NaBr catalyst about to be added to reaction miture но,(о) in acidic solution 2 Br (aq) + H,O,(aq) + 2 H* (aq) Brz(aq) + H,O,(aq) Br2(aq) +2 H2O(1) 2 Br (aq) + 2 H* (aq) + O2(8) brown colorless bubbles A Figure 14.21 Homogeneous catalysis. Effect of catalyst on the speed of hydrogen peroxide decomposition to water and coxygen gas.
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In Figure 14.21, we saw that Br - (aq) catalyzes the decomposition
of H2O2(aq) into H2O(l) and O2(g). Suppose that
some KBr(s) is added to an aqueous solution of hydrogen peroxide. Make a sketch of [Br - (aq)] versus time from
the addition of the solid to the end of the reaction.
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- The manganese(II)-catalyzed redox reaction between cerium(IV) and thallium(I) is thought to proceed by a three-step mechanism: Ce4+(aq) + Mn2+(aq) --> Ce3+(aq) + Mn3+(aq) (slow)Ce4+(aq) + Mn3+(aq) --> Ce3+(aq) + Mn4+(aq)Mn4+(aq) + Tl+(aq) --> Mn2+(aq) + Tl3+(aq) (a) If the first step of this mechanism is rate-determining (slow), choose the correct rate law for the overall process. Rate = k [Mn2+] [Mn3+] Rate = k [Ce4+]2 Rate = k [Ce4+] [Tl+] Rate = k [Mn2+] [Ce4+] Rate = k [Ce4+]2 [Tl+] Rate = k [Mn3+] [Tl+] (b) Choose the correct chemical equation for the overall process. Ce4+(aq) + Mn2+(aq) --> Ce3+(aq) + Mn3+(aq) Ce4+(aq) + Mn3+(aq) --> Ce3+(aq) + Mn4+(aq) 2 Ce4+(aq) + Tl+(aq) --> 2 Ce3+(aq) + Tl3+(aq) (c) Identify an intermediate in the reaction. Mn2+ Ce3+ Mn3+ Ce4+ (d) Identify the catalyst in the reaction. Mn2+ Mn3+ Ce3+ Ce4+ (e) Identify a reactant in the reaction. Ce3+ Ce4+ Mn2+ Mn3+ (f) Identify a product in the reaction. Mn3+ Mn2+ Ce4+…Carbonic anhydrase is one of the fastest enzymes known. If 10 µg of this enzyme catalyzes the conversion of 0.30 g of CO2 to bicarbonate in 1 minute at 37˚C. What is the Kcat value for this enzyme in min -1?A chemical engineering student is studying the effect of pH on the corrosion of iron. Ellie following data are collected: Corrosion Rate (mm/year) ph 0.03 13.00 0.06 12.00 0.16 11.00 0.22 10.00 0.25 9.00 0.25 8.00 0.25 7.00 0.25 6.00 0.25 5.00 0.27 4.00 0.37 3.00 0.38 2.80 0.63 2.80 1.00 2.80 Plot corrosion rate vs. pH. (HINT: Label the x axis with decreasing pH.) (a) How would you describe the dependence of corrosion on pH? (b) When the pH goes below 3, bubbles appear in the solution. What change takes place in the reduction half-reaction at low pH? (c) How do you explain the shape of the curve at the lowest pH? (Based on a graph in the Kirk-Otbmer Encyclopedia of Chemical Technology, 4th ed., vol 7. New York: John Wiley & Sons, p. 559.)
- If the concentration of Sn2+ ions in a solution of Sn(OH)2 was measured to be (1.24x10^-3), what is the Ksp value for Sn(OH)2?Reducing NO Emissions Adding NH3 to the stack gases at an electric power generating plant can reduceNOx emissions. This selective noncatalytic reduction (SNR) process depends on the reaction between NH3 (an odd-electron compound) and NO.$$4NH3(g)+6NO(g)5N2(g)+6H2O(g)The following kinetic data were collected at 1200 K. Experiment [NH3] (M) [NO] (M) Rate (M/s) 1 1.00x10-5 1.00x10-5 0.120 2 2.00x10-5 1.00x10-5 0.240 3 2.00x10-5 1.50x10-5 0.360 4 2.50x10-5 1.50x10-5 0.450 What is the rate-law expression for the reaction? Do not add multiplication symbols to your answer. $$Rate=Reaction of interest : S2O82-(aq) + 3I- (aq)→ 2SO42-(aq) + I3-(aq). rate= k[S2O82-]1[I-]1.
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- What is E2-26 meanWhich of the following are equivalent to 2,500 ppm Cu2+? (There may be more than one answer) MW: Cu (63.55) a) 2.5 ppb Cu2+ b) 2,500,000 ppb Cu c) 2.5 ppt Cu2+ d) 39.34 mM e) 0.03934 M f) 0.07868 N (in precipitation reaction) g) 0.07868 N (in redox into Cu+)A 0.326 8-g unknown containing lead lactate, Pb(CH3CHOHCO2)2 (FM 385.3), plus inert material was electrolyzed to produce 0.111 1 g of PbO2 (FM 239.2). Was the PbO2 deposited at the anode or at the cathode? Find the weight percent of lead lactate in the unknown.