(a)
Interpretation:
Nucleophile which forms the given compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
The nucleophile attacks the back side of the carbon that is attached to the halogen. Therefore it takes an inversion of configuration.
The configuration of the product is inverted relative to the configuration of the reactant.
(b)
Interpretation:
Nucleophile which forms given compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
Steric effect is the effect due to the groups occupies a certain volume of space.
Steric hindrance is caused by the bulky groups at the site of a reaction that makes it difficult for the reactants to approach each other.
(c)
Interpretation:
Nucleophile which forms given compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.
Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen.
The stronger base is always a better nucleophile in an aprotic solvent.
(d)
Interpretation:
Nucleophile which forms the following compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
The stronger base is always a better nucleophile in an aprotic solvent.
(e)
Interpretation:
Nucleophile which forms the following compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
The nucleophile attacks the back side of the carbon that is attached to the halogen. Therefore it takes an inversion of configuration.
The configuration of the product is inverted relative to the configuration of the reactant.
(f)
Interpretation:
Nucleophile which forms given compounds when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism. The nucleophile attacks the back side of the carbon that is attached to the halogen. Therefore it takes an inversion of configuration.
The configuration of the product is inverted relative to the configuration of the reactant.
(g)
Interpretation:
Nucleophile which forms given compound when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
The nucleophile attacks the back side of the carbon that is attached to the halogen. Therefore it takes an inversion of configuration.
The configuration of the product is inverted relative to the configuration of the reactant.
(h)
Interpretation:
Nucleophile which forms given compound when it reacts with
Concept Introduction:
The SN2 reaction is a type of reaction mechanism in which one bond is broken and one bond is formed i.e., in one step. SN2 is a kind of nucleophilic substitution reaction mechanism.
The nucleophile attacks the back side of the carbon that is attached to the halogen. Therefore it takes an inversion of configuration.
The configuration of the product is inverted relative to the configuration of the reactant.
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Chapter 9 Solutions
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
- Draw the structure of an alkene with one double bond that would give the following compound as the only product after ozonolysis followed by H2O2.arrow_forwardHow many elimination products will be formed in the following reaction?arrow_forward9. Which of the following nucleophiles can undergo a substitution reaction with an alcohol under strongly acidic conditions? NH₂ - A B Br C D MgBrarrow_forward
- Which carbon will attack the alkyl halide (methyl iodide) in the major organic product of the following substitution reaction? B H₂ CH3 A D 1) LDA, THF 2) CHẠI C A B ں 000 Darrow_forward5. What is the structure of an intermediate in the methyl shift rearrangement reaction shown in the box? A) C) B H₂SO4, H₂O B) D) OHarrow_forwardWhich of the following species is attacked by benzene in the electrophilic nitration reaction? NO+ NO₂ NO₂ HNO3 N3™ +arrow_forward
- Indicate which compound will have the highest reaction rate in the electrophilic aromatic substitution: 2-acetyltoluene and 2-hydroxybenzonitrile.arrow_forwardWhich benzene derivative would be the most reactive in an electrophillic aromatic substitution reaction? HO ONarrow_forwardWhich of the following aromatic compounds will not react with Friedel-Crafts alkylation? NO2 OH DAH DEH DIH DOH DEH DOH DAH DIHarrow_forward
- Write equations and answer questions for the following: Step 1: conversion of 1-bromobutane into a Grignard reagent. o Step 2: reaction of the Grignard reagent with the ketone to form an alkoxide salt. Identify the nucleophile (and its nucleophilic site) and electrophile (and its electrophilic site) in this reaction. O Step 3: protonation of the alkoxide salt using ammonium chloride as the proton source. Identify the acid and base in this reaction. o Write the net reaction.arrow_forwardWhich of these nucleophiles would be the best for converting a tertiary alkyl halide into an alcohol? CH3O- CH3OH H3O+ OH- H2Oarrow_forwardArrange the following compounds in an increasing order of their reactivity in nucleophilic addition reactions : ethanal, propanal, propanone, butanone.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning