An experiment was performed in a similar manner as Experiment 4 (The Hydrolysis of t-Butyl Chloride). The following data was obtained: Total Time (s) Volume NaOH Titrant used (mL) 46 2.01 91 3.97 131 5.98 175 8.03 220 10.00 266 11.99 311 14.01 357 15.97 401 17.98 450 20.02 Final Volume NaOH to fully react sample: 85.01 mL Assume the proposed reaction mechanism in the experimental procedure is correct. Based on the above measurements, how many minutes would it take for the solution to reach 81.0% completion? Round your final answer to two decimal places.

An experiment was performed in a similar manner as Experiment 4 (The Hydrolysis of t-Butyl Chloride). The following data was obtained: Total Time (s) Volume NaOH Titrant used (mL) 46 2.01 91 3.97 131 5.98 175 8.03 220 10.00 266 11.99 311 14.01 357 15.97 401 17.98 450 20.02 Final Volume NaOH to fully react sample: 85.01 mL Assume the proposed reaction mechanism in the experimental procedure is correct. Based on the above measurements, how many minutes would it take for the solution to reach 81.0% completion? Round your final answer to two decimal places.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when...

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An experiment was performed in a similar manner as Experiment 4 (The Hydrolysis of t-Butyl Chloride). The following data was obtained: Total Time (s) Volume NaOH Titrant used (mL) 0 0.00 49 1.99 103 4.00 164 6.00 216 8.00 267 10.02 319 11.97 381 14.01 437 15.99 483 17.97 540 20.00 Final Volume NaOH to fully react sample: 87.68 mL Assume the proposed reaction mechanism in the experimental procedure is correct. Based on the above measurements, how many minutes would it take for the solution to reach 84.0% completion? Round your final answer to two decimal places.
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Penicillin is hydrolyzed and thereby rendered inactive by penicillinase, an enzyme present in some resistant bacteria. The mass of this enzyme in Staphylococcus aureus is 29.6 kd. The amount of penicillin hydrolyzed in 1 minute in 10 ml solution containing 10–9 g of purified penicillinase was measured as a function of the concentration of penicillin. Assume that the concentration of penicillin does not change during the assay. [Penicillin] µM Amount hydrolyzed (nanomoles) 1 0.11 3 0.25 5 0.34 10 0.45 30 0.58 50 0.61 a) Plot V0 versus [S] and 1/V0 1/[S]. Does penicillinase appear to obey Michaelis-Menten kinetics? b) What is the value of KM? c) What is the value of Vmax? d) What is the turnover number of penicillinase under these conditions? (This is the question I need help…
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Penicillin is hydrolyzed and thereby rendered inactive by penicillinase, an enzyme present in some resistant bacteria. The mass of this enzyme in Staphylococcus aureus is 29.6 kDa. The amount of penicillin hydrolyzed in 1 minute in a 10 mL solution containing 10.9 g of purified penicillinase was measured as a function of the concentration of penicillin. Assume that the concentration of penicillin does not change appreciably during the assay. Note that kiloDalton is the unit for MW for biological molecules. A Dalton is another name for atomic mass unit. For example, a protein with a mass of 15 kDa means that the MW is 15,000 g/mol.Penicillin (M) Amount hydrolyzed (nanomoles)1 0.113 0.255 0.3410 0.4530 0.5850 0.611. Plot Vo versus [S] for these data. Does penicillinase appear to obey Michaelis-Menten kinetics? If…
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