Mercury (II) chloride reacts with the oxalate ion according to the equation below: 2 H9C12(ag) + C2Oalag) 2 Clag) +2 CO2(9) + Hg,Cl2(s) The initial rate of the reaction was determined for several concentrations of reactants and table below has the data obtained. Experiment [HgCl2] (mol L-1) [C20,²] (mol L-1) Rate (mol L-1 s-1) 1 0.144 0.132 5.63 × 10-5 2 0.144 0.396 5.10 x 10¬4 0.072 0.396 2.51 x 10-4 4 0.288 0.132 1.13 x 10-4

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 39QRT
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Is the overall reaction likely to be an elementary step? Explain. 

Mercury (II) chloride reacts with the oxalate ion according to the equation below:
2 H9C12(ag) + C2Oalag)
2 Clag) +2 CO2(9) + Hg,Cl2(s)
The initial rate of the reaction was determined for several concentrations of reactants and table below has the data obtained.
Experiment [HgCl2] (mol L-1)
[C20,²] (mol L-1)
Rate (mol L-1 s-1)
1
0.144
0.132
5.63 × 10-5
2
0.144
0.396
5.10 x 10¬4
0.072
0.396
2.51 x 10-4
4
0.288
0.132
1.13 x 10-4
Transcribed Image Text:Mercury (II) chloride reacts with the oxalate ion according to the equation below: 2 H9C12(ag) + C2Oalag) 2 Clag) +2 CO2(9) + Hg,Cl2(s) The initial rate of the reaction was determined for several concentrations of reactants and table below has the data obtained. Experiment [HgCl2] (mol L-1) [C20,²] (mol L-1) Rate (mol L-1 s-1) 1 0.144 0.132 5.63 × 10-5 2 0.144 0.396 5.10 x 10¬4 0.072 0.396 2.51 x 10-4 4 0.288 0.132 1.13 x 10-4
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