Discuss every labelled peak in the IR spectrum and identify functional group using the provided table 15.2 (Wavenumbers).

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter29: Mass Spectrometry
Section: Chapter Questions
Problem 29.5QAP
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  1. Discuss every labelled peak in the IR spectrum and identify functional group using the provided table 15.2 (Wavenumbers).
TABLE 15.2 IMPORTANT SIGNALS IN IR SPECTROSCOPY
FREQUENCY (cm 1)
FREQUENCY (cm)
STRUCTURAL UNIT
STRUCTURAL UNIT
USEFUL SIGNALS IN THE DIAGNOSTIC REGION
Single Bonds (X-H)
Double Bonds
O-H
3200-3600
C=0
1750-1850
0-H
2200-3600
RO
C=O
1700-1750
N-H
3350-3500
но
EC-H
~3300
C=O
1700-1750
R
3000-3100
R
c=O
R
1680-1750
-C-H
2850-3000
H,N
C=O
1650-1700
R
C-H
2750-2850
C=C
1600-1700
Triple Bonds
CEC-
2100-2200
1450-1600
1650-2000
CEN
2200-2300
Transcribed Image Text:TABLE 15.2 IMPORTANT SIGNALS IN IR SPECTROSCOPY FREQUENCY (cm 1) FREQUENCY (cm) STRUCTURAL UNIT STRUCTURAL UNIT USEFUL SIGNALS IN THE DIAGNOSTIC REGION Single Bonds (X-H) Double Bonds O-H 3200-3600 C=0 1750-1850 0-H 2200-3600 RO C=O 1700-1750 N-H 3350-3500 но EC-H ~3300 C=O 1700-1750 R 3000-3100 R c=O R 1680-1750 -C-H 2850-3000 H,N C=O 1650-1700 R C-H 2750-2850 C=C 1600-1700 Triple Bonds CEC- 2100-2200 1450-1600 1650-2000 CEN 2200-2300
IR spectrum
100
Overtone of 1720
peak. (ignore)
50
2900
1720
4000
3000
2000
1500
1000
500
Wavenumber (cm)
Transmittance (%)
Transcribed Image Text:IR spectrum 100 Overtone of 1720 peak. (ignore) 50 2900 1720 4000 3000 2000 1500 1000 500 Wavenumber (cm) Transmittance (%)
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