Concept explainers
(a)
Interpretation:
The reactant in excess and the amount of it remain unreacted are to be determined when
(a)
Explanation of Solution
One mole of
This means that the reaction of
Since
Thus,
(b)
Interpretation:
The amount of reactant that would need to be mixed to make the statement true is to be determined.
(b)
Explanation of Solution
According to the statement,
(c)
Interpretation:
The amount of reactant that would need to be mixed to make the statement true is to be determined.
(c)
Explanation of Solution
According to the statement,
Thus,
(d)
Interpretation:
The amount of reactant that would need to be mixed to make the statement true is to be determined.
(d)
Explanation of Solution
The number of unreacted moles of
Thus, the statement is true.
(e)
Interpretation:
The amount of reactant that would need to be mixed to make the statement true is to be determined.
(e)
Explanation of Solution
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Chapter 6 Solutions
INTRO TO CHEM LLF+ALEKS360 >BI<
- Carbon dioxide from the atmosphere weathers, or dissolves, limestone (CaCO3) by the reaction CaCO3(s)+CO2(g)+H2O(l)Ca2(aq)+2HCO3(aq) Obtain H for this reaction. See Table 6.2 for the data.arrow_forward3.81 The particulate scale drawing shown depicts the products of a reaction between H2 and O2 molecules. (a) Draw a similar representation for the reactants that must have been present before the reaction took place. (b) Write a balanced chemical equation for the reaction, using the smallest possible whole number coefficients.arrow_forward4.72 The picture shown depicts the species present at the start of a combustion reaction between methane, CH4 and oxygen, O2 (a) What is the limiting reactant? (b) Draw the resulting state after this set of reactants has reacted as far as possible.arrow_forward
- The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forwardLet us explore a reaction with a limiting reactant. Here, zinc metal is added to a flask containing aqueous HCl, and H2 gas is a product. Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g) The three flasks each contain 0.100 mol of HCl. Zinc is added to each flask in the following quantities. When the reactants are combined, the H2 inflates the balloon attached to the flask. The results are as follows: Flask 1: Balloon inflates completely, but some Zn remains when inflation ceases. Flask 2: Balloon inflates completely. No Zn remains. Flask 3: Balloon does not inflate completely. No Zn remains. Explain these results. Perform calculations that support your explanation.arrow_forwardMany cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?arrow_forward
- Methanol, CH3OH, can be prepared from carbon monoxide and hydrogen. CO(g) + 2 H2(g) CH3OH(l) What mass of hydrogen is required to produce 1.0 L of CH3OH (d = 0.791 g/mL) if this reaction has a 74% yield under certain conditions?arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forwardOn Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?arrow_forward
- A soft drink contains an unknown mass of citric acid, C3H5O(COOH)3. It requires 6.42 mL of 9.580 × 10−2-M NaOH to neutralize the citric acid in 10.0 mL of the soft drink. C3H5O(COOH)3(aq) + 3 NaOH(aq) → Na3C3H5O(COO)3(aq) + 3 H2O(ℓ) Determine which step in these calculations for the mass of citric acid in 1 mL soft drink is incorrect? Why? n (NaOH) = (6.42 mL)(1L/1000 mL)(9.580 × 10−2 mol/L) n (citric acid) = (6.15 × 10−4 mol NaOH) × (3 mol citric acid/1 mol NaOH) m (citric acid in sample) = (1.85 × 10−3 mol citric acid) × (192.12 g/mol citric acid) m (citric acid in 1 mL soft drink) = (0.354 g citric acid)/(10 mL soft drink) Determine the correct result.arrow_forward4.111 Aluminum metal reacts with sulfuric acid to form hydrogen gas and aluminum sulfate (a) Write a balanced chemical equation for this reaction. (b) Suppose that a 0.792-g sample of aluminum that contains impurities is reacted with excess sulfuric acid and 0.0813 g of H2 is collected. Assuming that none of the impurities reacts with sulfuric acid to produce hydrogen, what is the percentage of aluminum in the sample?arrow_forward4.90 Iron metal can be refined (rom the mineral hematite (Fe2O3). One way of converting the mineral to iron is to react it with carbon monoxide, as shown below: Fe2O3+3CO2Fe+3CO2 Because the hematite is obtained from various ores, it is usually not in a pure form. Suppose an iron manufacturer has 2.00 X 105 kg of ore available, and the ore is 93% Fe2O3 by mass. (There is no iron in the remaining 7% of the ore.) How many moles of Fe2O3are present in this ore? How many kg of pure iron could be obtained from this sample of ore? Assume that the process has a 100% yield and that excess CO is available.arrow_forward
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