CH3 а. (H3C)3C- SF3 H3C- CO2H CH b. H3C- H3C CO2H N-SF2 BF, H3C- (H3C)2HC ,Ni(OH);; К,СО,, DMSO -NH2 CF3

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 57AP: All attempts to isolate primary and secondary nitroso compounds result solely in the formation of...
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1. Give the major product for the following reactions.
CH3
а.
(H3C);C
SF3
H3C-
-CO2H
CH
b.
H3C-
H3C
CO2H
N-SF2 BF4
H3C
(H3C)2HC
, Ni(OH);; K2CO3, DMSO
-NH2
CF3
d.
Ru(phen),Cl2, CF;SO,CI, K,HPO4, MeCN,
H3CO-
Blue LED
HOl.
ICO2CH3
CI-
-S-F ,DBU, PHM
NTs
Ph
Transcribed Image Text:1. Give the major product for the following reactions. CH3 а. (H3C);C SF3 H3C- -CO2H CH b. H3C- H3C CO2H N-SF2 BF4 H3C (H3C)2HC , Ni(OH);; K2CO3, DMSO -NH2 CF3 d. Ru(phen),Cl2, CF;SO,CI, K,HPO4, MeCN, H3CO- Blue LED HOl. ICO2CH3 CI- -S-F ,DBU, PHM NTs Ph
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