Classify each of these reactions. Pb(NO,),(aq) + 2 KCI(aq) PbCl, (s) +2 KNO,(aq) - CH, +30,(g) –2C0,(g) + 2H,0(1) | 2 AGNO, (aq)+Zn(s) Zn(NO,),(aq) +2 Ag(s) - 2 KOH(aq) + H, SO, (aq) K,SO, (aq) + 2H,O(1) - Answer Bank precipitation redox acid-base neutralization
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- The Behavior of Substances in Water Part 1: a Ammonia, NH3, is a weak electrolyte. It forms ions in solution by reacting with water molecules to form the ammonium ion and hydroxide ion. Write the balanced chemical reaction for this process, including state symbols. b From everyday experience you are probably aware that table sugar (sucrose), C12H22O11, is soluble in water. When sucrose dissolves in water, it doesnt form ions through any reaction with water. It just dissolves without forming ions, so it is a nonelectrolyte. Write the chemical equation for the dissolving of sucrose in water. c Both NH3 and C12H22O11 are soluble molecular compounds, yet they behave differently in aqueous solution. Briefly explain why one is a weak electrolyte and the other is a nonelectrolyte. d Hydrochloric acid, HCl, is a molecular compound that is a strong electrolyte. Write the chemical reaction of HCl with water. e Compare the ammonia reaction with that of hydrochloric acid. Why are both of these substances considered electrolytes? f Explain why HCl is a strong electrolyte and ammonia is a weak electrolyte. g Classify each of the following substances as either ionic or molecular. KCl NH3 CO2 MgBr2 HCl Ca(OH)2 PbS HC2H3O2 h For those compounds above that you classified as ionic, use the solubility rules to determine which are soluble. i The majority of ionic substances are solids at room temperature. Describe what you would observe if you placed a soluble ionic compound and an insoluble ionic compound in separate beakers of water. j Write the chemical equation(s), including state symbols, for what happens when each soluble ionic compound that you identified above is placed in water. Are these substances reacting with water when they are added to water? k How would you classify the soluble ionic compounds: strong electrolyte, weak electrolyte, or nonelectrolyte? Explain your answer. l Sodium chloride, NaCl, is a strong electrolyte, as is hydroiodic acid, HI. Write the chemical equations for what happens when these substances are added to water. m Are NaCl and HI strong electrolytes because they have similar behavior in aqueous solution? If not, describe, using words and equations, the different chemical process that takes place in each case. Part 2: You have two hypothetical molecular compounds, AX and AY. AX is a strong electrolyte and AY is a weak electrolyte. The compounds undergo the following chemical reactions when added to water. AX(aq)+H2O(l)AH2O+(aq)+X(aq)AY(aq)+H2O(l)AH2O+(aq)+Y(aq) a Explain how the relative amounts of AX(aq) and AY(aq) would compare if you had a beaker of water with AX and a beaker of water with AY. b How would the relative amounts of X(aq) and Y(aq) in the two beakers compare? Be sure to explain your answer.A common experiment to determine the relative reactivity of metallic elements is to place a pure sample of one metal into an aqueous solution of a compound of another metallic element. If the pure metal you are adding is more reactive than the metallic element in the compound, then the pure metal willreplacethe metallic element in the compound. For example. if you place a piece of pure zinc metal into a solution of copper(II) sulfate, the zinc will slowly dissolve to produce zinc sulfate solution, and the copper(II) ion of the copper(II) sulfate will be converted to metallic copper. Write the unbalanced equation for this process.n general terms, what are the spectator ions in a precipitation reaction? Why are the spectator ions not included in writing the net ionic equation for a precipitation reaction? Does this mean that the spectator ions do not have to be present in the solution?
- A student mixes four reagents together, thinking that the solutions will neutralize each other. The solutions mixed together are 50.0 mL of 0.100M hydrochloric acid, 100.0 mL of 0.200 M of nitric acid, 500.0 mL of 0.0100 M calcium hydroxide, and 200.0 mL of 0.100 M rubidium hydroxide. Did the acids and bases exactly neutralize each other? If not, calculate the concentration of excess H+ or OH ions left in solution.One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?Consider the following generic equation: H+(aq)+ B(aq)HB(aq)For which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) nitric acid and calcium hydroxide (b) hydrochloric acid and CH3NH2 (c) hydrobromic acid and aqueous ammonia (d) perchloric acid and barium hydroxide (e) sodium hydroxide and nitrous acid
- Many plants are poisonous because their stems and leaves contain oxalic acid H2C2O4, or sodium oxalate, Na2C2O4. When ingested, these substances cause swelling of the respiratory tract and suffocation. A standard analysis for determining the amount of oxalate ion, C2O42 in a sample is to precipitate this species as calcium oxalate, which is insoluble in water. Write die net ionic equation for the reaction between sodium oxalate and calcium chloride. CaCl2, in aqueous solution.Citric acid, which can be obtained from lemon juice, has the molecular formula C6H8O7. A 0.250-g sample of citric acid dissolved in 25.0 mL of water requires 37.2 mL of 0.105 M NaOH for complete neutralization. What number of acidic hydrogens per molecule does citric acid have?Consider molecular, complete ionic, and net ionic equations. (a) What is the difference between these types of equations? (b) In what circumstance would the complete and net ionic equations for a reaction be identical?
- Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?xplain to your friend what chemists mean by a precipitation reaction. What is the driving force in a precipitation reaction? Using the information provided about solubility in these chapters, write balanced molecular and net ionic equations for five examples of precipitation reactions.A noncarbonated soft drink contains an unknown amount of citric acid, H3C6H5O7. lf 100. mL of the soft drink requires 33.51 mL of 0.0102 M NaOH to neutralize the citric add completely, what mass of citric acid does the soft drink contain per 100. mL? The reaction of citric acid and NaOH is H3C6H5O7(aq) + 3 NaOH(aq) Na3C6H5O7(aq) + 3 H2O()