EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
3rd Edition
ISBN: 8220101460288
Author: Deal
Publisher: PEARSON
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Chapter 9, Problem 9.51PP
Summary Introduction
To determine:
The stronger acid, lactic acid or pyruvic acid, which has
Introduction:
Strong acids readily dissociate into its ions when they are dissolved in water, whereas weak acid partially dissociates into its ions when they are dissolved in water.
The strengths of acids are compared by their
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Chapter 9 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
Ch. 9 - Prob. 9.1PPCh. 9 - Indicate if each of the following statements is...Ch. 9 - Prob. 9.3PPCh. 9 - Prob. 9.4PPCh. 9 - Prob. 9.5PPCh. 9 - In each of the following equations, identify the...Ch. 9 - Prob. 9.7PPCh. 9 - Prob. 9.8PPCh. 9 - Prob. 9.9PPCh. 9 - Which of the following are strong bases? a....
Ch. 9 - Prob. 9.11PPCh. 9 - Prob. 9.12PPCh. 9 - Prob. 9.13PPCh. 9 - Prob. 9.14PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.17PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.19PPCh. 9 - Prob. 9.20PPCh. 9 - Write an equilibrium constant expression lor the...Ch. 9 - Prob. 9.22PPCh. 9 - Prob. 9.23PPCh. 9 - Prob. 9.24PPCh. 9 - Prob. 9.25PPCh. 9 - Sulfur trioxide is produced by reacting sulfur...Ch. 9 - Prob. 9.27PPCh. 9 - Prob. 9.28PPCh. 9 - Prob. 9.29PPCh. 9 - When you exercise, energy is produced by...Ch. 9 - Using Tables 9.1 and 9.6, identity the stronger...Ch. 9 - Using Tables 9.1 and 9.6, identify the stronger...Ch. 9 - Prob. 9.33PPCh. 9 - Identify the acid and base on the reactant side of...Ch. 9 - Prob. 9.35PPCh. 9 - Prob. 9.36PPCh. 9 - Prob. 9.37PPCh. 9 - Write the formula and name of the conjugate acid...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of these following solutions is...Ch. 9 - Slate if each of the following solutions is...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the [H3O+] for each of the following...Ch. 9 - Calculate the [H3O+J lor each of the following...Ch. 9 - Prob. 9.49PPCh. 9 - Using Table 9.8, determine the stronger acid from...Ch. 9 - Prob. 9.51PPCh. 9 - Prob. 9.52PPCh. 9 - Prob. 9.53PPCh. 9 - Prob. 9.54PPCh. 9 - Valine has the zwitterion structure shown in the...Ch. 9 - Glycine has the zwitterion structure shown in the...Ch. 9 - Prob. 9.57PPCh. 9 - Prob. 9.58PPCh. 9 - During stress or trauma, a person can start to...Ch. 9 - A person who overdoses on antacids may neutralize...Ch. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - What are some ingredients found in antacids? What...Ch. 9 - Prob. 9.65APCh. 9 - Prob. 9.66APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - For the following reaction, 2HI(g)H2(g)+I2(g) a....Ch. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Determine the pH for the following solutions....Ch. 9 - Determine the pi! for the following solutions....Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Consider the acetic-acid buffer system with acetic...Ch. 9 - Consider the lactic-acid buffer with lactic acid,...Ch. 9 - In blood plasma, pH is maintained by the carbonic...Ch. 9 - Adding a few drops o! a strong add to water will...Ch. 9 - Consider the amino acid valine shown in its...Ch. 9 - Prob. 9.86CPCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CPCh. 9 - Prob. 9.89CPCh. 9 - Naproxen, the active ingredient in Aleve has the...Ch. 9 - To determine the concentration of an unknown weak...Ch. 9 - Explain why the following amino acid cannot exist...Ch. 9 - Prob. 1IA.1QCh. 9 - Prob. 1IA.2QCh. 9 - Prob. 1IA.3QCh. 9 - Prob. 1IA.4QCh. 9 - Prob. 1IA.5QCh. 9 - Provide the a. conjugate base of H2S. _______ b....Ch. 9 - If the lungs fail to expel normal amounts of CO2...Ch. 9 - If the lungs expel CO2 faster than normally...Ch. 9 - Prob. 2IA.3QCh. 9 - Prob. 2IA.4QCh. 9 - Prob. 1ICCh. 9 - Prob. 2ICCh. 9 - Prob. 3IC
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- Weak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/Aarrow_forwardWhich is the stronger of the following two acids? (a) acetic acid, CH3CO2H, Ka = 1.8 105 (b) chloroacetic acid, ClCH2CO2H, pKa = 2.85arrow_forwardConsider these acids (a) Arrange the acids in order of increasing acid strength from weakest to strongest. (b) Which acid has the smallest pKa value?arrow_forward
- Find the value of Kb for the conjugate base of the following organic acids. (a) picric acid used in the manufacture of explosives; Ka = 0.16 (b) trichloroacetic acid used in the treatment of warts; Ka = 0.20arrow_forwardTwo strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forwardThe base ethylamine (CH3CH2NH2) has a Kb of. A closely related base, ethanolamine(HOCH2CH2NH2), has a Kb of 3.2105. (a) Which of the two bases is stronger? (b) Calculate the pH of a 0.10M solution of the strong base?arrow_forward
- Which acid has the strongest conjugate base? (a) HNO2 (b) C6H5CO2H (c) HCN (d) HClarrow_forwardThe pH of a 0.10-M solution of propanoic acid, CH3CH2COOH, a weak organic acid, is measured at equilibrium and found to be 2.93 at 25 °C. Calculate the Ka of propanoic acid.arrow_forwardAll amino acids have at least two functional groups with acidic or basic properties. In alanine, the carboxylic acid group has Ka = 4.5 103 and the amino group has Kb = 7.4 105. Three ions of alanine are possible when alanine is dissolved in water. Which of these ions would predominate in a solution with [H+] = 1.0 M? In a solution with [OH] = 1.0 M?arrow_forward
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