(a)
Interpretation:
The increasing order of reactivity in the
Concept introduction:
An
(b)
Interpretation:
The increasing order of reactivity in the
Concept introduction:
An
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Organic Chemistry
- (a) Write the structures of main products when benzene diazonium chloride reacts with the following reagents :(i) H3PO2 + H2O (ii) CuCN/KCN (iii) H2O(b) Arrange the following in the increasing order of their basic character in an aqueous solution :C2H5NH2, (C2H5)2NH, (C3H5)3N(c) Give a simple chemical test to distinguish between the following pair of compounds :C6H5—NH2 and C6H5—NH—CH3arrow_forwardWhich of the following reaction coordinate diagrams represents SN1 and E1 reactions? A B C Darrow_forward(17, 18, 5) Give the relative rates of reaction of the four carboxylic acid derivatives below with aqueous sodium hydroxide to give the sodium carboxylate salt.arrow_forward
- List the alkyl halides in order of decreasing reactivity towards the Sn2 reaction.arrow_forwardCompound A produce compound D while undergo Friedel Crafts Alkylation. Compound D is then oxidized and produce compound E (C11H12O3) as a major product.What are the possible structural formula of compound D and E?arrow_forwardPropanal and propanone react in a similar way with acidified aqueous potassium cyanide, KCN. For this reaction to occur reasonably quickly, the pH of the solution should be approximately 4. The reaction of propanal proceeds with acidified potassium cyanide proceeds more rapidly than that of propanone. Referring to the mechanism of the reactions, explain this phenomenon.arrow_forward
- Which of the alkyl halide bromide below is/are capable of reacting by E2 elimination?arrow_forwardBenzenediazonium carboxylate decomposes when heated to yield N2, CO2, and a reactive substance that can't be isolated. When benzenediazonium carboxylate is heated in the presence of furan, the following reaction is observe. Propose a structure for the intermediate in this reaction.arrow_forwardAre compounds a and b potential products of the reaction - why?arrow_forward
- Establish the reaction and propose a mechanism for the reaction of benzene with bromine catalyzed with ferric bromidearrow_forwardBringing together your knowledge of the reaction chemistry of substituted benzenes, suggest a preparative route for conversion of compound A to compound B shown belowarrow_forwardPredict the major product of E1 elimination of the following compounds and write a detailed mechanism for its formationarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning