1. Listed below are the n" ionization energies for a carbon atom. The units are megajoules per mole. IE: IE2 2.35 MJ/mol IE3 IE4 IES IEG 1.09 4.62 6.22 37.83 47.28 MJ/mol MJ/mol MJ/mol MJ/mol MJ/mol (a) Convert each ionization energy into ev for an individual atom rather than MJ for a mole of atoms. (b) Explain the large jump in ionization energy from IE, to IEs. Use electron configurations in your explanation. (c) How much energy (in eV) is needed to remove all the electrons from a carbon atom?

Principles of Modern Chemistry
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Chapter4: Introduction To Quantum Mechanics
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Problem 39P: Chapter 3 introduced the concept of a double bond between carbon atoms, represented by C=C , with a...
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1. Listed below are the n" ionization energies for a carbon atom. The units are megajoules per mole.
IE:
IE2
IE3
IE4
IES
IEG
1.09
2.35
4.62
6.22
37.83
47.28
MJ/mol
MJ/mol
MJ/mol
MJ/mol
MJ/mol
MJ/mol
(a) Convert each ionization energy into eV for an individual atom rather than MJ for a mole of atoms.
(b) Explain the large jump in ionization energy from IE, to IEs. Use electron configurations in your
explanation.
(c) How much energy (in eV) is needed to remove all the electrons from a carbon atom?
(d) The negative value of the energy in (c) can be viewed as the ground-state energy of a carbon atom.
How does it compare to previous estimates of the carbon atom using the sum of hydrogenic energies
with a full nuclear charge AND also the effective nuclear charges that depend on the subshell? Report
those values from your previous assignment and compare.
(e) Electron affinity is usually defined for a neutral atom, but consider what is the electron affinity for the
c* cation?
Transcribed Image Text:1. Listed below are the n" ionization energies for a carbon atom. The units are megajoules per mole. IE: IE2 IE3 IE4 IES IEG 1.09 2.35 4.62 6.22 37.83 47.28 MJ/mol MJ/mol MJ/mol MJ/mol MJ/mol MJ/mol (a) Convert each ionization energy into eV for an individual atom rather than MJ for a mole of atoms. (b) Explain the large jump in ionization energy from IE, to IEs. Use electron configurations in your explanation. (c) How much energy (in eV) is needed to remove all the electrons from a carbon atom? (d) The negative value of the energy in (c) can be viewed as the ground-state energy of a carbon atom. How does it compare to previous estimates of the carbon atom using the sum of hydrogenic energies with a full nuclear charge AND also the effective nuclear charges that depend on the subshell? Report those values from your previous assignment and compare. (e) Electron affinity is usually defined for a neutral atom, but consider what is the electron affinity for the c* cation?
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I. E.  I. E. (MJ/mol)
IE1 1.09
IE2 2.35
IE3 4.62
IE4 6.22
IE5 37.83
IE6 47.28
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