CHM 101 VOL 1 2014 >IC<
CHM 101 VOL 1 2014 >IC<
17th Edition
ISBN: 9781269932905
Author: Pearson
Publisher: PEARSON C
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Chapter 8, Problem 42E

Arrange the bonds in each of the following sets in order of increasing polarity:

  1. C- F, 0-F, Be-F;
  2. 0-Cl, S- Br, C- P;
  3. C- S, B- F, N-0.

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Which has the greater N–O bond length, NO2– or NO3–? Can you explain why the answer is NO3-? Both have single bonds and double bonds so are they not the same?
Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfurtetrafluoride monoxide (OSF4) according to the followingunbalanced reaction: SF4(g) + O2(g)---->OSF4(g)The O atom and the four F atoms in OSF4 are bonded to acentral S atom. (a) Balance the equation. (b) Write a Lewisstructure of OSF4 in which the formal charges of all atomsare zero. (c) Use average bond enthalpies (Table 8.3) to estimatethe enthalpy of the reaction. Is it endothermic or exothermic?(d) Determine the electron-domain geometry ofOSF4, and write two possible molecular geometries for themolecule based on this electron-domain geometry. (e) Foreach of the molecules you drew in part (d), state how manyfluorines are equatorial and how many are axial.
“Inert” xenon actually forms several compounds, especially with the highly electronegative elements oxygen and fluorine.The simple fluorides XeF₂, XeF₄, and XeF₆ are all formed by di-rect reaction of the elements. As you might expect from the sizeof the xenon atom, the Xe-F bond is not a strong one. Calcu-late the Xe-F bond energy in XeF₆, given that the heat of for-mation is 402 kJ/mol.

Chapter 8 Solutions

CHM 101 VOL 1 2014 >IC<

Ch. 8.5 - Which of the these molecules has a Lewis structure...Ch. 8.5 - How many valence electrons should appear in the...Ch. 8.5 - Compare the lewis symbol for neon the structure...Ch. 8.5 - Prob. 8.7.2PECh. 8.5 - Prob. 8.8.1PECh. 8.5 - Prob. 8.8.2PECh. 8.5 - Prob. 8.9.1PECh. 8.5 - Prob. 8.9.2PECh. 8.6 - Which of the statements about resonance is true?...Ch. 8.6 - Prob. 8.10.2PECh. 8.7 - Prob. 8.11.1PECh. 8.7 - Prob. 8.11.2PECh. 8 - Prob. 1DECh. 8 - Prob. 1ECh. 8 - Prob. 2ECh. 8 - A portion of a two-dimensional "slab" of NaCl(s)...Ch. 8 - Prob. 4ECh. 8 - Prob. 5ECh. 8 - Incomplete Lewis structures for the nitrous acid...Ch. 8 - Prob. 7ECh. 8 - Prob. 8ECh. 8 - Prob. 9ECh. 8 - True or false: The hydrogen atom is most stable...Ch. 8 - Consider the element silicon, Si. Write its...Ch. 8 - Write the electron configuration for the element...Ch. 8 - Prob. 13ECh. 8 - What is the Lewis symbol for each of the following...Ch. 8 - Using Lewis symbols, diagram the reaction between...Ch. 8 - Use Lewis symbols to represent the reaction that...Ch. 8 - Predict the chemical formula of the ionic compound...Ch. 8 - Prob. 18ECh. 8 - Prob. 19ECh. 8 - Prob. 20ECh. 8 - Is lattice energy usually endothermic or...Ch. 8 - NaCI and KF have the same crystal structure. The...Ch. 8 - Prob. 23ECh. 8 - Prob. 24ECh. 8 - Consider the ionic compounds KF, NaCl, NaBr, and...Ch. 8 - Which of the following trends in lattice energy is...Ch. 8 - Energy is required to remove two electrons from Ca...Ch. 8 - Prob. 28ECh. 8 - Use data from Appendix C, Figure 7.10, and Figure...Ch. 8 - Prob. 30ECh. 8 - Prob. 31ECh. 8 - Prob. 32ECh. 8 - Using Lewis symbols and Lewis structures, diagram...Ch. 8 - Use Lewis symbols and Lewis structures to diagram...Ch. 8 - Prob. 35ECh. 8 - Prob. 36ECh. 8 - Prob. 37ECh. 8 - What is the trend in electronegativity going from...Ch. 8 - Prob. 39ECh. 8 - By referring only to the periodic table, select...Ch. 8 - which of the following bonds are polar? B-F,...Ch. 8 - Arrange the bonds in each of the following sets in...Ch. 8 - Prob. 43ECh. 8 - Prob. 44ECh. 8 - In the following pairs of binary compounds,...Ch. 8 - Prob. 46ECh. 8 - Prob. 47ECh. 8 - Write Lewis structures for the following: H2CO...Ch. 8 - Prob. 49ECh. 8 - Draw the dominant Lewis structure for the...Ch. 8 - Write Lewis structures that obey the octet rule...Ch. 8 - Prob. 52ECh. 8 - Prob. 53ECh. 8 - Prob. 54ECh. 8 - Prob. 55ECh. 8 - Prob. 56ECh. 8 - Prob. 57ECh. 8 - Prob. 58ECh. 8 - Prob. 59ECh. 8 - Prob. 60ECh. 8 - Prob. 61ECh. 8 - 8.62 For Group 3A-7A elements in the third row of...Ch. 8 - Draw the Lewis structures for each of the...Ch. 8 - Prob. 64ECh. 8 - In the vapor phase, BeCl2exists as a discrete...Ch. 8 - 8.66 Describe the molecule xenon trioxide, XeO3,...Ch. 8 - 8.67 There are many Lewis structures you could...Ch. 8 - Prob. 68ECh. 8 - Using Table 8.3, estimate H for each of the...Ch. 8 - Using Table 8.3, estimate H for the following...Ch. 8 - State whether each of these statements is true or...Ch. 8 - Prob. 72ECh. 8 - Prob. 73ECh. 8 - Prob. 74ECh. 8 - Prob. 75ECh. 8 - Prob. 76ECh. 8 - A new compound is made that has a C-C bond length...Ch. 8 - A new compound is made that has an N-N bond length...Ch. 8 - Prob. 79AECh. 8 - Prob. 80AECh. 8 - An ionic substance of formula MX has a lattice...Ch. 8 - Prob. 82AECh. 8 - Prob. 83AECh. 8 - Prob. 84AECh. 8 - Consider the collection of nonmetallic elements 0,...Ch. 8 - The substance chlorine monoxide, CIO(g), is...Ch. 8 - [8.87] a. using the electronegativities of Br...Ch. 8 - Prob. 88AECh. 8 - Although I3- is a known ion, F3- is not. a. Draw...Ch. 8 - Calculate the formal charge on the indicated atom...Ch. 8 - The hypochlorite ion, CIO- , is the active...Ch. 8 - Prob. 92AECh. 8 - a. Triazine, C3 H3N3, is like benzene except that...Ch. 8 - Prob. 94IECh. 8 - Prob. 95IECh. 8 - Prob. 96IECh. 8 - Prob. 97IECh. 8 - Prob. 98IECh. 8 - Prob. 99IECh. 8 - Prob. 100IECh. 8 - Prob. 101IECh. 8 - Prob. 102IECh. 8 - 8.103 The compound chloral hydrate, known in...Ch. 8 - Barium azide is 62.04% Ba and 37.96% N. Each azide...Ch. 8 - Acetylene (C2H2) and nitrogen (N2) both contain a...Ch. 8 - Prob. 106IECh. 8 - Prob. 107IECh. 8 - 8.108 Formic acid has the chemical formula...Ch. 8 - Prob. 109IECh. 8 - Prob. 110IE
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY