Solutions for EBK THERMODYNAMICS, STATISTICAL THERMOD
Problem 2.1CP:
Electrical current is passed through a resistor immersed in a liquid in an adiabatic container. The...Problem 2.2CP:
Two ideal gas systems undergo reversible expansion under different conditions starting from the same...Problem 2.3CP:
You have a liquid and its gaseous form in equilibrium in a piston and cylinder assembly in a...Problem 2.5CP:
For a constant pressure process, H=qp. Does it follow that qp is a state function? Explain.Problem 2.6CP:
A cup of water at 278 K (the system) is placed in a microwave oven and the oven is turned on for 1...Problem 2.7CP:
In the experiments shown in Figure 2.4a and 2.4b, Usurrondings0, but Tsurrondings0. Explain how this...Problem 2.8CP:
What is wrong with the following statement? Burns caused by steam at 100C can be more severe than...Problem 2.10CP:
You have a liquid and its gaseous form in equilibrium in a piston and cylinder assembly in a...Problem 2.12CP:
Explain how a mass of water in the surroundings can be used to determine q for a process. Calculate...Problem 2.13CP:
A chemical reaction occurs in a constant volume enclosure separated from the surroundings by...Problem 2.15CP:
In the experiment shown in Figure 2.4b, the weight drops in a very short time. How will the...Problem 2.16CP:
Discuss the following statement: If the temperature of the system increased, heat must have been...Problem 2.17CP:
Discuss the following statement: Heating an object causes its temperature to increase.Problem 2.18CP:
An ideal gas is expanded reversibly and adiabatically. Decide which of q, w, U, and H are positive,...Problem 2.19CP:
An ideal gas is expanded reversibly and isothermally. Decide which of q, w, U, and H are positive,...Problem 2.20CP:
An ideal gas is expanded adiabatically into a vacuum. Decide which of q, w, U, and H are positive,...Problem 2.23CP:
A student gets up from her chair and pushes a stack of books across the table. They fall to the...Problem 2.24CP:
Explain why ethene has a higher value for CV,m at 800 K than CO.Problem 2.1NP:
A 3.75 mole sample of an ideal gas with Cv,m=3R/2 initially at a temperature Ti=298K and Pi=1.00 bar...Problem 2.2NP:
The temperature of 1.75 moles of an ideal gas increases from 10.2C to 48.6C as the gas is compressed...Problem 2.3NP:
A 2.50 mole sample of an ideal gas, for which Cv,m=3R/2, is subjected to two successive changes in...Problem 2.4NP:
A hiker caught in a thunderstorm loses heat when her clothing becomes wet. She is packing emergency...Problem 2.5NP:
Count Rumford observed that using cannon boring machinery a single horse could heat 11.6 kg of ice...Problem 2.6NP:
A 1.50 mole sample of an ideal gas at 28.5C expands isothermally from an initial volume of 22.5dm3...Problem 2.7NP:
Calculate q, w, U, and H if 2.25 mol of an ideal gas with Cv,m=3R/2 undergoes a reversible adiabatic...Problem 2.8NP:
Calculate w for the adiabatic expansion of 2.50 mol of an ideal gas at an initial pressure of 2.25...Problem 2.10NP:
A muscle fiber contracts by 3.5 cm and in doing so lifts a weight. Calculate the work performed by...Problem 2.11NP:
A cylindrical vessel with rigid adiabatic walls is separated into two parts by a frictionless...Problem 2.12NP:
In the reversible adiabatic expansion of 1.75 mol of an ideal gas from an initial temperature of...Problem 2.13NP:
A system consisting of 82.5 g of liquid water at 300. K is heated using an immersion heater at a...Problem 2.14NP:
A 1.25 mole sample of an ideal gas is expanded from 320. K and an initial pressure of 3.10 bar to a...Problem 2.15NP:
A bottle at 325 K contains an ideal gas at a pressure of 162.5103Pa. The rubber stopper closing the...Problem 2.16NP:
A 2.25 mole sample of an ideal gas with Cv,m=3R/2 initially at 310. K and 1.25105Pa undergoes a...Problem 2.18NP:
An ideal gas undergoes an expansion from the initial state described by Pi,Vi, T to a final state...Problem 2.19NP:
An ideal gas described by Ti=275K,Pi=1.10bar, and Vi=10.0L is heated at constant volume until...Problem 2.20NP:
In an adiabatic compression of one mole of an ideal gas with Cv,m=5R/2, the temperature rises from...Problem 2.21NP:
The heat capacity of solid lead oxide is given by CP,m=44.35+1.47103TKinunitsofJK1mol1 Calculate the...Problem 2.26NP:
A 2.50 mol sample of an ideal gas for which Cv,m=3R/2 undergoes the following two-step process: (1)...Problem 2.27NP:
A 2.35 mole sample of an ideal gas, for which Cv,m=3R/2, initially at 27.0C and 1.75106Pa, undergoes...Problem 2.29NP:
A nearly flat bicycle tire becomes noticeably warmer after it has been pumped up. Approximate this...Problem 2.32NP:
Consider the isothermal expansion of 2.35 mol of an ideal gas at 415 K from an initial pressure of...Problem 2.33NP:
An automobile tire contains air at 225103Pa at 25.0C. The stem valve is removed and the air is...Problem 2.34NP:
One mole of an ideal gas is subjected to the following changes. Calculate the change in temperature...Problem 2.36NP:
A pellet of Zn of mass 31.2 g is dropped into a flask containing dilute H2SO4 at a pressure of...Problem 2.37NP:
Calculate H and U for the transformation of 2.50 mol of an ideal gas from 19.0C and 1.00 atm to...Problem 2.38NP:
A 1.75 mole sample of an ideal gas for which CV,m=20.8JK1mol1 is heated from an initial temperature...Problem 2.41NP:
The Youngs modulus (see Problem P2.40) of muscle fiber is approximately 2.80107Pa. A muscle fiber...Browse All Chapters of This Textbook
Chapter 1 - Fundamental Concepts Of ThermodynamicsChapter 2 - Heat, Work, Internal Energy, Enthalpy, And The First Law Of ThermodynamicsChapter 3 - The Importance Of State Functions: Internal Energy And EnthalpyChapter 4 - ThermochemistryChapter 5 - Entropy And The Second And Third Laws Of ThermodynamicsChapter 8 - Phase Diagrams And The Relative Stability Of Solids, Liquids, And GasesChapter 14 - Ensemble And Molecular Partition FunctionsChapter 15 - Statistical Thermodynamics
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