(A)
Interpretation:
The molar volume
Concept Introduction:
The expression to calculate the molar volume
Here, pressure is P, gas constant is R, and temperature is T.
(B)
Interpretation:
The molar volume
Concept Introduction:
The expression for van der Waals parameter
Here, critical temperature is
Write the expression for van der Waals parameter
(C)
Interpretation:
The molar volume
Concept Introduction:
Write the relationship between the parameter, m and Soave’s EOS.
Here, the acentric factor is
Write the reduced temperature.
Here, critical temperature is
Write the expression
Here, reduced temperature is
Write the reduced pressure
Here, pressure is
Write the expression of a at the critical point.
Write the expression of b as Soave equation.
Write the expression to calculate the molar volume using the Soave equation.
(D)
Interpretation:
The molar volume
Concept Introduction:
Write the expression to calculate the parameter a for Peng-Robinson EOS.
Write the expression to calculate the
Write the expression to calculate the value of parameter a at the critical point.
Write the expression to calculate the van der Waals parameter
Write the expression to calculate the van der Waals parameter
Write the expression to calculate the molar volume
(E)
Interpretation:
The molar volume
Concept Introduction:
Write the expression to calculate the virial parameter or coefficient
Write the expression to calculate the virial parameter
Write the expression to calculate parameter as a function of temperature and the acentric factor.
Here, function of temperature is
Write the expression to calculate the relative pressure.
Write the expression to calculate the virial compressibility factor
(F)
Interpretation:
The molar volume
Concept Introduction:
Write the expression to calculate the compressibility factor
Here, compressibility of compound with
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Chapter 7 Solutions
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