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Jan 9, 2024
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NSB PRACTICE SETS
TOSS-UP
1) Energy
– Multiple Choice
SLAC National Accelerator Lab scientists are studying the
electrocyclic reactions that C
6
H
8
can undergo. Which of the following could NOT be
the identity of this molecule?
W) 1,3-cyclohexadiene
X) 1,4-cyclohexadiene
Y) 1,3,5-cyclohexatriene
Z) Hex-3-ene-1-yne
ANSWER: Y) 1,3,5-CYCLOHEXATRIENE
BONUS
1) Energy
– Short Answer
Department of Energy-supported researchers are studying
nitrogenase enzymes. What two metals are most commonly used to allow these enzymes to
function?
ANSWER: MOLYBDENUM AND IRON
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
2) Physics
– Short Answer
Consider two parallel current-carrying wires that are exerting a
magnetic force on one another. If the current in each wire were tripled, by what factor would the
force be multiplied?
ANSWER: 9
BONUS
2) Physics
– Short Answer
Vince is flying in his spaceship when he notices a 15-kilogram
probe experiencing an apparent 30-newton force in the same direction that he's traveling. He
then notices that his ship's thrusters are on, causing his spaceship to accelerate forward
at 3 meters per second squared. In newtons, what's the magnitude of the true net force acting
upon the probe?
ANSWER: 75
NSB practice sets
Page
1
TOSS-UP
3) Math
– Multiple Choice
Consider the polynomial equation:
.
12𝑥
3
− 11𝑥
2
+ 18 = 0
According to the rational root theorem, which of the following is NOT a possible rational root of
this equation:
W) -9
X) 1/9
Y) 9
Z) -9/2
ANSWER: X) 1/9
BONUS
3) Math
– Short Answer
The perimeters of two squares differ by 16 inches, and their areas
differ by 92 square inches. What's the perimeter in inches of the larger square?
ANSWER: 54
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
4) Biology
– Short Answer
What type of enzyme facilitates joining of DNA fragments whose
phosphodiester bonds have been broken by nucleases?
ANSWER: DNA LIGASE
BONUS
4) Biology –
Short Answer
Identify all of the following three statements that are true of
temperate phages: 1) They can replicate via the lytic cycle; 2) They can replicate via the
lysogenic cycle; 3) They can form a prophage.
ANSWER: ALL OF THEM
NSB practice sets
Page
2
TOSS-UP
5) Chemistry –
Short Answer
A sample of an ideal gas has a volume of one liter when its
pressure is 10 atmospheres. What will its volume be in liters when the pressure is reduced to 4
atmospheres?
ANSWER: 2.5
BONUS
5) Chemistry –
Multiple Choice
Which of the following statements is NOT true regarding
lattice energy?
W) Lattice energy is a measure of the energy contained in the crystal lattice of a compound
X) Lattice energy can be represented using a modified form of Coulomb’s law
Y) Lattice energy of a compound can be found by measuring the energy change involved in the
synthesis of the compound from gaseous ions of the component elements
Z) Sodium fluoride has a greater lattice energy than magnesium oxide
ANSWER: Z) SODIUM FLUORIDE HAS A GREATER LATTICE ENERGY THAN
MAGNESIUM OXIDE
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
6) Earth and Space –
Short Answer
To two significant figures, if a star's magnitude decreases
by one unit, by what number has its brightness been multiplied?
ANSWER: 2.5
BONUS
6) Earth and Space –
Short Answer
Identify all of the following 3 minerals that are
tectosilicates, or framework silicates: 1) Quartz; 2) Amphibole; 3) Garnet.
ANSWER: 1 ONLY
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3
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TOSS-UP
7) Energy –
Short Answer
Researchers at Brookhaven National Lab are using the STAR
detector to track particles in collisions of heavy nuclei. What phase of matter involving particles
of subunit charge is formed when these nuclei collide at high energies?
ANSWER: QUARK-GLUON PLASMA
BONUS
7) Physics –
Short Answer
What effect is observed when a potential difference across a
conductor causes a current flow perpendicular to the direction of an applied magnetic field,
resulting in an induced electric field?
ANSWER: HALL EFFECT
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
8) Math –
Short Answer
A pair of 12-sided dice, each with the numbers 1 through 12 printed
on the faces, is rolled. What's the probability that the two numbers rolled are different?
ANSWER: 11/12
BONUS
8) Math –
Short Answer
In the expansion of the cube of the binomial: 2A - 3B, what is the
coefficient of the A squared B term?
ANSWER: -36
NSB practice sets
Page
4
TOSS-UP
9) Earth and Space –
Multiple Choice
Which of the following rock composition changes
could not describe a magma that is cooling and undergoing differentiation?
W) Peridotite to gabbro
X) Peridotite to diorite
Y) Granite to gabbro
Z) Diorite to granite
ANSWER: Y) GRANITE TO GABBRO
BONUS
9) Earth and Space –
Short Answer
In the Norwegian cyclone model, cold-type and
warm-type are classes of what type of front?
ANSWER: OCCLUDED
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
10) Biology –
Short Answer
Aside from ATP, what other high-energy intermediate is
produced through glycolysis?
ANSWER: NADH
BONUS
10) Biology –
Multiple Choice
Jan is choosing a type of microscopy to resolve objects in her
sample that are 0.2 nanometers apart. Which of the following types of microscopes should she
use?
W) Differential interference contrast
X) Fluorescence
Y) Transmission electron
Z) Super-resolution
ANSWER: Y) TRANSMISSION ELECTRON
NSB practice sets
Page
5
TOSS-UP
11) Physics –
Short Answer
PET, or Positron Emission Tomography, is a type of imaging
that relies on two gamma rays being emitted in opposite directions. This is generated through
what process?
ANSWER: ANNIHILATION
BONUS
11) Physics –
Short Answer
Identify all of the following three statements that are true of the
work done by a conservative force: 1) Work is independent of the path taken; 2) Work is
sometimes irreversible; 3) If an object returns to its starting point, the total work done is zero.
ANSWER: 1 AND 3
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
12) Chemistry –
Short Answer
What's the IUPAC name for the simplest alkyne?
ANSWER: ETHYNE
BONUS
12) Chemistry –
Short Answer
Identify all of the following three statements that are true
of the heat capacity for all ideal gasses: 1) Heat capacity is independent of temperature; 2) A
diatomic ideal gas will have a higher heat capacity than a monatomic ideal gas; 3) CP is higher
than CV.
ANSWER: ALL OF THEM
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TOSS-UP
13) Biology –
Short Answer
What nematode commonly used as a model organism is
characterized by occurrence of exactly 131 instances of apoptosis during its development?
ANSWER: C. ELEGANS
BONUS
13) Biology –
Short Answer
If a tall pea plant with purple flowers is crossed with a short pea
plant with white flowers, and it is assumed that purple flower color is dominant to white flower
color and tall height is dominant to short height, what is the probability that their offspring will
be tall plants with white flowers?
ANSWER: 3/16
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
14) Energy –
Short Answer
Scientists at Oak Ridge National Lab are using neutron scattering
to study the structure of long, filamentous structures that compose most of the fungal body.
What's the term for these structures?
ANSWER: HYPHAE
BONUS
14) Energy –
Multiple Choice
Researchers at Fermilab have recently been studying weakly
interacting massive particles, or WIMPs. These hypothetical particles are leading candidates for
which of the following?
W) Superconductor charge carriers
X) Dark matter particles
Y) Neutrino decay products
Z) Gravitational field excitations
ANSWER: X) DARK MATTER PARTICLES
NSB practice sets
Page
7
TOSS-UP
15) Earth and Space –
Multiple Choice
A star is burning neon. As a result, which of the
following elements is this star most likely to be producing?
W) Helium
X) Magnesium
Y) Iron
Z) Carbon
ANSWER: X) MAGNESIUM
BONUS
15) Earth and Space –
Short Answer
Sometimes the two different stars in a binary system
cannot be resolved, but the light emitted by the system has two obviously different spectra
superimposed. What's the term for this type of binary system?
ANSWER: SPECTRUM BINARY
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
16) Physics –
Multiple Choice
Which of the following conditions could describe an unstable
equilibrium but not a stable equilibrium?
W) The potential energy is zero
X) The first derivative of potential energy with position is zero
Y) The second derivative of potential energy with respect to position is positive
Z) The second derivative of potential energy with respect to position is negative
ANSWER: Z) THE SECOND DERIVATIVE OF POTENTIAL ENERGY WITH RESPECT TO
POSITION IS NEGATIVE
BONUS
16) Physics –
Short Answer
Follow a hollow pipe that is open on one end and closed on the
other. The second overtone will have a frequency that is what multiple of the fundamental
frequency?
ANSWER: 5
NSB practice sets
Page
8
TOSS-UP
17) Chemistry –
Short Answer
What molecule is the acid anhydride of carbonic acid?
ANSWER: CO2
BONUS
17) Chemistry –
Short Answer
You empirically determine the mass percent of carbon in a
pure sample is 80% plus or minus 10%. Identify all of the following three molecules that satisfy
this condition: 1) C2H6; 2) C3H8; 3) C6H6.
ANSWER: 1 AND 2
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
18) Math –
Short Answer
What is the partial derivative with respect to Y of the expression:
X to 5th, Y to 8th?
ANSWER: 8X^5, Y^7
BONUS
18) Math –
Short Answer
What's the polynomial with least degree, real coefficients and
leading coefficient one that has (-7, -9i) as a zero?
ANSWER: X^2 + 14X + 130
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TOSS-UP
19) Biology –
Short Answer
Damaged organelles can be broken down in vesicles through
what lysosomal process?
ANSWER: AUTOPHAGOCYTOSIS
BONUS
19) Biology –
Short Answer
In the Hershey-Chase experiment, sulfur-35 was used to label the
proteins in bacteriophages. Into which two amino acids were these labels incorporated?
ANSWER: CYSTEINE AND METHIONINE
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
20) Chemistry
–
Short Answer
What's the electrochemical quantity used to measure the
tendency of a substance to gain electrons?
ANSWER: REDUCTION POTENTIAL
BONUS
20) Chemistry –
Multiple Choice
Which of the following is the reason why BCl3 cannot
dimerize to form B2Cl6 but AlCl3 can dimerize to form Al2Cl6?
W) Chlorine is not capable of forming three center, two electron bonds with boron
X) Boron does not possess d-electrons to participate in bonding, but aluminum does
Y) Boron does not have enough valence electrons to form four bonds, but aluminum does
Z) Boron’s small atomic radius does not allow it to accommodate the chlorine atoms
ANSWER: Z) BORON’S SMALL ATOMIC RADIUS DOES NOT ALLOW IT TO
ACCOMMODATE THE CHLORINE ATOMS
NSB practice sets
Page
10
TOSS-UP
21) Earth and Space –
Multiple Choice
Which of the following best describes why gasses like
hydrogen and helium can escape Earth's atmosphere while gasses like oxygen and nitrogen do
not?
W) Hydrogen and helium are primarily produced in the upper atmosphere
X) Hydrogen and helium have a higher average velocity
Y) Hydrogen and helium are less abundant in the atmosphere
Z) Hydrogen and helium are not involved in as much biogeochemical reactions
ANSWER: X) HYDROGEN AND HELIUM HAVE A HIGHER AVERAGE VELOCITY
BONUS
21) Earth and Space –
Multiple Choice
Changes in which of the following properties are
responsible for most major seismic wave discontinuities in the Earth's interior?
W) Pressure
X) Temperature
Y) Mineral phase
Z) Convection velocity
ANSWER: Y) MINERAL PHASE
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
TOSS-UP
22) Math –
Short Answer
What is the area of a triangle with vertices at the three points with
coordinates (1,4), (1,7) and (9,8)?
ANSWER: 12
BONUS
22) Math –
Short Answer
Four 10-sided dice, each with the numbers 1 through 10 printed on
the face, are rolled. What is the probability that at least two of the numbers rolled are the same?
ANSWER: 62/125
NSB practice sets
Page
11
TOSS-UP
23) Physics –
Multiple Choice
Which of the following is the best description of
bremsstrahlung?
W) Splitting of atomic energy levels in the presence of a magnetic field
X) Radiation emitted due to the deceleration of charged particles
Y) State of matter compared of bosons cooled to temperatures close to absolute zero
Z) Random motion of particles suspended in a medium
ANSWER: X) RADIATION EMITTED DUE TO THE DECELERATION OF CHARGED
PARTICLES
BONUS
23) Physics –
Short Answer
Rank the following three materials at standard temperature and
pressure in order of increasing dielectric constant: 1) Air; 2) Liquid benzene; 3) Glass.
ANSWER: 1, 2, 3
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The reaction of 3-methylene-1-cyclohexene and HBr yields the four products shown in the attachment. Which two are formed at high temperatures and which two are formed at low temperatures? Why? Why is 1-bromo-3-methylenecyclohexane not formed?
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4
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6
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H-CH3
H3C H
Br
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(2S,3S)-2-bromo-3-methylpentane
O (2R,3S)-2-bromo-3-methylpentane
(1R, 2S)-1-bromo-1,2-dimethylbutane
(1S,2R)-1-bromo-1,2-dimethylbutane
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1) 1-bromohexane 2) 3-bromo-3-methyl-pentane
4) 3-bromo-2-methylpentane
3) 1-bromo-2,2-dimethylbutane
5) 2-bromo-3-methylpentane
Choose the alkyl halide(s) from the above list of C6H13Br isomers that meet each criterion below:
a) the compound(s) that can exist as enantiomers
b) the compound(s) that can exist as diastereomers
c) the compound that gives the fastest SN2 with sodium methoxide
d) the compound that is least reactive to sodium methoxide in methanol
e) the compound(s) that give only one alkene during E2
f) the compound(s) give an E2 but no SN2 reaction with sodium methoxide in methanol
g) the compound(s) that undergo SN1 reaction to give products with shifts
h) the compound that gives the fastest SN1 reaction
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Assign a systematic (IUPAC) name for the following compound:
(Z)-3,3,4,5-tetramethyl-4-heptene
(E)-3,3,4,5-tetramethyl-4-heptene
(E)-3,4,5,5-tetramethyl-3-heptene
O (Z)-3,4,5,5-tetramethyl-3-heptene
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H3C
OH
The alcohol above can be classified as
and is named
secondary, cyclopentanol
O tertiary, 1-methylphenol
secondary, cyclopentanol
tertiary, 1-methylcyclopentanol
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Thionyl choride, SOCl2, is a reagent commonly used to convert the –OH group of an alcohol to a better leaving group. What is the formal charge on S in this molecule?
A) +2
B) +1
C) 0
D) -1
E) -2
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B₂H6(g) + 3 O2(g) →B2O3(s) + 3 H₂O(g)
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N,N-diethyl-m-toluamide (DEET) is the active ingredient in many insect repellent preparations. Following is one of the steps in its synthesis. In the box below draw the structure of the product of this reaction.
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• You do not have to consider stereochemistry.
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cis-3-hexene
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CH3 CH3
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0
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[F
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CH3
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NO2
H2SO4
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•
Apply formal charges to any nitro groups.
•
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•
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?
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Draw a structural formula for the major organic product of the following reaction:
CH2C2
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opy aste
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what kind of isomers are the following pairs
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Name the following cycloalkene:
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O 1,6-Dimethyl-1,3-cyclohexadiene
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I and III
B
II and III
C
III and IV
D
I and IV
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There are two alkenes that react with HBr to give 1-bromo-1-methylcyclohexane.
Draw their structures.
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Can someone show the movement of atoms when finding the product?
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Draw a structural formula for the major organic product of the following reaction:
CH₂Cl₂
Br₂
Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring.
. Do not show stereochemistry in other cases.
If enantiomers are formed, just draw one.
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000 - IF
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Draw a structural formula for the product formed upon hydroboration/oxidation of the alkene below.
CH3CH2
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Related Questions
- The reaction of 3-methylene-1-cyclohexene and HBr yields the four products shown in the attachment. Which two are formed at high temperatures and which two are formed at low temperatures? Why? Why is 1-bromo-3-methylenecyclohexane not formed?arrow_forwardDraw the structures for the compoundarrow_forwardStart with the cyclohexene at the top of the page. You have a bank of structures below that you can use below. There are more structures in the bank than you need some of the structures in the bank are unnecessary, and some may belong in some of the unlabelled boxes. Which structure belongs in each of the numbered boxes? 1 4 LIAIH4 NaCN 1) SOCI₂ 2) NH₂ HBr 5 6 1) Mg 2) CO2 3) H3O+ CH3OH H* NBS hv LIAIH4 2 thi PCC NaOH NH₂ H* 2) LIAIH4 1) Na 2) 3 7 Tarrow_forward
- Draw the line bond structures for the following alkenes, cyclic alkenes, and alkynes: Can you explain to me about this part A) noncyclic alkenes that contain 4 carbon atoms (3 possible), please? Can you explain to me about this part B) cyclic alkenes that contain 4 carbon atoms (4 possible), please? Can you explain to me about this part C) alkynes that contain 4 carbon atoms (2 possible, neither of them is a cyclic alkyne), please?arrow_forward5arrow_forwardName the following molecule. CH₂CH3 H-CH3 H3C H Br (2R, 3R)-2-bromo-3-methylpentane (2S,3S)-2-bromo-3-methylpentane O (2R,3S)-2-bromo-3-methylpentane (1R, 2S)-1-bromo-1,2-dimethylbutane (1S,2R)-1-bromo-1,2-dimethylbutanearrow_forward
- 3- Answer the following questions based on your understanding of organic reactions: 1) 1-bromohexane 2) 3-bromo-3-methyl-pentane 4) 3-bromo-2-methylpentane 3) 1-bromo-2,2-dimethylbutane 5) 2-bromo-3-methylpentane Choose the alkyl halide(s) from the above list of C6H13Br isomers that meet each criterion below: a) the compound(s) that can exist as enantiomers b) the compound(s) that can exist as diastereomers c) the compound that gives the fastest SN2 with sodium methoxide d) the compound that is least reactive to sodium methoxide in methanol e) the compound(s) that give only one alkene during E2 f) the compound(s) give an E2 but no SN2 reaction with sodium methoxide in methanol g) the compound(s) that undergo SN1 reaction to give products with shifts h) the compound that gives the fastest SN1 reactionarrow_forwardAssign a systematic (IUPAC) name for the following compound: (Z)-3,3,4,5-tetramethyl-4-heptene (E)-3,3,4,5-tetramethyl-4-heptene (E)-3,4,5,5-tetramethyl-3-heptene O (Z)-3,4,5,5-tetramethyl-3-heptenearrow_forwardH3C OH The alcohol above can be classified as and is named secondary, cyclopentanol O tertiary, 1-methylphenol secondary, cyclopentanol tertiary, 1-methylcyclopentanolarrow_forward
- Thionyl choride, SOCl2, is a reagent commonly used to convert the –OH group of an alcohol to a better leaving group. What is the formal charge on S in this molecule? A) +2 B) +1 C) 0 D) -1 E) -2arrow_forward1) Find AH for the synthesis of B₂H6, diborane: 2B(s) + 3H2(g) → B₂H6(g) Given: 2 B(s) + 1/2O2(g) → B2O3(s) B₂H6(g) + 3 O2(g) →B2O3(s) + 3 H₂O(g) H2(g) + 1/2O2(g) → H₂O(1) H₂O(1)→ H₂O(g) AH₁ = -1273 kJ/mole AH₂=-2035 kJ/mole AH3= -286 kJ/mole 44 kJ/mole AH4=arrow_forwardN,N-diethyl-m-toluamide (DEET) is the active ingredient in many insect repellent preparations. Following is one of the steps in its synthesis. In the box below draw the structure of the product of this reaction. MgBr H3C 0 ▾ + 1. CO₂ 2. H3O+ • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Draw the Grignard reagent as a covalent magnesium bromide. n [ ]# product ChemDoodleⓇ 28arrow_forward
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