Calculate AG (at 298K) for the reaction: 2CR2+ (aq) + 2H+ (aq) 2 2C13+ (aq) + H2 (g) At pH = 2.5 (pH = -log[H*]) and in which [Cr2*] = [Cr3+]=1.0 M; and E of Cr3+/Cr2+ = -0.41 V Hints: 1. Search for # of e- involved in the reaction 2. Determine [H*] with pH value given I 3. Calculate the cell potential Ecut with the Nerst equation 4. Use equation 1 to calculate AG energy

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter23: Potentiometry
Section: Chapter Questions
Problem 23.23QAP: The following cell was found to have a potential of —0.492 V: Ag|AgCl(sat’d)||HA(0.200 M),NaA(0.300...
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Calculate AG (at 298K) for the reaction:
2Cr2+ (aq) + 2H+
(aq)
2 2C13+
+ H2 (g)
(aq)
At pH = 2.5 (pH =-log[H*]) and in which [Cr2+]= [Cr3+]=1.0 M; and Eo of Cr3+/Cr2+ = -0.41 V
%3D
Hints: 1. Search for # of e- involved in the reaction
2. Determine [H*] with pH value given I
3. Calculate the cell potential Ecet with the Nerst equation
4. Use equation 1 to calculate AG energy
Transcribed Image Text:Calculate AG (at 298K) for the reaction: 2Cr2+ (aq) + 2H+ (aq) 2 2C13+ + H2 (g) (aq) At pH = 2.5 (pH =-log[H*]) and in which [Cr2+]= [Cr3+]=1.0 M; and Eo of Cr3+/Cr2+ = -0.41 V %3D Hints: 1. Search for # of e- involved in the reaction 2. Determine [H*] with pH value given I 3. Calculate the cell potential Ecet with the Nerst equation 4. Use equation 1 to calculate AG energy
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