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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

What is the structure of the carboxylic acid needed to produce each of the following amides via an amidification reaction?

Chapter 6, Problem 6.133EP, What is the structure of the carboxylic acid needed to produce each of the following amides via an , example  1

Chapter 6, Problem 6.133EP, What is the structure of the carboxylic acid needed to produce each of the following amides via an , example  2

Chapter 6, Problem 6.133EP, What is the structure of the carboxylic acid needed to produce each of the following amides via an , example  3

Chapter 6, Problem 6.133EP, What is the structure of the carboxylic acid needed to produce each of the following amides via an , example  4

(a)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  1 group present in carboxylic acid and Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  2 from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  3

Explanation

Given structure of compound is,

As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it, the amide is a primary amide.  Primary amide is produced by the reaction of ammonia with carboxylic acid.  The “parent” carboxylic acid can be identified as shown below,

(b)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  4 group present in carboxylic acid and Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  5 from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  6

(c)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  7 group present in carboxylic acid and Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  8 from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  9

(d)

Interpretation Introduction

Interpretation:

Structure of carboxylic acid that is required to produce the given compound as product through amidification has to be given.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  10 group present in carboxylic acid and Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  11 from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Organic And Biological Chemistry, Chapter 6, Problem 6.133EP , additional homework tip  12

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