Solutions for EBK THERMODYNAMICS, STATISTICAL THERMOD
Problem 1.1CP:
Real walls are never totally adiabatic. Use your experience to order the following walls in...Problem 1.2CP:
The parameter a in the van der Waals equation is greater for H2O than for He. What does this say...Problem 1.3CP:
Give an example based on molecule—molecule interactions excluding chemical reactions, illustrating...Problem 1.6CP:
The location of the boundary between the system and the surroundings is a choice that must be made...Problem 1.8CP:
At sufficiently high temperatures, the van der Waals equation has the form PRT/Vmb. Note that the...Problem 1.14CP:
The mass of a He atom is less than that of an Ar atom. Does that mean that because of its larger...Problem 1.2NP:
A compressed cylinder of gas contains 2.74103g of N2 gas at a pressure of 3.75107 Pa and a...Problem 1.3NP:
Calculate the pressure exerted by Ar for a molar volume of 1.31Lmol1 at 426 K using the van der...Problem 1.4NP:
A sample of propane C3H8 is placed in a closed vessel together with an amount of O2 that is 2.15...Problem 1.5NP:
A gas sample is known to be a mixture of ethane and butane. A bulb having a 230.0cm3 capacity is...Problem 1.6NP:
One liter of fully oxygenated blood can carry 0.18 liters of O2 measured at T=298K and P=1.00atm....Problem 1.7NP:
Yeast and other organisms can convert glucose C6H12O6 to ethanol CH3CH2OH by a process called...Problem 1.8NP:
A vessel contains 1.15 g liq H2O in equilibrium with water vapor at 30.C. At this temperature, the...Problem 1.9NP:
Consider a 31.0 L sample of moist air at 60.C and one atm in which the partial pressure of water...Problem 1.12NP:
A rigid vessel of volume 0.400m3 containing H2 at 21.25C and a pressure of 715103Pa is connected to...Problem 1.13NP:
A mixture of oxygen and hydrogen is analyzed by passing it over hot copper oxide and through a...Problem 1.14NP:
An athlete at high performance inhales 3.75L of air at 1.00 atm and 298 K. The inhaled and exhaled...Problem 1.15NP:
Devise a temperature scale, abbreviated G, for which the magnitude of the ideal gas constant is...Problem 1.16NP:
Aerobic cells metabolize glucose in the respiratory system. This reaction proceeds according to the...Problem 1.18NP:
A mixture of 2.10103g of O2, 3.88103mol of N2, and 5.251020 molecules of CO are placed into a vessel...Problem 1.21NP:
An initial step in the biosynthesis of glucose C6H12O6 is the carboxylation of pyruvic acidCH3COCOOH...Problem 1.23NP:
Assume that air has a mean molar mass of 28.9gmol1 and that the atmosphere has a uniform temperature...Problem 1.24NP:
When Julius Caesar expired, his last exhalation had a volume of 450.cm3 and contained 1.00 mole...Problem 1.25NP:
Calculate the number of molecules per m3 in an ideal gas at the standard temperature and pressure...Problem 1.27NP:
A mixture of H2 and NH3 has a volume of 139.0cm3 at 0.00C and 1 atm. The mixture is cooled to the...Problem 1.28NP:
A sealed flask with a capacity of 1.22dm3 contains 4.50 g of carbon dioxide. The flask is so weak...Problem 1.29NP:
A balloon filled with 11.50 L of Ar at 18.7C and 1 atm rises to a height in the atmosphere where the...Problem 1.30NP:
Carbon monoxide competes with oxygen for binding sites on the transport protein hemoglobin. CO can...Problem 1.31NP:
The total pressure of a mixture of oxygen and hydrogen is 1.65 atm. The mixture is ignited and the...Problem 1.32NP:
Suppose that you measured the product PV of 1 mol of a dilute gas and found that PV=24.35L atm at...Problem 1.33NP:
Liquid N2 has a density of 875.4kgm3 at its normal boiling point. What volume does a balloon occupy...Problem 1.34NP:
Calculate the volume of all gases evolved by the complete oxidation of 0.375 g of the amino acid...Problem 1.36NP:
A glass bulb of volume 0.198 L contains 0.457 g of gas at 759.0 Torr and 134.0C. What is the molar...Browse All Chapters of This Textbook
Chapter 1 - Fundamental Concepts Of ThermodynamicsChapter 2 - Heat, Work, Internal Energy, Enthalpy, And The First Law Of ThermodynamicsChapter 3 - The Importance Of State Functions: Internal Energy And EnthalpyChapter 4 - ThermochemistryChapter 5 - Entropy And The Second And Third Laws Of ThermodynamicsChapter 8 - Phase Diagrams And The Relative Stability Of Solids, Liquids, And GasesChapter 14 - Ensemble And Molecular Partition FunctionsChapter 15 - Statistical Thermodynamics
Book Details
Engel and Reid’s Thermodynamics, Statistical Thermodynamics, and Kinetics gives students a contemporary and accurate overview of physical chemistry while focusing on basic principles that unite the sub-disciplines of the field. The Third Edition continues
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