2ClO2 (aq) + 2OH- (aq) --> ClO3- (aq) + ClO2- (g) + H2O (l) [ClO2]o (M) [OH-]o (M) Initial Rate (M/s) 1. 0.0500            0.100          5.75*10^-2 2. 0.100              0.100           2.30 *10^-1 3. 0.100              0.0500        1.15*10^-1  a) What is the generic rate law for this reaction? b) What is the order for each reactant? What is the order for the overall reaction? c) What is the complete rate law for this reaction? d) If the initial concentrations were as follows, [ClO2]o = 0.25 M and [OH- ]o = 0.095 M, what would the initial rate be?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 13QRT
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             2ClO2 (aq) + 2OH- (aq) --> ClO3- (aq) + ClO2- (g) + H2O (l)

[ClO2]o (M)

[OH-]o (M)

Initial Rate (M/s)

1. 0.0500            0.100          5.75*10^-2

2. 0.100              0.100           2.30 *10^-1

3. 0.100              0.0500        1.15*10^-1 

a) What is the generic rate law for this reaction?

b) What is the order for each reactant? What is the order for the overall reaction?

c) What is the complete rate law for this reaction?

d) If the initial concentrations were as follows, [ClO2]o = 0.25 M and [OH- ]o = 0.095 M, what would the initial rate be?

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