to add to his exercise...Ch. 5 -
5.116 TheSun supplies about 1.0 kilowatt of...Ch. 5 -
5.117 Itis estimated that the net amount of...Ch. 5 -
5.118 At 20 °C (approximately room temperature)...Ch. 5 - Suppose an Olympic diver who weighs 52.0 kg...Ch. 5 -
5.120 Consider the combustion of a single...Ch. 5 -
5.121 Consider the following unbalanced...Ch. 5 - Consider the following acid-neutralization...Ch. 5 -
5.123 Consider two solutions, the first being...Ch. 5 - The precipitation reaction between AgNO3(aq) and...Ch. 5 -
5.125 A sample of a hydrocarbon is combusted...Ch. 5 -
5.126 The methane molecule, CH4, has the geometry...Ch. 5 -
5.127 One of the best-selling light, or...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- need it fast!!!!!!! Gaseous hydrogen and liquid bromine combine in the reaction below to form hydrogen bromide (HBr) in its gaseous state: H2(g) + Br2(l) --> 2 HBr(g) If ∆Ho for this reaction is -72.4 kJ, what is the standard enthalpy of formation, Hfo, for gaseous hydrogen bromide, in kJ? answer:_____________________arrow_forwardThe heat released when one mole of water is formed from the elements is 1,198 kJ. An experiment was conducted that permitted water to form in this manner, and the heat was contained in 2.0 liters of water. The water temperature before the reaction was 34.5°C, and after the reaction it had risen to 52.0°C. How many moles of water were formed? (The specific heat of water is 4.184 J/g·°C.)Answer: 0.12 mole (Can you explain how?)arrow_forwardSIMPLE ALGORITHM: Correct significant figures and rounding off (Conventional). 6. Given the following reactions: CaCO3(s) → CaO(s) + CO2(g) ΔH = 178.1 kJ C(s, graphite) + O2(g) → CO2(g) ΔH = -393.5 kJ Determine the enthalpy of the reaction of CaCO3(s) → CaO(s) + C(s, graphite) + O2(g).arrow_forward
- 59. When 24.0 g of carbon and 10.0 g of hydrogen are placed in a calorimeter and reacted according to the equation 3 C(s) + 4 H2(g) → C3H8(g) + 103.8 kJ, the maximum amount of heat liberated by this reaction is? (hint: limiting reagent) Answer: 69.1 kJarrow_forwardConsider the following reaction: 2 CH3OH(g) → 2 CH4(g) + O2(g) DH = 252.8 kJ (a) Is reaction exothermic or endothermic? ANSWERED (b) Calculate the amount of heat transferred when 24.0 g of CH3OH(g) is decomposed by this reaction at constant pressure. ANSWERED (c) For a given sample of CH3OH, the enthalpy change during the reaction is 82.1 kJ. How many grams of methane gas are produced? ANSWERED (d) How many kilojoules of heat are released when 38.5 g of CH4(g) reacts completely with O2(g) at constant pressure?arrow_forwardPractice Exercise 1If the heat of formation of H2O1l2 is -286 kJ>mol, whichof the following thermochemical equations is correct?(a) 2 H1g2 + O1g2¡H2O1l2 ΔH = -286 kJ(b) 2 H21g2 + O21g2¡2 H2O1l2 ΔH = -286 kJ(c) H21g2 + 12 O21g2¡H2O1l2 ΔH = -286 kJ(d) H21g2 + O1g2¡H2O1g2 ΔH = -286 kJ(e) H2O1l2¡H21g2 + 12O21g2 ΔH = -286 kJarrow_forward
- A 4.53 g sample of candy is placed in a bomb calorimeter and combusts in excess oxygen. The temperature of the calorimeter increases from 22.17oC to 25.36oC. The heat capacity of the calorimeter is 30.50 kJ/K. How many nutritional Calories are there per gram of the candy? ANSWER : ______ Calarrow_forwardPlease don't handwrite solution. 5) What quantity of heat (in kJ) will be absorbed by a 31.5 g piece of aluminum (specific heat = 0.930 J/g・ °C) as it changes temperature from 23.0 °C to 67.0 °C? 7) When 1.831 grams of sucrose (Molar mass 342.3 g/mol) is burned in a bomb calorimeter, the temperature of the calorimeter increases from 22.410 °C to 26.630 °C. If the heat capacity of the calorimeter is 4.900 kJ/ °C, what is the heat of combustion of sucrose, in kJ/mol?arrow_forwardA gas is enclosed in a system similar to that shown in Figure 6.9. More weights are added to the piston, giving a total mass of 2.20 kg. As a result, the gas is compressed, and the weights are lowered 0.250 m. At the same time, 1.50 J of heat evolves from the system. What is the change in internal energy of the system, U? The force of gravity on a mass m is mg, where g is the constant acceleration of gravity (g = 9.81 m/s2).arrow_forward
- Suppose that 120 g of water and 150 g of ethanol, which are at 5 °C and in different containers, are heated in the same heat source that supplies 8 kJ/min, until the alcohol reaches 25 °C. (Consider: specific heat of water is 1 cal/g °C and of ethanol is 0.6 cal/g °C). Answer: a) How long and at what temperature will the water reach until there is the same amount of heat that the system containing ethanol absorbed when it reached 25 °C? b) If the two systems are heated during the same period, theoretically which liquid should indicate a higher temperature? Explain in detail. c) Explain how interaction forces influence the thermal capacity and specific heat of materials.arrow_forwardSIMPLE ALGORITHM. Correct significant figures and rounding off (Conventional). 9. In the reaction 2Al(s) + 3O2(g) → 2Al2O3(s), determine the ΔH0f of Al2O3(s) if the value of ΔH0 is -3351 kJ.arrow_forwardCalculate the average H-S bond enthalpy in H2S(g) given that thestandard enthalpies of formation of H2S(g), H(g) and S(g) are-20.1, 218.0, and 223.0 kJ/mol, respectively. Answer = 340 kJ/mol, how do I derive please?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY