Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.95E: The mutual exclusion rule states that for certain molecules, vibrations that are IR-active are not...
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- Draw the possible structures of ICl4F and determine the best one using VSEPR model.
- Predict the point group of ICl4F giving the main symmetry elements.
- determine the reducible representations of fluoride (GF ) and chloride (GCl ) ions separately and total (Gtotal ) for ICl4
- determine the symmetry species of fluoride and chloride ions by reducing the matrix representations to irreducible representations.
- Assign the IR active vibrational modes.
- Draw the MO diagram of ICl4F . (Ignore the p-orbital interaction)
- Assign HOMO and LUMO
Determine the Magnetic behavior
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