A water sample was tested for water hardness. A 50.00 mL sample, prepared and buffered to pH 10, required 23.55 mL of 0.0250 M EDTA. A second 50.00 mL aliquot, prepared with NaOH, was titrated with 14.53 mL of the same EDTA solution. Calculate the total hardness of the water sample, express in ppm CaCO3 Calculate the concentration of CaCO3 in the sample in ppm Calculate the concentration of MgCO3 in the sample in ppm а. b. С.

A water sample was tested for water hardness. A 50.00 mL sample, prepared and buffered to pH 10, required 23.55 mL of 0.0250 M EDTA. A second 50.00 mL aliquot, prepared with NaOH, was titrated with 14.53 mL of the same EDTA solution. Calculate the total hardness of the water sample, express in ppm CaCO3 Calculate the concentration of CaCO3 in the sample in ppm Calculate the concentration of MgCO3 in the sample in ppm а. b. С.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter17: Complexation And Precipitation Reactions And Titrations

Section: Chapter Questions

Problem 17.29QAP

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A water sample was tested for water hardness. A 50.00 mL sample, prepared and buffered to pH 10, required 23.55 mL of 0.0250 M EDTA. A second 50.00 mL aliquot, prepared with NaOH, was titrated with 14.53 mL of the same EDTA solution. a. Calculate the total hardness of the water sample, express in ppm CaCO3
c. An EDTA solution is standardized against high-purity CaCO3 by dissolving 0.3982 g CaCO3 in hydrochloric acid, adjusting the pH to 10 with ammoniacal buffer, and titrating. If 38.26 mL was required for the titration, calculate the molarity of the EDTA. (Molecular weight EDTA = 292.24 g mol-1)
A 5.00 mL tap water sample was measured out with a volumetric pipette, and added to a 25 mL Erlenmeyer flask. It was then titrated with a 0.0100 M Na2EDTA.2H2O solution, and found to take 0.635 mL of the EDTA solution to reach the blue endpoint. a.) How many moles of the 0.0100 M Na2EDTA.2H2O were added in the titration reaction? Show calculation. b.) How many moles of calcium ions were reacted?
The concentration of a solution of EDTA was determined by standardizing against a solution of Ca2+ prepared from the primary standard CaCO3. A 0.4025 g sample of CaCO3 was transferred into a 250 mL Erlenmeyer flask and the pH adjusted by adding 5 mL of a pH 10 NH3-NH4Cl buffer containing a small amount of Mg2+EDTA. After adding calmagite as a visual indicator, the solution was titrated with the EDTA requiring 42.36 mL to reach the end point. Report the molar concentration of the titrant.
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A 0.3045 g of CaCO3 primary standard was dissolved using concentrated HCl, evaporated to incipient dryness and quantitatively transferred to a 250 mL volumetric flask, and diluted to mark. A 10 mL of aliquot was then transferred to an Erlenmeyer flask, together with 5mL buffer and 5 drops of EBT indicator, and was used to standardize the EDTA titrant. The solution turned blue after the addition of 24.10 mL of EDTA. A blank correction was performed and was determined to be 0.4 mL. What is the concentration of EDTA obtained (MW CaCO3 = 100.0869 g/mol)?
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