Intro Spectroscopy
5th Edition
ISBN: 9781305221796
Author: PAVIA
Publisher: Cengage
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To obtain the most precise value of BE from the equation BE=[ZM(1H)+ Nmn]c2 − m(AX)c2 , we should take into account the binding energy of the electrons in the neutral atoms. Will doing this produce a larger or smaller value for BE? Why is this effect usually negligible?
Consider the following four transitions in ahydrogen atom:(i) ni = 2, nf = 6 (ii) ni = 2, nf = 8(iii) ni = 7, nf = 8 (iv) ni = 6, nf = 2Find (a) the longest- and (b) the shortest-wavelength photon thatcan be emitted or absorbed by these transitions. Give the valueof the wavelength in each case. (c) For which of these transitionsdoes the atom lose energy? Explain.
Explain the reason that metal atomic chains have quantized G, different from bulk metals.
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