(a) What are the requirements that should be met for a precipitation reaction to serve as the basis of a gravimetric method? 1. (b) What is "digestion"? In what ways can digestion improve the quality of an analytical precipitate? (c) A typical thermogravimetric curve for magnesium oxalate (MgC204) precipitates is given below. 18 134 226 398 478 900 Temperature, °C Describe the weight loss as a function of temperature. Select a suitable ignition temperature for the gravimetric analysis of magnesium. Explain your choice. i. Predict the possible composition of the residues collected at the chosen temperature. ii. Weight, g

(a) What are the requirements that should be met for a precipitation reaction to serve as the basis of a gravimetric method? 1. (b) What is "digestion"? In what ways can digestion improve the quality of an analytical precipitate? (c) A typical thermogravimetric curve for magnesium oxalate (MgC204) precipitates is given below. 18 134 226 398 478 900 Temperature, °C Describe the weight loss as a function of temperature. Select a suitable ignition temperature for the gravimetric analysis of magnesium. Explain your choice. i. Predict the possible composition of the residues collected at the chosen temperature. ii. Weight, g

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter13: Titrations In Analytical Chemistry

Section: Chapter Questions

Problem 13.5QAP

See similar textbooks

Similar questions

What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.
It is required to know the concentration of an aqueous solution of H2SO4 that appeared in the laboratoryChemistry III and it's unlabeled. To this end, a student of analytical chemistry carried out the followingProcedure: He took 5.00 mL of a fresh and standardized solution of 0.525M NaOH and brought them to a250.0 mL balloon to be completed with distilled water. Subsequently, he poured 15.00 mL of the solutionH2SO4 of unknown concentration in an Erlenmeyer flask and added 2 drops of phenolphthalein.Using a burette filled with the last NaOH solution, he noticed that when adding 39.40 mL of the hydroxidethe Erlenmeyer solution reached a faint but permanent pink. With the above dataDetermine the concentration and pH of the H2SO4 solution.
Do you agree/disagree with the following statement below? State your reasons. "Classical precipitation gravimetric analysis is best used towards the end of quantitative analysis while classical volumetric analysis is best used as the first technique to quantify analytes."
As part of a soil analysis on a plot of land, a scientist wants to determine the ammonium content using gravimetric analysis with sodium tetraphenylborate, Na+B(C6H5)4−. Unfortunately, the amount of potassium, which also precipitates with sodium tetraphenylborate, is non‑negligible and must be accounted for in the analysis. Assume that all potassium in the soil is present as K2CO3 and all ammonium is present as NH4Cl. A 5.095 g soil sample was dissolved to give 0.500 L of solution. A 150.0 mL aliquot was acidified and excess sodium tetraphenylborate was added to precipitate both K+ and NH4+ ions completely. B(C6H5)4-+K+⟶KB(C6H5)4(s) B(C6H5)4-+NH4+⟶NH4B(C6H5)4(s) The resulting precipitate amounted to 0.269 g. A new 300.0 mL aliquot of the original solution was made alkaline and heated to remove all of the NH4+ as NH3. The resulting solution was then acidified, and excess sodium tetraphenylborate was added to give 0.129 g of precipitate. Find the mass percentages of NH4Cl and…
The following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mL
While working in a metal processing facility, Letlen had accidentally mixed two metal vatstogether creating an alloy. One vat was labeled for cadmium, while the other was not. It canbe assumed that these are of pure metal composition. To identify this metal, Letlen took 1.000 g of the homogenous alloy sample composed ofcadmium and the unknown metal, dissolved, and diluted it to exactly 100.0 mL in avolumetric flask. A 20.00-mL aliquot was taken and titrated this using 22.82 mL of 0.05000M EDTA. In a second 20.00-mL aliquot, the Cd was masked through the addition of HCN/NaCN buffer.The titration of the unknown metal in the aliquot required 15.13 mL of EDTA.MW: Cd (112.411 g/mol) a. Calculate the moles of Cd and the moles of unknown metal in the 20.00-mL aliquot.b. Calculate the moles of Cd and the moles of unknown metal in the sample.
Solubility tests of benzoic acid with a dissolution enthalpy of -32kJ / mol were performed at 2 different temperatures. In the first experiment carried out at 27 ° C, 5 mL of the sample taken from the benzoic acid solution is taken into 25 mL of water and titrated with 0.02M NaOH. As a result of the titration, there is a consumption of 8 mL, respectively. In the second experiment performed at a different temperature under the same conditions, 22 mL was consumed. Taking advantage of these results a) Solubility of benzoic acid at 27 ° C .................................................; b) solubility of benzoic acid at different temperature ................................................; c) second test temperature ....................................................... (M (benzoic acid): 122.12 g / mol) Note: enter only required numerical values and units in the spaces in the question.
The Ksp for silver chromate (Ag2CrO4) is 1.1x10-12. Using the same initial set up of 10mL of 1M silver nitrate is combined with 25mL of 0.1M sodium chromate, what is the mass of the silver chromate precipitate in grams?
The chloride in the sample is to be determined gravimetrically by precipitating and weighing AgCl. What weight in grams of sample should be taken so that the percentage of Cl is obtained by simply multiplying the weight of the AgCl precipitate by 10?
I am only confused on part D of this problem. I understand that the 10g of A will dissolve completely and begin to precipitate at approx. 55 degrees celsius, but do not understand how to find the grams precipitated.
Calculate the gravimetric factor of the following. 2 Fe3O4 is sought(Analyte), 3 Fe2O3 is weighed (Precipitate)
How is Qsp affected when adding in excess reagent during a precipitation?