ORGANIC CHEM W/BIOLOGICAL TOP. ACCESS
6th Edition
ISBN: 9781264382545
Author: SMITH
Publisher: MCG CUSTOM
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Chapter 7.12, Problem 23P
What happens to the rate of an
a.
b. Both
c.
d.
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2. Consider the following reaction for the formation of HCl in the presence of light.
Cl2 + CHCI3 → HCI + cl4
The following is the proposed reaction mechanism:
Step 1
Cl2 → CI + CI
Step 2
Step 3
CI + CCl3 → CCI4
Determine Step 2 of the reaction mechanism (show work).
The rate equation for the reaction of CH3CH2Br with −OH is: rate = k[CH3CH2Br][−OH]. What effect does the indicated concentration change have on the overall rate of the reaction?
a. tripling the concentration of CH3CH2Br only
b. tripling the concentration of −OH only
c. tripling the concentration of both CH3CH2Br and −OH
Draw an energy diagram for each reaction. Label the axes, the starting material, product, transition state, ΔHo, and Ea.
a. a concerted reaction with ΔHo = −80 kJ/mol and Ea = 16 kJ/mol
a two-step reaction, A → B → C, in which the relative energy of the compounds is A < C < B, and the step A → B is rate-determining
Chapter 7 Solutions
ORGANIC CHEM W/BIOLOGICAL TOP. ACCESS
Ch. 7.1 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7.2 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7.2 - Prob. 3PCh. 7.3 - An sp3 hybridized CCl bond is more polar than an...Ch. 7.4 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 10PCh. 7.8 - Prob. 15PCh. 7.8 - Prob. 16PCh. 7.8 - Prob. 17P
Ch. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Draw the product of each SN2 reaction and indicate...Ch. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - What happens to the rate of an SN1 reaction under...Ch. 7.12 - Draw the products of each SN1 reaction and...Ch. 7.13 - Classify each carbocation as 1,2, or 3. a. b. c....Ch. 7.15 - Problem 7.30 For each alkyl halide and...Ch. 7.15 - Prob. 30PCh. 7.15 - Prob. 31PCh. 7.15 - Prob. 32PCh. 7.15 - Prob. 33PCh. 7.15 - Prob. 34PCh. 7 - Give the IUPAC name for each compound, including...Ch. 7 - Draw the products of each nucleophilic...Ch. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - 7.53 Consider the following reaction.
Draw a...Ch. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - Consider the following SN1 reaction. a.Draw a...Ch. 7 - 7.59 Pick the reactant or solvent in each part...Ch. 7 - Draw the products of each SN1 reaction and...Ch. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Draw a stepwise, detailed mechanism for the...Ch. 7 - When a single compound contains both a nucleophile...Ch. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Draw a stepwise, detailed mechanism f or the...Ch. 7 - Prob. 72PCh. 7 - Prob. 78P
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