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Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079

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Chapter
Section
BuyFindarrow_forward

Organic And Biological Chemistry

7th Edition
STOKER + 1 other
ISBN: 9781305081079
Textbook Problem

Which of the following properties would be the same for a pair of enantiomers?

  1. a. interaction with plane-polarized light
  2. b. solubility in a chiral solvent
  3. c. melting point
  4. d. no correct response

Interpretation Introduction

Interpretation: The property which would be the same for a pair of enantiomers has to be predicted.

Concept introduction: An enantiomeric pair contains two compounds.  One is dextrorotatory and another is levorotatory.  Enantiomers have same melting points, boiling points and densities.  These properties depend on the intermolecular forces and the intermolecular forces do not depend upon chirality.

Explanation

Reason for correct option:

An enantiomeric pair contains two forms of a chiral molecule.  These chiral molecules posses similar set of functional groups.  These two forms in the enantiomeric pair will have same strength of intermolecular forces.  Therefore, chirality does not affect the strength of intermolecular forces in these molecules.  The physical properties of enantiomers depend upon the strength of intermolecular forces...

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