310_07_211nmr_data_sheet_postlab

.doc

School

Northern Kentucky University *

*We aren’t endorsed by this school

Course

310L

Subject

Chemistry

Date

Dec 6, 2023

Type

doc

Pages

4

Uploaded by Lovely7812

Report
NMR DATA SHEET NAME: Section: Unknown number: Attach your 1 H NMR obtained using the benchtop NMR equipment. Now use the standard NMR obtained on 500 MHz equipment provided by your instructor to finish the NMR data analysis below: Draw the structure of your unknown below with all non-equivalent H’s labeled (a, b, etc.) for NMR identification. Redraw the structure and assignments directly on the 1 H NMR spectrum, making sure the assignments also match the table below. Label the peak(s) on the spectrum that corresponds to the NMR solvent used by writing the solvent above it (them). Complete the table below for the 1 H NMR spectrum. If necessary, use the expanded, online spectra for multiplicity and coupling constants. For Identification , use the same a, b, etc. that you used in your structure above. Do not include the solvent peak in your table. (ppm) Multiplicity Coupling Constant J (Hz) Number of H’s Identification Sample calculations of chemical shift and coupling constant: 1 - NMR
Draw the structure of the unknown below with all non-equivalent C’s labeled (a, b, etc.) for NMR identification. Redraw the structure and assignments directly on the 13 C NMR spectrum, making sure the assignments match those in the table below. Label the peak(s) on the spectrum that corresponds to the NMR solvent used by writing the solvent above it (them). Complete the table below for the 13 C NMR Spectrum. For Identification , use the same a, b, etc. that you used in your structure above. Do not include the solvent peak in your table. (ppm) Identification (ppm) Identification Post-lab Questions: 1. The deuterated forms of the solvents below are common solvents for NMR. Commercially available deuterated solvents normally have 99.0 ~ 99.96% deuterium, meaning trace amounts of non-deuterated solvents are also present. What are the 1 H and 13 C chemical shifts produced by these residual solvents? Also, trace amounts of water are often found in 1 H spectra taken in CDCl 3 and d6-DMSO. What is the chemical shift of water in these solvents? Tables of these values can be found on line or in the lab. residual solvent 1 H (ppm) 13 C (ppm) Water in … 1 H (ppm) CHCl 3 CHCl 3 DMSO DMSO CH 2 Cl 2 2 - NMR
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
  • Access to all documents
  • Unlimited textbook solutions
  • 24/7 expert homework help