Consider the following reaction schemes involving the reaction of an imine with an organolithium compound [RLi]n 1. C A 2. H,0 в D THE -90°C THE -78°C HO, 2 E THE -78"C 1. C 2. H20 THE -78°C G HO,

Organic Chemistry: A Guided Inquiry
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ISBN:9780618974122
Author:Andrei Straumanis
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Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 19CTQ
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Consider the following reaction schemes involving the reaction of an imine with an organolithium
compound [RLi]n
1. C
A
2. H,0
B
D
THE
-90°C
THE
-78°C
HO,
2 E
Br
THE
-78°C
1. C
2. Hо
THE
-78°C
G
HO.
Transcribed Image Text:Consider the following reaction schemes involving the reaction of an imine with an organolithium compound [RLi]n 1. C A 2. H,0 B D THE -90°C THE -78°C HO, 2 E Br THE -78°C 1. C 2. Hо THE -78°C G HO.
(b) Based on your choice of A and E draw the structures of the two lithiated intermediates B and F:
Structure of (B)
Structure of (F) (Take care to define R here)
Transcribed Image Text:(b) Based on your choice of A and E draw the structures of the two lithiated intermediates B and F: Structure of (B) Structure of (F) (Take care to define R here)
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