100 mL of mineral water containing Mg2+ and Ca2+ is taken and titrated with 86.65 mL of 0.06120 M EDTA. NH4F was added to the second 100 mL portion taken from the mineral water to mask the magnesium in the sample as MgF2, and when this sample was titrated with the same EDTA solution, 38.56 mL was spent. Find the concentration of CaCO3 and MgCO3 in the sample in ppm

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.20QAP
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100 mL of mineral water containing Mg2+ and Ca2+ is taken and titrated with 86.65 mL of 0.06120 M EDTA. NH4F was added to the second 100 mL portion taken from the mineral water to mask the magnesium in the sample as MgF2, and when this sample was titrated with the same EDTA solution, 38.56 mL was spent. Find the concentration of CaCO3 and MgCO3 in the sample in ppm.
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