310_07_211nmr_data_sheet_postlab
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NMR
DATA SHEET
NAME:
Section:
Unknown number: Attach your 1
H NMR obtained using the benchtop NMR equipment. Now use the standard NMR obtained on 500 MHz equipment provided by your instructor to finish the NMR data
analysis below: Draw the structure of your unknown below with all non-equivalent H’s labeled (a, b, etc.) for NMR identification.
Redraw the structure and assignments directly on the 1
H NMR spectrum, making sure the assignments also
match the table below. Label the peak(s) on the spectrum that corresponds to the NMR solvent used by writing the
solvent above it (them).
Complete the table below for the 1
H NMR spectrum. If necessary, use the expanded, online spectra for multiplicity
and coupling constants. For Identification
, use the same a, b, etc. that you used in your structure above. Do not
include the solvent peak in your table.
(ppm)
Multiplicity
Coupling Constant J (Hz)
Number of H’s
Identification
Sample calculations of chemical shift and coupling constant: 1 - NMR
Draw the structure of the unknown below with all non-equivalent C’s labeled (a, b, etc.) for NMR identification.
Redraw the structure and assignments directly on the 13
C NMR spectrum, making sure the assignments match
those in the table below. Label the peak(s) on the spectrum that corresponds to the NMR solvent used by writing
the solvent above it (them).
Complete the table below for the 13
C NMR Spectrum. For Identification
, use the same a, b, etc. that you used in
your structure above. Do not include the solvent peak in your table.
(ppm)
Identification
(ppm)
Identification
Post-lab Questions:
1.
The deuterated forms of the solvents below are common solvents for NMR. Commercially available
deuterated solvents normally have 99.0 ~ 99.96% deuterium, meaning trace amounts of non-deuterated
solvents are also present. What are the 1
H and 13
C chemical shifts produced by these residual solvents? Also,
trace amounts of water are often found in 1
H spectra taken in CDCl
3 and d6-DMSO. What is the chemical shift
of water in these solvents? Tables of these values can be found on line or in the lab. residual solvent
1
H
(ppm)
13
C
(ppm)
Water in …
1
H
(ppm)
CHCl
3
CHCl
3
DMSO
DMSO
CH
2
Cl
2
2 - NMR
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Related Questions
Give an analysis of Benzene NMR Spectrum
Questions:
Proton environment
How many types of proton environments are present?
How many different NMR signals would you expect?
Chemical Shift
Give the chemical shift:
Splitting pattern
Number of neighboring protons?
Number of lines expected?
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Please fill in the data similar to the example table down below.
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Part E
How many signals are in its 13C NMR spectrum?
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Br
Express your answer as an integer.
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Please show complete answer.
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of the NMR between 8-6.5 ppm has been magnified for easier viewing. (Hint: Draw resonance structures to
distinguish the benzene and alkene Hs.
1H
2H
1H
الس
2H
CHH
BH.
CH3
A
CH3 D
H3C
N
H
CH3 H
6H
6H
PPM
b) Draw a resonance that shows how you can differentiate the alkene hydrogens in the NMR. It is ok to have
more than one positive and negative charge for the resonance structures with a NO2 group.)
H
H3C-N
CH3
CH3
CH3
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Related Questions
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