Chapter 9, Problem 9.52AP

Interpretation Introduction

(a)

Interpretation:

The structure of the nucleophile that could be used to convert the iodoethane into $\text{1-}$ ethoxypropane is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by the other nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer to Problem 9.52AP

The structure of the nucleophile that could be used to convert them into $\text{1-}$ ethoxypropane is shown below.

Explanation of Solution

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

The reaction that takes place to convert the iodoethane into the $\text{1-}$ ethoxypropane is shown below.

Figure 1

The structure of the nucleophile that could be used to convert the iodoethane to give $\text{1-}$ ethoxypropane is shown below.

Figure 2

Conclusion

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown in Figure 2.

Interpretation Introduction

(b)

Interpretation:

The structure of the nucleophile that could be used to convert the iodoethane to give the ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\text{CN}$ compound is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer to Problem 9.52AP

The structure of the nucleophile that could be used to convert the iodoethane to give the ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\text{CN}$ compound is $\text{NaCN}$

Explanation of Solution

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

The reaction that takes place to convert the iodoethane into ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\text{CN}$ is shown below.

Figure 3

The structure of the nucleophile that could be used to convert the iodoethane to give the ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\text{CN}$ compound is $\text{NaCN}$.

Conclusion

The structure of the nucleophile that could be used to convert the iodoethane to give the ${\text{CH}}_{\text{3}}{\text{CH}}_{\text{2}}\text{CN}$ compound is $\text{NaCN}$.

Interpretation Introduction

(c)

Interpretation:

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer to Problem 9.52AP

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown below.

Explanation of Solution

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

The reaction that takes place to convert the iodoethane into the given compound is shown below.

Figure 4

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown below.

Figure 5

Conclusion

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown in the Figure 5.

Interpretation Introduction

(d)

Interpretation:

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer to Problem 9.52AP

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown below.

Explanation of Solution

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

The reaction that takes place to convert the iodoethane into the given compound is shown below.

Figure 6

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown below.

Figure 7

Conclusion

The structure of the nucleophile that could be used to convert the iodoethane to give the given compound is shown in the Figure 7.

Interpretation Introduction

(e)

Interpretation:

The structure of the nucleophile that could be used to convert the iodoethane to give ${\left({\text{CH}}_{\text{3}}\right)}_{\text{3}}\stackrel{\text{+}}{\text{N}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{3}}{\text{ I}}^{-}$ compound is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer to Problem 9.52AP

The structure of the nucleophile that could be used to convert the iodoethane to give ${\left({\text{CH}}_{\text{3}}\right)}_{\text{3}}\stackrel{\text{+}}{\text{N}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{3}}{\text{ I}}^{-}$ compound is shown below.

Explanation of Solution

The ${\text{S}}_{\text{N}}\text{2}$ reaction is a nucleophilic substitution bimolecular reaction in which the addition of incoming nucleophile and removal of outgoing nucleophile takes place simultaneously.

The reaction that takes place to convert the iodoethane into ${\left({\text{CH}}_{\text{3}}\right)}_{\text{3}}\stackrel{\text{+}}{\text{N}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{3}}{\text{ I}}^{-}$ is shown below.

Figure 8

The structure of the nucleophile that could be used to convert the iodoethane to give ${\left({\text{CH}}_{\text{3}}\right)}_{\text{3}}\stackrel{\text{+}}{\text{N}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{3}}{\text{ I}}^{-}$ compound is shown below.

Figure 9

Conclusion

The structure of the nucleophile that could be used to convert the iodoethane to give ${\left({\text{CH}}_{\text{3}}\right)}_{\text{3}}\stackrel{\text{+}}{\text{N}}{\text{CH}}_{\text{2}}{\text{CH}}_{\text{3}}{\text{ I}}^{-}$ compound is shown in the Figure 9