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- A sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCl and NaCl weighing 0.1801 g. These chlorides are dissolved in H2O, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.1000N KCNS, with ferric alum as indicator. Calculate the percentage of K2O in the silicate.Phase Behavior of Elemental Gallium: Gallium (Ga) is one of the few metals that is liquid near room temperature (Tm = 302 K). a) The vapor pressure for Ga has been measured at 100 Pa at 1620 K and 10 kPa at 2125 K. What is the average metal-metal bond strength (in kJ/mol) for Ga assuming a liquid state coordination number of 6? b) What is the boiling point ( in K) for Ga in a standard lab at sea-level given the above information10.11/ A 1.5-kg specimen of a 90 wt% Pb-10 wt% Sn alloy is heated to 250°C (480°F), at which temperature it is entirely an a-phase solid solution . The alloy is to be melted to the extent that 50% of the speci- men is liquid, the remainder being the a phase. This may be accomplished either by heating the alloy or changing its composi- tion while holding the temperature con- stant. (a) To what temperature must the speci- men be heated? (b) How much tin must be added to the 1.5-kg specimen at 250°C to achieve this state? 10.15) A magnesium-lead alloy of mass 5.5 ka consists of a solid a phase that has a compo- sition that is just slightly below the solubility limit at 200°C (390°F). (a) What mass of lead is in the alloy? (b) If the alloy is heated to 350°C (660°F). how much more lead may be dissolved in the a phase without exceeding the solubility limit of this phase? 10.27 A hypothetical A-B alloy of composition 55 wt% B-45 wt% A at some temperature is found to consist of mass…
- For a Copper-Nickel (Cu-Ni) alloy of composition 25 wt % Ni and 75 wt % Cu at 1200 OC (Point B), refer to the phase diagram provided in Figure 2 and answer the following. (i) What is composition of liquid phase? (ii) What is composition of solid phase? (iii) What fraction of the system is liquid for a 25% Ni alloy at 1250 OC? (iv) What fraction of the system is solid for a 25% Ni alloy at 1250 OC?In a system ABC, a ternary alloy with composition of 30 wt. % B and 30 wt. % C consists at a particular temperature of three phases of equilibrium compositions as follows:Liquid phase: 50 % A, 40 % B, 10 % Calfa solid solution: 85 % A, 10 % B, 5 % Cbeta solid solution: 10 % A, 20 % B, 70 % Ca. Plot the composition of the alloy.b. Calculate the proportion by weight of liquid, and present in this alloy.c. For the same temperature, find the composition of the alloy which will consist of equal proportion of and phases of the compositions stated above, but with no liquid phase.(d) By using the data provided below, calculate the PillingBedworth ratio for the nickel (Ni) – nickel oxide (NiO) system and determine whether NiO is protective against corrosion. Atomic mass of nickel = 58.7 g.mol-1 Density of nickel = 8.91 Mg.m-3 Molecular mass of nickel oxide = 74.7 g.mol-1 Density of nickel oxide = 6.67 Mg.m-3 (e) A stainless steel pressure vessel that has fracture toughness, K1C, of 197 MN.m-3/2 is going to be exposed to a stress of 398 MN.m-2 . By using this information explain how designers can determine the thickness of the vessel so that catastrophic failure can be avoided.
- Pyrite (FeS2) is often roasted to obtain sulfur dioxide for making sulfuric acid. Consider the roasting reactionFeS2 + O2 = Fe2O3 + SO2Stoichiometric exercises:a) Formulate the correct stoichiometric roasting reaction Calculate, in respect to 1 t of pyrite, the stoichiometric amounts ofb) Oxygen required for roasting (in m3) c) Obtained hematite by-product (in t) d) Sulfur dioxide produced (in m3) Thermodynamic considerations:e) Calculate the reaction enthalpy ∆Ho298 for the above roasting reaction (in MJ/t of pyrite) Mind you: Requested is the reaction enthalpy per 1 t of pyrite! f) State whether the reaction is exo- or endothermic and say why. g) Calculate the actual change of entropy ∆So298 in J/(mol K) and explain why it is positive or negativewhat wt. of limestone containing 9.57% Mg must be taken for analysis in order to precipitate of 0.551g Mg2P2O7? how many grams of Na2SO4 are required to ppte Ag2SO4 from 2.000t of AgNO3? a sample of magnetite (impure Fe3O4) weighing 0.5000g is fused with oxidizing flux and the ferric compound formed is eventually precipitated as ferric hydroxide and ignited to ferric oxide which weighs 0.4980calculate %Fe & %Fe2O3Given the solubility of ferrihydrite (Fe(OH)3) and goethite (FeOOH), with dissolution reactions shown below: [1] Fe(OH)3 3 H+ à Fe3+ + 3 H2O Ksp = 8.4 x 10^4 ∆ Gr0 = -28 KJ/mol Solubility of Fe(OH3) = 7.468 [2] FeOOH + 3 H+ à Fe3+ + 2 H2O Ksp = 8.8 x 10^-2 ∆ Gr0 = 6 KJ/mol Solubility of FeOOH = 0.353 QUESTION: [A] How much Fe3+ from ferrihydrite would dissolve at pH 2 ? [B] How much Fe3+ from ferrihydrite would dissolve at pH 7 ? [C] How much Fe3+ from goethite would dissolve at pH 2 ? [D] How much Fe3+ from goethite would dissolve at pH 7 ?
- A scientist was tasked to extract Fe from an aqueous suspension that contains 106 g of Fe2O3. The following steps detail the transformation of Fe2O3 (aq) to elemental iron: I. Enough sulfur trioxide gas was bubbled to Fe2O3 aqueous suspension to completely yield ferric sulfate. II. Then, 5.00 M nitric acid was added to ferric sulfate yielding an aqueous solution of ferric nitrate. III. Excess magnesium powder was added to the aqueous solution of ferric nitrate precipitating the solid iron ----- a. Write the balanced chemical reaction and the type of chemical reaction for [I], [II], [III]. Do not forget to indicate the states of the reactants and products (s, l, g).(CHOICES: COMBINATION, SINGLE DISPLACEMENT, DOUBLE DISPLACEMENT) b. What is the final mass of iron? Express final answers in 3 significant figures. c. High-concentration HCl is supposed to be added at the last part of the procedure. Briefly state its purpose.A 90 wt% Ag-10 wt% Cu alloy is heated to a temperature within the β + liquid phase region. If the composition of the liquid phase is 85 wt% Ag, determine:(i) The temperature of the alloy(ii) The composition of the β phase(iii) The mass fractions of both phases1. What are the practical implications of alloying in carbon and alloy steels? 2. Make use of drawings of segments of the Fe-Cr phase diagram to illustrate the reason for the existence offerritic, martensitic and austenitic stainless steels by also noting the influence of specific alloying elementswhere-applicable. .