Chapter 6.1, Problem 6.4P

The energy of the Hamiltonian operator defined below for the one-dimensional anharmonic oscillator Calculate first-order contributions to eigenvalues. (Here ? is a small number.)

What is the magntiude of the integral of B over dl for part c? Enter in your answer in micro-T*m. Assume that all currents are 14.7 A instead of what the textbook has noted.

Consider a system consisting of a single hydrogen atom/ion, which has two possible states: unoccupied (i.e., no electron present) and occupied (i.e., one electron present, in the ground state). Calculate the ratio of the probabilities of these two states, to obtain the Saha equation, already derived. Treat the electrons as a monatomic ideal gas, for the purpose of determining J-l. Neglect the fact that an electron has two independent spin states.

Discover the stack's true potential by letting it shine.

Consider the Lennard-Jones potential between atoms in a solid material. Find the dependence of the equilibrium postion x0, on the parameters in the potential. Then for small perturbations, δx around x0, determine the restoring force as a function of δx.

Show that if A and B are matrices which don’t commute, then eA+B = eAeB, but if they do commute then the relation holds. Hint: Write out several terms of the infinite series for eA, eB, and eA+B and do the multiplications carefully assuming that A and B don’t commute. Then see what happens if they do commute.

To obtain the value of an unknown electrical charge, a group performed an experiment. From the graph of the electric potential (voltage) V in volts, as a function of the inverse distance (1/r) in m^-1, the group obtained an angular coefficient 6838 Nm^2/C by the linear equation of the best straight line. Knowing that V=(kq)/r, calculate the value of the electric charge, in nC (nanocoulomb), from the slope provided by the best line. Round the answer to a whole number. Use: k = 8.9876 x 10^9 N⋅m^2⋅C^−2

The spherical harmonics are the eigenfunctions of ?̂2 and ?̂ ? for the rigid rotor and thehydrogen atom (and other spherically symmetric problems). In this problem, we willexamine the nature of the angular nodes for these systems.Since the spherical harmonics include a factor of eim, which never has magnitude zero, forthis exercise we will construct some linear combinations of the spherical harmonics so weare working with real-valued functions. Two of the real-valued spherical harmonics are:12 (?1−1 + ?11) = 12 √ 32? sin ? cos ? 12? (?32 − ?3−2) = 14 √1052? sin2 ? cos ? sin 2?(a) Determine the angles at which nodal surfaces will occur for each of these functions, anddescribe the nature of the nodal surfaces that they represent. In other words, identifythe locations of nodal planes and other surfaces in the Cartesian axis system.(b) What atomic orbitals (e.g. 1s, 2p, etc.) are represented by these functions and what isthe total number of distinct angular nodal surfaces?

Consider a free Fermi gas in two dimensions, confined to a squarearea A = L2. Because g(€) is a constant for this system, it is possible to carry out the integral 7.53 for the number of particles analytically. Do so, and solve for μ as a function of N. Show that the resulting formula has the expected qualitative behavior.