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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Classify each of the molecules in Problem 18-38 as a D enantiomer or an L enantiomer.

(a)

Interpretation Introduction

Interpretation: The classification of the given molecule whether being a D enantiomer or a L enantiomer has to be stated.

Concept introduction: The D and L designations are the configurations for the handedness of the two isomers of the enantiomeric pair.  D stands for dextro which means right and L stands for laevo which means left.

Explanation

The D and L configuration for a monosaccharide is determined by the chiral center present at the farthest distance from the carbonyl carbon atom.  The given compound is,

If the hydroxyl group on the farthest chiral carbon from the carbonyl group is present on the right side, then the enantiomer is classified as D-enantiomer...

(b)

Interpretation Introduction

Interpretation: The classification of the given molecule whether being a D enantiomer or a L enantiomer has to be stated.

Concept introduction: The D and L designations are the configurations for the handedness of the two isomers of the enantiomeric pair.  D stands for dextro which means right and L stands for laevo which means left.

(c)

Interpretation Introduction

Interpretation: The classification of the given molecule whether being a D enantiomer or a L enantiomer has to be stated.

Concept introduction: The D and L designations are the configurations for the handedness of the two isomers of the enantiomeric pair.  D stands for dextro which means right and L stands for laevo which means left.

(d)

Interpretation Introduction

Interpretation: The classification of the given molecule whether being a D enantiomer or a L enantiomer has to be stated.

Concept introduction: The D and L designations are the configurations for the handedness of the two isomers of the enantiomeric pair.  D stands for dextro which means right and L stands for laevo which means left.

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