163_PS1_PartA_S24_1019
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Problem Set 1 - Ch 10 & 19 – Part A Purpose: Problem set 1 is a three part assessment of the learning objectives outlined for chapters 10 & 19. Students will be assessed on their ability to synthesize and apply the concepts covered in class, as well as recall information and reflect on their learning and problem solving strategies. Task: Students will work individually to complete all 3 parts of the assessment. Students may not work together, they may not work with tutors, and they may not use online resources outside the class resources posted on canvas. Part A:
This is a take home set of challenging questions that will require students to synthesize and apply the concepts covered in class. Part B:
This will be an in-class set of questions provided by the instructor to assess student’s ability to recall information used in Part A of the problem set. Part C:
This will be a set of reflection questions both about student’s problem solving strategies and their learning process. This part may include a class or small group discussion. Part A Evaluation: Students that attempt all questions in good faith for all parts of the problem set by the deadline will earn a Revise grade. Students that submit an assignment that meets the list of requirements below (or revise their work with instructor feedback to meet the requirements) will earn a Complete grade on the assignment. Problem Set 1 Part A Standards to Earn a Complete Grade Students attempt each question in good faith and revise questions with instructor feedback if requested. Short answer responses are formatted in complete sentences and paragraphs. Claims are supported by evidence with scientific reasoning. All work is shown for calculations. Student demonstrates a strong understanding of the material and is able to apply and synthesize the concepts covered. Student work may have small errors but does not show large gaps in knowledge. The student will answer 4/5
questions without significant errors. The student is able to answer recall questions about the concepts in the challenge questions and are able to discuss their responses to each question with the instructor if it is necessary to clarify their work.
1.
In the MC Escher painting below 3 boxes have been drawn and labeled A, B,
& C
. Which one represents the smallest unit cell
? Justify your answer with evidence (observations of the image) and scientific reasoning that includes a definition of “unit cell.” 2.
Calcium carbonate, the material shellfish shells are made of, can crystallize into two different unit cells, shown below. The green balls are Ca
+2
ions and the grey ball and red ball molecules are CO
3
-2
. Determine the chemical formula of calcite and aragonite from the unit cells above. Show all work. 3.
Lead and Tungsten are commonly used metals in fishing weights, in use they will have the same mass, but be different sizes, implying the density of the two metals are different. Compare the density of lead and tungsten using the information below. Will the lead or the tungsten fishing weight be smaller when they are the same mass (ex: 0.45 kg for off-shore fishing)? Lead: atomic radius of 0.175 nm Tungsten: atomic radius of 0.136 nm A
B
C
Lead unit cell: Tungsten unit cell: 4.
A chemist synthesizes a monomeric coordination compound with a chemical formula they believe to be [Fe(acac)(CO)
2
(NH
3
)Cl]Br
. “
acac
” is acetylacetonate: a.
Name the coordination compound. b.
Draw the complete coordination compound and label the complex ions, ligands, and counterion. Your image should be drawn in 3 dimensions. c.
Draw each of the listed isomers based on your drawing of the coordination compound in b
. i.
Coordination isomer ii.
Linkage isomer iii.
Geometric isomer (cis/trans or fac/mer) iv.
Optical isomer 5.
A coordination compound with a trigonal prismatic geometry is shown to the right. The xyz axis is shared to provide an orientation for the ligands relative to one another. Derive the d-orbital splitting diagram for the metal ion in the coordination compound. Be sure to distinguish between dz
2
, dx
2
-y
2
, dxy, dxz, and dyz orbitals and show your reasoning either as a short explanation or in drawings. Your answer will not be graded on the correctness of your diagram but rather your consistency in applying crystal field theory
. z
y
x
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Related Questions
26) The floor tiles in SE 27 are about 1 square foot and the lab is about 25 tiles wide and about
36 tiles from front to back. When the emergency shower was demonstrated, in 10. seconds
the water in the trash can was about 1 foot deep. One student estimated this was 2.5 gallons.
Estimate how deep the room will get in inches after a 15 minute shower. List 3 simplifving
assumptions you make in this calculation
rea
L-36 Tile
fiDw
ill it cost2 The density of gold is
27l An artist plans to apply gold leaf to a painting with an area of 2.32 f? and a thickness of 1.50
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Answer questions 1 and 2 according to the data given.
Dater Weight of cream i: 326 kỳ. Table shows some data
obtained directly from Lactascan instrument.
Fat % SNF % Lacto-
density
27.32
30.23
Raw milk 4.15 7.97
Skim milk 0.08 8.26
Q1. Calculate fat percent of creamn
A) 46 B) 28 (C) 3D D) 0.046
آدرما 396
100 x
Q2. Calculate efficiency of the cream separator.
A) 100%
B98%
C) 97%
D) 96%
E) 87.2%
amount
2500 L
E) 0.28
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The lab will analyze large samples for Cu. What instrument would you recommend purchasing to support this work, Atomic absorption spectrophotometer or an inductively coupled plasma atomic spectrophotometer? Explain the basis for your decision.
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B
NA
BH2 bh3
S =
6
6H
Calculator:
NA indicates
neutral axis
Section Modulus I Beam Universal
Calculator
For the next four questions (including this one)
ignore k and k1 in your calculations.
Using the same table, enter the value for B in
inches. (three sig figs)
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question 2 and 3 with detail and reasons for each question
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1-38. To entertain children between the ages of 2 and 90, I enjoy
popping corks from bottles containing vinegar and baking soda
pour about 50 mL of vinegar into a 500-mL plastic bottle. Then I
wrap about 5 g of baking soda (which is sodium bicarbonate,
NaHCO3) in one layer of tissue and drop the tissue into the bottle
I place a cork tightly in the mouth of the bottle and step back. The
chemical reaction generates CO2(g) that pressurizes the bottle and
eventually bursts the cork into the air. Everyone smiles.
I
CH2CO2HNaHCO3 >CH2CO2 + Na + CO2(g) H2O
Acetic acid
Sodium bicarbonate
in vinegar
in baking soda
(a) Find the formula mass of acetic acid and of sodium bicarbonate
(b) How many grams of acetic acid are required to react with 5 g of
NaHCO3?
(c) Vinegar contains ~5 wt% acetic acid. How many grams of vinegar
are required to react with 5 g of NaHCO3? The density of vinegar is
close to 1.0 g/mL. How many mL of vinegar are required to react
with 5 g of NaHCO3?
(d) Which is the limiting…
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STARTING AMOUNT
esc
C
X
C
2
F2
W
#
3
1000
F3
ADD FACTOR
x( )
$
4
1
97.9
FS
de in
%
5
2
Convert 23.4 kJ to calories
2.34 x 104
t
4184
kcal
6
P
0.001
J
4.184
COMEC
DOLL
ANSWER
&
7
9.79 × 104
cal
00
8
RESET
FO
2
23.4
(
5590
A
FIT
120
Jan 21
del
+
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Many common materials that we ingest, though quite safe in reasonable quantities, become toxic when taken in very large doses. A measure of toxicity is the LD50 value (Lethal Dose, 50%). It is the quantity of material, expressed in mg of material per kg of subject-body-weight that, if administered to a population of subjects, would cause 50% of the population to die. The LD50 value for FD&C Red Dye No. 40 is >10,000 mg/kg in rats. Assume that the LD50 value for humans is the same as for rats.
Calculate the number of mg of Allura Red present in an 9 fluid ounce glass of the beverage you used in this lab and use this calculation to determine the number of such glasses of Allura Red sports drink required to reach the LD50 of 10,000 mg of Allura Red/kg body weight. Assume that the concentration of Allura Red in the beverage is 0.000038 M and the person has a body weight of 175 lbs.
The molar mass of Allura Red is 496.42 grams/mol
1 fl oz = 29.5735 mL
2.205 lbs = 1 kg
You may assume…
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$
F4
An aqueous solution of 2.87 M hydrochloric acid, HCl, has a density of 1.05 g/mL.
The percent by mass of HCl in the solution is
%.
Submit Answer
%
5
T
G
F5
Retry Entire Group 9 more group attempts remaining
6
Cengage Learning | Cengage Technical Support
Y
H
[Review Topics]
[References]
Use the References to access important values if needed for this question.
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gilinent-take
F7
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DII
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9
F9
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deles
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CH₂-COOH
Citric acid has the formula HO-C-COOH
I
CH₂-COOH
CH2–CDD - Na*
+
HD-C-CDD- Na
CH₂-COO-
COO-Na
A 25.0 mL sample of a concentrated citrus fruit cordial component (e.g. for lime juice), used in the food & drinks industry, was
diluted to 250 mL in a graduated volumetric flask.
A 25.0 mL sample of this diluted solution, required, on average, 22.5 mL of a standard 0.100 molar sodium hydroxide solution
using phenolphthalein indicator for the titration end-point.
A) 0.0075
Assuming all the acid in the cordial was citric acid, calculate the concentration of the acid in g/mL in the original solution.
B) 0.576
D
and is tribasic acid, forming the tri-sodium salt
on complete neutralisation with sodium hydroxide.
1.44
0.00225
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I need answers for # 2-9 on this worksheet
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Please answer questions 3 and 4 and show work please. Thank you
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Explain your rationale for using the summative assessment (below) from the lesson plan on mixing substances in a 5th-grade classroom based on the below standard and learning objective, including how it aligns with the learning objective.
Summative Assessment
Summative:
Components of the Lab Report
Purpose: The student should clearly state the purpose of the experiment, which is to determine whether the mixing of two or more substances results in new substances.
Procedure: The student should describe the steps they took to conduct the experiment. This includes the substances they chose to mix and the safety equipment they used.
Observations: The student should record any observable changes that occurred when the substances were mixed. This could include a color change, the formation of a precipitate, or a change in temperature.
Conclusion: The student should state whether a new substance was formed based on their observations. They should also reflect on their accuracy in…
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Hey! Could you check these answers to make sure they are all correct? If they aren't, could you please help me to figure out what I did wrong?
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Absorbance (arb.units)
SA
8.3
B-Carotene Calibration Curve
2004
65,03UM
3.26 mM
5,06 nM
y=(105612 Mx-0.1736
2.94 M
4304 1064 ENY 181 121
Concentration (M)
1004
5
Abserbence (arb.units)
200
0.25
300
A student creates a standard curve of B-Carotene and plots the line of best fit. They then measure the
absorbance of a solution of B-Carotene with an unknown concentration. What is the concentration of
the sample? You can assume they used a cuvette with a pathlength of 1 cm.
400
500
600
Wavelength (nm)
YOU
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Q2. Two widely used pain relievers are aspirin and
acetaminophen (Tylenol). “Liquid” Children's Tylenol® is
simply acetaminophen suspended in fruit-flavored sugar
water with food coloring and an acid buffer. As you may
know, "children's medications" are big money makers
for pharmaceutical companies. Despite this fact, the
liquid form of Children's Aspirin is NOT commercially
available. CONCISELY explain why liquid Children's
Aspirin is not available (HINT: cannot be prepared!)
CH3
میں میں
aspirin
OH
HO
.NH–C
acetaminophen
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Please provide all answers in the spaces provided. All answers must be hand drawn using a pencil,
a pen, or an equivalent tablet device. Answers that are typed, drawn using templates, or pasted
from the Internet (!!!) will not be accepted. You should upload your problem sets into Gradescope
after scanning them with your phone or exporting your tablet drawings as a pdf file. You are strongly
encouraged to work in groups while completing this problem set, but each student must turn in their
own copy of the answers. Please let us know if you have any questions or need further instructions.
1. Provide the reagent(s) that would be required for each of the following synthetic
transformations. Please note that some of the reactions involve multiple steps. In cases where
relative stereochemistry is shown (i.e. wedges and dashes, E-or Z-alkenes, etc.), your reagents
should be selected to yield the correct isomer as the major product. You do not need to supply
any arrow pushing mechanisms, but…
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Related Questions
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