Draw the possible structures of ICl4F and determine the best one using VSEPR model

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.95E: The mutual exclusion rule states that for certain molecules, vibrations that are IR-active are not...
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  1. Draw the possible structures of ICl4F and determine the best one using VSEPR model.
  2. Predict the point group of ICl4F giving the main symmetry elements.
  3. determine the reducible representations of fluoride (GF ) and chloride (GCl ) ions separately and total (Gtotal ) for ICl4
  4. determine the symmetry species of fluoride and chloride ions by reducing the matrix representations to irreducible representations.
  5. Assign the IR active vibrational modes.
  6. Draw the MO diagram of ICl4F . (Ignore the p-orbital interaction)
  7. Assign HOMO and LUMO

Determine the Magnetic behavior

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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,