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CHEM 2545 -Fall 2023
Lab 2: Characterization of Unknowns
Post-lab (65 pts total)
1.
Upload a copy of your notebook pages with your data/observations from this lab (as a pdf). (2 pts)
The next 3 questions of this post-lab will relate to your experimental data. Please refer to your notebook pages for values you recorded during lab. For full credit on the following questions, show all
calculations and include units.
2.
Liquid unknown number (1 pts): 74
Solid unknown number (1 pts): 87
4
3.
Please complete the following questions using the data obtained for your liquid unknown.
a.
Calculate density of your unknown liquid in g/mL. Show all steps of your calculations and include all/any units for full credit. (5 Pts)
Weight of vial w/o liquid : 5.225 g
Weight of vial with unknown liquid: 6.195g Volume 1 mL
6.195g - 5.225 g = 0.97 g
D=M/V
D= 0.97g /1mL
D= 0.97 g/mL
Density of your liquid unknown: 0.97 g/mL
b.
Use the equation in your manual (page 20) to calculate refractive index a 20°C. Show all steps of your calculations for full credit. (5 pts)
n
20
=n
T
+0.00045(T-20
oC
)
n
20
=1.426+0.00045*(23.1 -20)
n
20
=1.427
Refractive index of your liquid unknown: 1.427
c.
Boiling point of your liquid unknown (2 pts): 80
o
C
d.
Use the data given in your manual to identify your liquid unknown (4 pts): Cyclohexane
1
CHEM 2545 -Fall 2023
Lab 2: Characterization of Unknowns
Post-lab (65 pts total)
4.
Please complete the following questions using the data obtained for your solid unknown.
a.
Melting point of your solid unknown (2 pts): 135
o
C-136
o
C
b.
Which standard(s) did you use for mixed melting point (4 pts): trans-cinnamic acid
c.
Mixed melting point (2 pts): 133
o
C-136
o
C
d.
What is the identity of your solid unknown (4 pts): trans-cinnamic acid
e.
Calculate the percent weight recovery of your solid unknown. Show all steps of your calculations and include all/any units for full credit. (5 Pts)
The next two questions of this post-lab require you to understand the concepts related to this lab.
The lab manual is an excellent resource if you are having trouble with these questions. If you are
still unsure how to answer these questions (after reading the lab manual) seek help during TA
office/zoom hours.
5.
Read the description of dipole-dipole forces on page 9 of your lab manual. Polar molecules
experience permanent partial positive and partial negative charges. Use arrows (like the ones shown on page 9 of your manual) to show the direction of the net
dipoles in the following molecules. If there is no net dipole, circle the molecule (16 pts). The first one is shown as an example.
Hint: When drawing your arrows, think about electronegativity of each atom. The arrow
will point towards the location of the electron density.
2
CHEM 2545 -Fall 2023
Lab 2: Characterization of Unknowns
Post-lab (65 pts total)
6.
Three molecules are drawn below. Although they have similar molecular weights, their boiling points are very different. This is due to the differences in intermolecular forces present in each liquid (12 pts). In the table below, indicate (yes or no) if each of the intermolecular forces are present for each liquid.
Intermolecular Forces
Molecule A
Molecule B
Molecule C
Induced dipole- Induced dipole
Yes
Yes
Yes
Dipole-dipole
Yes
Yes
No
Hydrogen bonding
Yes
No
No
Ionic
No
No
No
3
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Spring 2023 CHEM 1411 14 General Chemistry I LAB
Experiment 2 Postlab
57 minutes remaining
Postlab Content
Page 3 of 6
Question 2
An object with a mass of 47.2 kilograms and a volume of 47.6 liters. Find the density with units of g/cm³. Report your answer
with three significant figures.
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MindTap-Cengage Learning X
ISBN 9781305657571&nbld=3576712&snapshotld-3576712&id=1854206...
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References
237 g
Use the References to access important values if needed for this question.
A copy of your chemistry textbook is found to have a mass of 2310 grams.
Using unit analysis, show what the mass of this copy of your chemistry textbook is in
ounces.
12 oz
7. Unit Conversion: Metric/Standard: This is group attempt 1 of 5
Autosaved at 11:14 PM
Oz
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28.3 g
2.20 lb
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Q Search this course
454 g
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A sample of gas occupies a volume of 381 mL at 1.26 atm and 99 °C. Calculate the temperature of the gas if its pressure is changed to 1.64 atm while its volume is held constant.
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Nitrogen dioxide and dinitrogen monoxide gases react to form nitrogen monoxide gas(es).
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2. Boil I L of distilled water for 5 min to expel CO2. Pour the water into a polyethylene
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affected if one did not boil the water (would the [NaOH] be higher, lower, or no change)? Please explain
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A 1.10 g sample of octane, C8H18, is combusted in a bomb calorimeter and the temperature rises by 62.0 °C. Given a Ccal value of 850.6 J/°C,
determine AUrxn per mol of octane.
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Ba(NO,l(aq) + K,SOlaq) Baso(s) + 2 KNOlaq)
Volume
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0.10 M K,SO, (ml)
Mass Baso4 (s)
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50.
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Use the data to identify the limiting reagent for each reaction performed.
V Trail 1
a. Neither/Both
EV Trial 2
b. Baso4
EV Trial 3
C. KSO4
EV Trial 4
d. Ba(NO3)2
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Why is the amount of precipitate in the Data Table above the same in Trials 3 through 5?
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A student added 5 grams of calcium chloride, a white solid substance, to 15 grams of water at 22° C. Several observations were made and
the student inferred that a chemical reaction occurred.
Which observation best supports the student's inference that a chemical reaction occurred?
O A. The calcium chloride dissolved in the solution,
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Categorize each as a determinate or an indeterminate error and further
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a) An unknown sample being weighed is hygroscopic.
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reacts with the column packing.
c) A radioactive sample being counted repeatedly without any change in
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d) The tip of the pipet used in the analysis is broken.
e) In measuring the same peak heights of a chromatogram, two
technician each report different heights.
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B Quizzes - SCH3UE-15-Chemistry- X
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In testing for the presence of lead(II) ions in solution, Jamaal adds a solution of
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Enter your answer in the provided box.
When potassium cyanide (KCN) reacts with hydrochloric acid, hydrogen cyanide (HCN), a poisonous
gas, is produced. The equation is
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Calculate the number of g of KCN that will react with 6.93 mol of HCI.
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1. Use the following Absorbance Data to generate a Bradford Assay Standard Curve.
Protein Concentration
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- & Spring 2023 CHEM 1411 14 General Chemistry I LAB Experiment 2 Postlab 57 minutes remaining Postlab Content Page 3 of 6 Question 2 An object with a mass of 47.2 kilograms and a volume of 47.6 liters. Find the density with units of g/cm³. Report your answer with three significant figures. Add your answer Questions Filter (5) 5 OF 5 QUESTIONS REMAINING K First Last > Continue Details & In PER Assessm 2/23/23 X ✓ • You after 76°F Time li 60 min Attem 2 atte Grading Saarrow_forwardplease answer the following with equations used and calculations.arrow_forwardMindTap-Cengage Learning X ISBN 9781305657571&nbld=3576712&snapshotld-3576712&id=1854206... A M req req O Search X Back 2310 g x My Grades-Fall 2023 TTU Introd X A Submit Answer References 237 g Use the References to access important values if needed for this question. A copy of your chemistry textbook is found to have a mass of 2310 grams. Using unit analysis, show what the mass of this copy of your chemistry textbook is in ounces. 12 oz 7. Unit Conversion: Metric/Standard: This is group attempt 1 of 5 Autosaved at 11:14 PM Oz Drag and drop your selection from the following list to complete the answer: 28.3 g 2.20 lb + () 16 oz Q Search this course 454 g Next 4x X C 11:14 10/8/2arrow_forward
- Sample Name: Test2 Acq. Operator : SYSTEM Sample Operator: SYSTEM Acq. Instrument : 6890N_GC-FID Injection Date Acq. Method Last changed : 11/11/2024 2:21:09 PM Location : 1 Inj Volume Manually : C:\CHEM32\1\METHODS \DEHYD351L.M : 11/8/2024 3:26:55 PM by SYSTEM Analysis Method : C:\CHEM32\1\METHODS\DEF_GC.M 11/12/2024 10:20:57 AM by SYSTEM FID1A, (CHEM351LITest2 2024-11-11 14-21-09.D) Last changed PA 1750 1500 1250 1000 750 500 250 0 1.226 1.338 1.393 1.445 1.513 0.2 0.4 0.6 0.8 1.2 1.4 1.6 1.8 min Area Percent Report Sorted By Multiplier : Signal 1.0000 Dilution 1.0000 Use Multiplier & Dilution Factor with ISTDS # [min] Signal 1: FID1 A, Peak RetTime Type Width ----|-------|----|-------|-------| Area [min] [PA*s] Height [PA] Area % |--------| 1 1.226 BB 0.0138 2.49083 2.96068 0.12408 2 1.338 BB 0.0173 6.06945 5.33509 0.30236 3 1.393 BV 0.0175 180.39203 156.04135 8.98645 4 1.445 VB 0.0147 17.87214 5 1.513 BB S 19.50680 0.89032. 0.0151 1800.55408 1899.02905 89.69679 Totals: 2007.37852…arrow_forwardW. Practice 4 - CHEM 1201 X co Course: 2020 Spring CHEM b My Questions | bartleby A https://www.webassign.net/web/Student/Assignment-Responses/randomize?pos=7&dep=22671454&tags=autosave#question359851_7 ... 8. 0/0 POINTS PREVIOUS ANSWERS 2/100 Submissions Used MY NOTES ASK YOUR TEACHER A sample of gas occupies a volume of 381 mL at 1.26 atm and 99 °C. Calculate the temperature of the gas if its pressure is changed to 1.64 atm while its volume is held constant. O a) The temperature is 108618.7 °C. O b) The temperature is -144.1 °C. O c) The temperature is 12.8 °C. O d) The temperature is 211.2 °C. O e) The temperature is 184203.6 °C. 9. 0/0 POINTS PREVIOUS ANSWERS 6/100 Submissions Used MY NOTES ASK YOUR TEACHER Nitrogen dioxide and dinitrogen monoxide gases react to form nitrogen monoxide gas(es). NO2(g) + N20(g) → 3 NO(g) At a certain temperature and pressure 18.4 L of NO, reacts with 18.4 L of N,0. If all the NO, and N20 are consumed, what volume of NO, at the same temperature and…arrow_forwardW. Practice 4 - CHEM 1201 X co Course: 2020 Spring CHEM b My Questions | bartleby A https://www.webassign.net/web/Student/Assignment-Responses/randomize?pos=1&dep=22671454&tags=autosave#question359689_1 ... 2. 0/0 POINTS PREVIOUS ANSWERS 5/100 Submissions Used MY NOTES ASK YOUR TEACHER Choose the answer which gives the electron-domain geometry and molecular geometry which are both correct for IF5 . O a) The electron-domain geometry is octahedral. The molecular geometry is square pyramidal. O b) The electron-domain geometry is trigonal bipyramidal. The molecular geometry is trigonal bipyramidal. O c) The electron-domain geometry is octahedral. The molecular geometry is trigonal bipyramidal. O d) The electron-domain geometry is trigonal bipyramidal. The molecular geometry is seesaw-shaped. O e) The electron-domain geometry is octahedral. The molecular geometry is seesaw-shaped. 3. 0/0 POINTS PREVIOUS ANSWERS 13/100 Submissions Used MY NOTES ASK YOUR TEACHER Choose the selection which…arrow_forward
- W Practice 4 - CHEM 1201 X co Course: 2020 Spring CHEM b My Questions | bartleby A https://www.webassign.net/web/Student/Assignment-Responses/randomize?pos=6&dep=22671454&tags=autosave#question359795_6 ... 7. 0/0 POINTS PREVIOUS ANSWERS 2/100 Submissions Used MY NOTES ASK YOUR TEACHER Choose the selection which gives the correct number of o and T bonds present in one molecule or ion of NO,. Make the central atom in your Lewis structure follow the octet rule if possible. O a) There are 1 o bonds and 2 T bonds in one molecule or ion of this substance. O b) There are 2 o bonds and 5 T bonds in one molecule or ion of this substance. O c) There are 3 o bonds and 5 T bonds in one molecule or ion of this substance. O d) There are 2 o bonds and 1 T bonds in one molecule or ion of this substance. O e) There are 2 o bonds and 2 T bonds in one molecule or ion of this substance. 8. 0/0 POINTS PREVIOUS ANSWERS 2/100 Submissions Used MY NOTES ASK YOUR TEACHER A sample of gas occupies a volume of 430…arrow_forwardPls help ASAP.arrow_forwardPlease help me solve these.arrow_forward
- ee X m Firefox Privacy Notice- Mozillax O Server Not Found New Tab O 8 https://mygmu.ac.ae/Imsnew/pluginfile.php/240960/mod_resource/content/1/1-Laboratory meas of 19 + Automatic 2 Practice • Perform the following conversions 1. 100 mg= %3D με ... 2. 20 1 = ..... ml 3. 2.5 kg = . g= ........ ..mg ....... . 4. 1000 ng = ......... ug %3D ...... ......... to search Sub- devision of basisarrow_forwardW Practice 4 - CHEM 1201 co Course: 2020 Spring CHEM b My Questions | bartleby A https://www.webassign.net/web/Student/Assignment-Responses/randomize?pos=0&dep=22671454&tags=autosave#question359495_0 ... TurmuJIgmmy you JuDTunoweTay qucJuon. TUuurc Chapters 9 & 10 required to use a new randomization after every 1 question submissions. O Description Assignment Scoring Your last submission is used for your score. 1. 0/0 POINTS PREVIOUS ANSWERS 2/100 Submissions Used MY NOTES ASK YOUR TEACHER Choose the correct total number of electron domains (bonding and nonbonding) about a central atom if the angle(s) between the electron domains have two different values, either about 90 or 180 degrees. O a) The central atom has 4 electron domains. O b) The central atom has 6 electron domains. O c) The central atom has 3 tron domains. O d) The central atom has 2 electron domains. O e) The central atom has 5 electron domains. 2. 0/0 POINTS PREVIOUS ANSWERS 5/100 Submissions Used MY NOTES ASK YOUR…arrow_forwardI said don't use Ai only solve accurate. Chemistry expert only . suggest to Chemistry experts okk. Solve accurate no ai okk take 5 hrs but solve accuratearrow_forward
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