According to Werner's postulate, the sum of the primary and secondary valences in the compound hexaaminecobalt(III) oxalate is.

Q: Questions regarding tetrahedral geometry. a) Pretend low-spin cases are possible for tetrahedral…

A: Solution for the (a) part: In the complex [Fe(N)(PR3)3]+, the oxidation state of iron is +3 and it…

Q: The compound [Ni(NH3)½C12] is paramagnetic and does not exhibit structural or geometric isomerism,…

A: It is given that [Ni(NH3)2Cl2] is paramagnetic and doesn't exhibit isomerism So, it must be…

Q: 1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO]…

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Q: . Explain why compounds of Sc3+ are colorless, but compounds ofTi3+ are colored?

A: Color of d-block compounds are generally coloured due to d-d transitions

Q: (c) Design syntheses of (i) cis and (ii) trans isomers of [PtCl₂(CN)(NH3)], using K₂PtCl4, KCN and…

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Q: Predict the structure of I(CF3)Cl2. Do you expect the CF3 group to be in an axial or equatorial…

A: Generally the groups which are more electronegative will occupy the axial position while depicting…

Q: Q3. Draw the d-orbital splitting diagrams of the central metal ions in a. Heptacyanoosmate(IV) b.…

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Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Hybridization is the process of mixing up of atomic orbitals to give new orbitals, hybrid orbitals.…

Q: 7. MO Diagram. Consider the molecule [Cr(CO)6]²*. e) bonding (nb), and antibonding (*) orbitals,…

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Q: Give the total number of isomers with the formula [PtCl3Br3]2−.   total isomers:

A: We have to determine  the total number of isomers with the formula [PtCl3Br3]2−.

Q: 28. The three "d" orbitals that have higher energy in an octahedral field c) dz2 and dx2 - y2 a) dxy…

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Q: 26. The molecular shape of the atoms in PCla1 is best described as (A) tetrahedral (C) see-saw (B)…

A: The shape of the molecule can be predicted with the help of the VSEPR theory. The shape is predicted…

Q: Consider a d8 compound (like Pt(II)). What is more likely to form a 4-coordinate or a 6-coordinate…

A: Valence Bond Theory (VBT) Crystal Field Theory (CFT) Considers formation of covalent bonds…

Q: Both ions A2+ (Z=28) and B2+ (Z=46) can coordinate with the same types of ligands (X and Y) to form…

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Q: Consider a d8 compound [like Pt(II)]. What is more likely to form a 4-coordinate or a 6-coordinate…

A: The crystal field splitting of d8 is-

Q: 2. Which of the following pair of complexes will have the lowest average CO IR stretching frequency.…

A: Concept: If there are more electron donating ligands in the complex, the more electron rich the…

Q: Count up the 18-electron rule of the organometallic complex (Ferrocene) using covalent counting…

A: Since you have posted with multiple questions, we will solve first question for you. If you want the…

Q: Predict the structure of the following. Indicate the direction of distortions from the regular…

A: Structure :

Q: Include pi-bonding in the MO-scheme for O, complexes 1) How many vectors will you use. 2) Work out…

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Q: (c) Please illustrate the orbital overlap that describes "back-bonding" transition metal M–CO…

A: Metal carbonyls are complexes, that involves CO as the ligand. They have both σ and π character.

Q: 1 R3P" d. Consider complex 1. i. Draw a molecular orbital (MO) energy level diagram to describe the…

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Q: For each pair of molecules below, choose the one you would predict to be more stable and briefly…

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Q: true or false ?  The flowing compound is the amino acid glycine that contains glycinate bidentate…

A: The glycinate ion H2NCH2CO2- is formed by deprotonation of the amino acid glycine can function as a…

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s?3d6 Cdº: [Kr]5s²4d10 Pt0:…

A: Option D; All of the above

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s²3d6 Cdº: [Kr]5s²4d10 Ptº:…

A: A multiple choice question based on coordination complex, which is to be accomplished.

Q: a) Trialkylphosphine and ammonia are both strong-field ligands. However, experimental data show that…

A: Solution for a, PR3 ligands cause higher Δo than the NH3 because PR3 is σ-donor as well as…

Q: (d). When the bidentate neutral ethylenediamine (en, -NH2CH2CH2NH2-) reacts with Co(lII) chloride,…

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Q: The organometallic chemistry of magnesium and zinc is often considered to be very similar. However,…

A: Answer - Organometallic compound - Organometallic compounds are defined as compounds containing a…

Q: Q5 Below are the Period 4 transition metals. Indicate on the table: a) the element that forms an…

A: 18 electron rule  The 18 electron rule is used primarily for prediction and rationalizing formula…

Q: 3) The molecule [CuFaJK, has a unique structure (due to jahn-teller distortion) where it has an…

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Q: 7. a. Which has higher stability: the complex between Li' and NH3 or the complex betweer K* and NH3?…

A: Given: stability of the complex between Li+ and NH3 or the complex between K + and NH3  solubility…

Q: The frequency of the symmetrical M-O stretching vibration of the octahedral aqua ions [M(OH2)6]2+…

A: Answer i) Acidity of Octahedral aqua complex is due to the pull of electron density in :O-H2 by…

Q: 1: Rank and explain your ranking of the following chlorides of group 15 in the order of increasing…

A: A question based on general chemistry that is to be accomplished.

Q: What are the applications or importance of tris (butadiene) molybdenum?

A: Since you have asked multiple questions, we will solve the first one for you. For remaining…

Q: The compound X2Y is only partially dissociated in water solution to form X+ and Y2- ions. A 0.0100 m…

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Q: Draw a complete molecular orbital diagram for 1,3,5,7-octatetraene including: Labeled y-axis. MO…

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Q: When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing 2-coordinate Cu2…

A: Given: When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing…

Q: 3.3. Study the following pairs of compounds, in each case state the type of isomerism exhibited by…

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Q: Explain the Simonini reaction with example.

A: Simonini reaction: The synthesis of aliphatic ester from two equivalents of silver carboxylate and…

Q: 3. (a) Based on the compound, deca-1,3,5,7,9-pentaene: (0) Give the total number of TT molecular…

A: Frontier molecular orbital theory is most widely used in Pericyclic reactions. The FMO analysis is…

Q: For the penta-1,3-denyl anion, draw the molecular orbitals and the MO diagram. Identify the orbitals…

A: Penta-1,3-dienyl anion contains 2 double bonds and one negative charge charge in conjugation, hence…

Q: (a) What coordination geometries could [AuI4]− take and how might it differ from the [AuCl4]− ion?

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Q: (c) The authors determined the C-C bond lengths and the Si-C-C bond angles in the acetylene ligand…

A: We have to tell among the given two complexes which one has the stronger π back bonding with the…

Q: Draw the hybridization for the metal centre of the complex below

A: According to Valence bond theory: Electrons in a molecule occupy atomic orbitals rather than…

Q: raw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Since you have posted more than 1 question, we are doing 1st one for you. To do the rest repost the…

Q: a. Identify the molecules and highlight all electron dense areas with yellow. b. Encircle all…

A: Interpretation: a. To identify and highlight the electron dense areas with yellow. b. Encircle…

Q: واجب بيتي: اي عضوية فلزية؟ Which of the following are organometallic co Cr(CD), , PdHMe,Br WMe,,…

A: Substance which has minimum one metal carbon bond , is called organometallic compound.  Thus to…

Q: Propose a model complex structure for vitamin B12 (draw and give a name to complex) and explain in…

A: Vitamin B-12 is also called as cyanocobalamin. It is an important vitamin for the formation of…

Q: 1. Use specific examples, convincingly explain, and using your own words the differ- ence between…

A: Configurational isomers are type of stereoisomers which can not be converted to one…