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CHM2132 DGD Assignment #6
•
One copy of your group’s solutions must be uploaded to Brightspace on your
Group page by 8 pm on Wednesday Nov 1st.
•
You must show your work to receive full credit.
•
Appropriate sig figs and units are required in the final answer.
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After the DGD, every student must record participation marks for each of their
group members using the link:
https://forms.gle/potADxGJB3oaHEM3A
•
Students who do not complete the form will not receive credit for participation
at that DGD.
1)
a) The enthalpy of fusion of mercury is 2.292 kJ/mol at its normal freezing point
of 234.3 K.
The density of mercury (
M
= 200.6 g/mol) is 13.69 g/cm
3
when liquid
and 14.184 g/cm
-3
when solid. What would be the freezing point at the bottom
of a 50.0 m column of mercury?
b) Will the melting point increase or decrease as more mercury is added to the
column?
2)
Suppose the vapour pressure of water in the atmosphere was found to be 525 Pa
on a fall morning when the temperature was -2.96
o
C.
Use a calculation to
predict whether frost would form under these conditions. You may need to use
some of the data below, and assume that the enthalpy values are temperature
independent.
3)
Consider a 2.650 L balloon filled with air in a room measuring 6.000 m x 4.000 m
by 5.000 m held at 23.6
o
C. What would be the Gibbs energy of mixing if the
balloon popped, releasing its air into the room?
Data for H
2
O
D
vap
H
o
m
= 40.656 kJ mol
-1
density = 0.9971 g/mL
Δ
fus
H
m
o
=
6.01 kJ mol
-1
C
p
,
m
o
l
( )
=
75.3 J K
-1
mol
-1
C
p
,
m
o
g
(
)
=
33.6 J K
-1
mol
-1
T
triple point
=
273.16 K
p
triple point
=
611.2 Pa
M
=
18.02 g mol
-1
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CH3CH2CH2CI
AICI 3
CH2CH2CH3
CH3CH2CCI
AICI3
Ова
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Group:,
H CH3
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Score:
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2 grams
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How does the quantization of energy explain the observed photoelectric effect and
emission of UV energy?
When light shines on a metal, electrons can be ejected from the surface of the
metal in “the photoelectric effect". Experiments showed that the wavelength of
light is inversely proportional to kinetic energy of the electrons ejected.
Identify the best explanation of the photoelectric effect.
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- what is the concentration of the unknown sample using serial diluitions: 0.05M 1.7472nm, 0.025M 0.8569nm, 0.0125M 0.4167nm, 0.00625M 0.1958nm the epsilon value is 0.0101 and l is 1 cmarrow_forwardReal life applications of standardization of NaOH.arrow_forwardRead and interpret the following information using the following abstract from a scientific journal article. In 2-3 sentences, summarize what you understand from this researcharrow_forward
- Firefox File Edit View History Bookmarks Tools Window Help my.CSMD.edu I Module 12 HW Chi wr NWP Assessme X De Module 9 HW Cha W NWP Assessment I Module 11 HW Che w NWP Assessment O 8 https://education.wiley.com/was/ui/v2/assessment-player/index.html?launchld=b0085ec6-77d3-4053-89d4-c26a8188beb3- E Module 12 HW Chapter 21 - Selected Exercises Question 5 of 8 -/1 E Starting with diethyl malonate, and using any other reagents of your choice, show how you would prepare the following compound: Fill 1) ? 2) ? Que Multi EtO 3)? 4) ? 5) ? Choose from the following list of reagents: OEt HO. Ques Multipa Questi A B D Multistep CH3Br LIAIH4 LDA NaOEt / EtOH Viewing Multipart Question E G H. Molecular Dra NaOH EtBr MgBr, H,O H20, heat heat Question 7 Multipart Question 8 Multistep MacBook Air esc F2 F3 F4 FS F10 @ 23 $ % & 1 2 3 4 7 8 W E R Y tab A S D F caps lock C V shift alt coms control option commandarrow_forwardYou work in a research organization that is looking for markers of various diseases that can be used as a diagnostic for the disease. It has been reported in the past that high levels of Cu are found in the sweat of people with cystic fibrosis. One of the research projects is focused on looking for high levels of Cu in samples that can be obtained non-invasively such as saliva, sweat, hair, nails, etc. The lab will analyze large samples for Cu. What instrument would you recommend purchasing to support this work, Atomic absorption spectrophotometer or an inductively coupled plasma atomic spectrophotometer? Explain the basis for your decision.arrow_forward00:40 A < 50 8 allall 85% Due Date for Submission: Friday, 25th October @ 4:06 PM UNIVERSITY OF PAPUA NEW GUINEA SCHOOL OF NATURAL AND PHYSICAL SCIENCES CHEMISTRY DISCIPLINE 1.10203 Chemistry 1B - Assignment No. 3 Please note that all assignments must be submitted in handwritten form; printed submissions will not be accepted. Additionally, ensure that you submit your work directly to your assigned tutor. Failure to do so will result in a zero mark. This process has been streamlined to prevent misplaced assignments and to avoid complaints at the end of the semester. If you have submitted your work to the wrong tutor, retrieve it and submit it to the correct one to avoid any penalties or issues later on. Name: ID#: 1. Study the following reactions and draw their reaction mechanisms A (a) (b) Edit < CH3CH2CH2CI AICI 3 CH2CH2CH3 CH3CH2CCI AICI3 Ова CH2CH3 Group:, H CH3 CH3 Score: Page 1 of 6 Annotate Fill & Sign Convert All Oarrow_forward
- Commun x Bb Blackboard Collaborate Ultra -2 X General Psychology-Fall 20 O X A ALEKS - Griffin Barden - Learn ww-awa.aleks.com/alekscgi/x/Isl.exe/1o_u-IgNslkr7j8P3jH-JcZzdcvSCzsqTCIDqNGV3bKqhMfPmUcQ4ENkmiXn9QCwgeDPDkQ06yszYWESPcekwL0-Qg619rekU7404HgFAGBEZaDr080?1oBw7QYjibavbSPXtx-YCjsh_7mMmrq#item O THERMOCHEMISTRY Griffin V Using Hess's Law to calculate net reaction enthalpy Nitric acid can be formed in two steps from the atmospheric gases nitrogen and oxygen, plus hydrogen prepared by reforming natural gas. In the first step, nitrogen and hydrogen react to form ammonia: N,(g) + 3 H,(g) → 2 NH3(g) AH=-92. kJ In the second step, ammonia and oxygen react to form nitric acid and water: NH3(g) + 20,(g) HNO3(g) H,O(g) AH=-330. kJ – + Calculate the net change in enthalpy for the formation of one mole of nitric acid from nitrogen, hydrogen and oxygen from these reactions. dla Round your answer to the nearest kJ. kJarrow_forwardWe are stuck on 9. We get how Q is 16 and rxn goes left. at eq 2+ x. 2 + x. -2 x We get x= 1. Therefore k = 4. Please help us. Questin 9. See conditions from 8 This is not a graded question as it is a practice question . I am 60 years old and helping my son prepare for the AP exam in a few months. We do questions at the back of the textbook by Zumdahl and Zumdahlarrow_forwardOnCourse Connect Assessment: Chemistry x Copy of spread_of_islar x = The Spread of Islam -G x M Inbox (904) - aarojame A Classes boncourseconnect.com/assessment/1651879/5287e2a3-0d0b-e2c0-c15c-3e68a37149b4 D TPSS Bookmarks CHEMISTRY BENCHMARK TEST 01 CHEMISTRY I 12-7 (AARON JAMES, ID: 12390724) A student dissolved 15 grams of pure acetic acid (CH,COOH) in enough water to make 100. milliliters of solution. Given the atomic masses provided on the periodic table, what is the molarity (M) of the acetic acid solution? a 0.025 molar D0.40 molar © 2.5 molar O 4 molar A B B 1 2 4 5 6 7 8 9 10 3. O Save/Exit 4 sn TESSarrow_forward
- G neural crest tissue - Google Sear x A CHM 112 112-1 and 112-E1 A Presentation Session Student + 8 https://app.peardeck.com/student/twkkhzvar For quick access, place your favorites here on the favorites bar. Manage favorites now Peardeck Exercises Use #3. Nitol6) + 3 Fa(6)Z NF(1) + 3 HF(G) [1: 5,0 x10°n 0.10M Calculat K 2.0M 3.5 x 10°M Pear Deck Interactive Slide Students, draw anywhere on this slide! Do not remove this bar Slide 1/2arrow_forwardЗа. Bromine and methanoic acid react in aqueous solution. Br, (aq) + HCO0Н (ад) — 2Br (aq) + 2H" (аq) + Со, (g) The reaction was monitored by measuring the volume of carbon dioxide produced as time progressed. o 5 10 15 20 25 [Source: © International Baccalaureate Organization 2019] 30 20 40 60 80 100 120 140 160 Time / s [Source: © International Baccalaureate Organization 2019] Determine from the graph the rate of reaction at 20 s, in cm³ s1, showing your working. 3b. Outline, with a reason, another property that could be monitored to measure the rate of this reaction. 3c. Describe one systematic error associated with the use of the gas syringe, and how the error affects the calculated rate. 3d. Identify one error associated with the use of an accurate stopwatch. Volume of carbon dioxide / cm T m mm moarrow_forwardTetrachloromethane(CC14)is accidentally spilled on a bench in the laboratory. Describe a safety clean-up procedure briefly. (Hint: MSDS and PPE)arrow_forward
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