3. The nicotinamide coenzymes (see Fig. 13-24) can undergo reversible redox reactions with specific substrates in the presence of the appropriate redox enzyme. In these reactions NADH + H* serves as the hydrogen source as described in problem 1 above. In the reactions below, IF a redox change has occurred balance the reaction with the necessary amounts of NAD*, NADH, H* and H20. The objective is to recognize when a redox enzyme is necessary in a metabolic reaction. (adapted from Problem 5, chapter 16) (a) CH,CH,OH CH,- Ethanol Acetaldehyde (d) CH, + co, OPo; OH CH,-C-C `OPo}- OPo; OH CH,-C-C Pyruvate Acetate (b) + HPO он (e) оос— сн, —с— соо- -оос — сн, — с—соо- 1,3-Bisphosphoglycerate Glyceraldehyde 3-phosphate H Oxaloacetate Malate CH,-C-C CH,- + co, (c) (f) сн, — с— сн, — с + H* сн, — с—сн, + со, Pyruvate Acetataldehyde Acetoacetate Acetone

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ISBN:9781947172517
Author:Matthew Douglas, Jung Choi, Mary Ann Clark
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Chapter6: Metabolism
Section: Chapter Questions
Problem 7RQ: Which of the following comparisons or contrasts between endergonic and exergonic reactions is false?...
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3. The nicotinamide coenzymes (see Fig. 13-24) can undergo reversible redox reactions with specific substrates
in the presence of the appropriate redox enzyme. In these reactions NADH + H* serves as the hydrogen source
as described in problem 1 above. In the reactions below, IF a redox change has occurred balance the reaction
with the necessary amounts of NAD+, NADH, H* and H2O. The objective is to recognize when a redox enzyme
is necessary in a metabolic reaction. (adapted from Problem 5, chapter 16)
(a)
CH,CH,OH
CH,
H.
Ethanol
Acetaldehyde
(d)
CH,-
CH,
+ co2
OPO OH
OPo? OH
сH, — с —с
`OPO;-
Pyruvate
Acetate
(b)
CH,-C-C
+ HPO?
он
TH.
H.
(e) -оос— сн, —с— соо-
-оос— сн, — с — соо-
1,3-Bisphosphoglycerate
Glyceraldehyde 3-phosphate
H
Oxaloacetate
Malate
(c)
сH, — с —с
сн, —с
+ co2
сH, — с — сн-
+ H*
+ CH,- C-CH; + Co,
(f)
Pyruvate
Acetataldehyde
Acetoacetate
Acetone
Transcribed Image Text:3. The nicotinamide coenzymes (see Fig. 13-24) can undergo reversible redox reactions with specific substrates in the presence of the appropriate redox enzyme. In these reactions NADH + H* serves as the hydrogen source as described in problem 1 above. In the reactions below, IF a redox change has occurred balance the reaction with the necessary amounts of NAD+, NADH, H* and H2O. The objective is to recognize when a redox enzyme is necessary in a metabolic reaction. (adapted from Problem 5, chapter 16) (a) CH,CH,OH CH, H. Ethanol Acetaldehyde (d) CH,- CH, + co2 OPO OH OPo? OH сH, — с —с `OPO;- Pyruvate Acetate (b) CH,-C-C + HPO? он TH. H. (e) -оос— сн, —с— соо- -оос— сн, — с — соо- 1,3-Bisphosphoglycerate Glyceraldehyde 3-phosphate H Oxaloacetate Malate (c) сH, — с —с сн, —с + co2 сH, — с — сн- + H* + CH,- C-CH; + Co, (f) Pyruvate Acetataldehyde Acetoacetate Acetone
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