ORGANIC CHEMISTRY-W/ACCESS >CUSTOM<
10th Edition
ISBN: 9781260028362
Author: Carey
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 7.19, Problem 30P
A standard method for the synthesis of ethers is an
Show possible combinations of alkoxide and
a)
b)
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
A standard method for the synthesis of ethers is an SN2 reaction between an alkoxide and an alkyl halide.Show possible combinations of alkoxide and alkyl halide for the preparation of the following ethers. Which of these can be prepared effectively by this method?
What product is obtained from the reaction of excess benzene with each of the following reagents?
a. isobutyl chloride + AlCl3
b. 1-chloro-2,2-dimethylpropane + AlCl3
c. dichloromethane + AlCl3
Choose from the options A-E and explain briefly by illustrations the chemistry behind each answer.
Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic products. 1.Predict the products that would be formed from such a reaction
A.1-pentene (80%) and 2-pentene (20%)B.1-pentene (20%) and 2-pentene (80 %)C.1-pentene (50 %) and 2-pentene (50 %)D.1-pentene (0 %) and 2-pentene (100 %)E.1-pentene (100 %) and 2-pentene (0 %)
2.What reaction pathway is followed by the reaction above?A.E2 dehydrohalogenation B.E1 dehydrohalogenationC.SN1 dehydrohalogenationD.SN2 dehydrohalogenationE.A mixture of E1 and E2 pathways
3.What is responsible for the formation of different products (major and minor).A.The different activated complex involved in the mechanism.B.Bimolecular Nucleophilic substitution reaction C.Bimolecular Elimination reaction D.The presence of sodium ethoxideE.The hybridisation…
Chapter 7 Solutions
ORGANIC CHEMISTRY-W/ACCESS >CUSTOM<
Ch. 7.1 - Name each of the following using IUPAC...Ch. 7.1 - Prob. 2PCh. 7.2 - How many carbon atoms are sp2-hybridized in the...Ch. 7.3 - Prob. 4PCh. 7.3 - Are cis-2-hexene and trans-3-hexene stereoisomers?...Ch. 7.4 - Prob. 6PCh. 7.4 - Prob. 7PCh. 7.4 - Give the IUPAC name of each of the compounds in...Ch. 7.5 - Arrange the following in order of increasing...Ch. 7.6 - Prob. 10P
Ch. 7.6 - Standard enthalpies of formation are known for all...Ch. 7.6 - Prob. 12PCh. 7.6 - Despite numerous attempts, the alkene...Ch. 7.6 - Write structural formulas for the six isomeric...Ch. 7.7 - Place a double bond in the carbon skeleton shown...Ch. 7.9 - Identify the alkene obtained on dehydration of...Ch. 7.10 - Prob. 17PCh. 7.11 - Prob. 18PCh. 7.12 - Prob. 19PCh. 7.13 - The alkene mixture obtained on dehydration of...Ch. 7.14 - Write the structures of all the alkenes that can...Ch. 7.14 - Write structural formulas for all the alkenes that...Ch. 7.15 - A study of the hydrolysis behavior of...Ch. 7.15 - Use curved arrows to illustrate the electron flow...Ch. 7.15 - Predict the major product of the reaction shown.Ch. 7.16 - Prob. 26PCh. 7.17 - Prob. 27PCh. 7.18 - Prob. 28PCh. 7.19 - Predict the major organic product of each of the...Ch. 7.19 - A standard method for the synthesis of ethers is...Ch. 7 - Write structural formulas for each of the...Ch. 7 - Prob. 32PCh. 7 - Give an IUPAC name for each of the following...Ch. 7 - A hydrocarbon isolated from fish oil and from...Ch. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Choose the more stable alkene in each of the...Ch. 7 - Suggest an explanation for the fact that...Ch. 7 - Prob. 41PCh. 7 - Write structural formulas for all the alkene...Ch. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Predict the major organic product of each of the...Ch. 7 - Prob. 46PCh. 7 - Prob. 47PCh. 7 - The rate of the reaction In the first order in...Ch. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - You have available 2,2-dimethylcyclopentanol (A)...Ch. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Acid-catalyzed dehydration of...Ch. 7 - The ratio of elimination to substitution is...Ch. 7 - Prob. 57PCh. 7 - Prob. 58DSPCh. 7 - Prob. 59DSPCh. 7 - Prob. 60DSPCh. 7 - Prob. 61DSPCh. 7 - A Mechanistic Preview of Addition Reactions The...Ch. 7 - Prob. 63DSPCh. 7 - Prob. 64DSPCh. 7 - Prob. 65DSP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using your reaction roadmap as a guide, show how to convert 1-butanol and ethanol into racemic 2-ethoxy-1-butanol. You must use 1-butanol and ethanol as the source of all carbon atoms in the ether product. Show all required reagents and all molecules synthesized along the way.arrow_forwardUsing your reaction roadmap as a guide, show how to convert butane into butanal. Show all reagents needed and all molecules synthesized along the way.arrow_forwardStarting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. a. Cyclohexanol b. Cyclohexene c. cis-1,2-Cyclohexanediol d. 1-Methylcyclohexanol e. 1-Methylcyclohexene f. 1-Phenylcyclohexanol g. 1-Phenylcyclohexene h. Cyclohexene oxide i. trans-1,2-Cyclohexanediolarrow_forward
- Choose reagents to convert 2-cyclohexenone to the following compounds.arrow_forwardPredict the starting material or reagents needed to carry out the desired reactions.arrow_forwardDescribe how 3-methyl-1-phenyl-3-pentanol can be prepared from benzene. You can use any inorganic reagents and solvents, and any organic reagents provided they contain no more than two carbons.arrow_forward
- INSTRUCTIONS: Choose from the options A-E and explain briefly by illustrations the chemistry behind each answer. Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic products. Predict the products that would be formed from such a reaction a)1-pentene (80%) and 2-pentene (20%)B)1-pentene (20%) and 2-pentene (80 %)C)1-pentene (50 %) and 2-pentene (50 %)D)1-pentene (0 %) and 2-pentene (100 %)E)1-pentene (100 %) and 2-pentene (0 %) What reaction pathway is followed by the reaction above?a)E2 dehydrohalogenation B)E1 dehydrohalogenationC)SN1 dehydrohalogenationD)SN2 dehydrohalogenation A mixture of E1 and E2 pathways What is responsible for the formation of different products (major and minor).A)The different activated complex involved in the mechanism. B)Bimolecular nuclephilic substitution reaction C)Bimolecular Elimination reaction D)The presence of sodium ethoxideE)The…arrow_forwardINSTRUCTIONS: Choose from the options A-E and explain briefly by illustrations the chemistry behind each answer. Preamble: A reaction flask contains a 2-bromopentane in an ethanolic solution of sodium ethoxide at room temperature and results in the formation of two olefinic products. Predict the products that would be formed from such a reaction A. 1-pentene (80%) and 2-pentene (20%) B. 1-pentene (20%) and 2-pentene (80 %) C. 1-pentene (50 %) and 2-pentene (50 %) D. 1-pentene (0 %) and 2-pentene (100 %) E. 1-pentene (100 %) and 2-pentene (0 %) 2. What reaction pathway is followed by the reaction above? A. E1 dehydrohalogenation B. E2 dehydrohalogenation C. SN1 dehydrohalogenation D. SN2 dehydrohalogenation E. A mixture of E1 and E2 pathways 3. What is responsible for the formation of different products (major and minor). A. The different activated complex involved in the mechanism. B. Bimolecular Nucleophilic substitution reaction C. Bimolecular Elimination reaction D. The…arrow_forwardThe reaction of a ketone and excess methanol with an acid as a catalyst gives what product? A) Hemiacetal B) Di-ether C) Hemiketal D) Acetal E) Ketalarrow_forward
- Propose a reaction starting material and reagents to prepare diphenyl sulfide in the laboratory. Show all the needed steps in the formation of the productarrow_forwardGive the products, if any, of each of the following reactions: a. benzonitrile + methyl chloride + AlCl3 b. phenol + Br2 c. benzoic acid + CH3CH2Cl + AlCl3 d. benzene + 2 CH3Cl + AlCl3arrow_forwardShow how to bring about the following conversions using as one step the hydrolysis of a cyano group.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Alcohols, Ethers, and Epoxides: Crash Course Organic Chemistry #24; Author: Crash Course;https://www.youtube.com/watch?v=j04zMFwDeDU;License: Standard YouTube License, CC-BY