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Fundamentals Of Analytical Chemistry

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter30: Kinetic Methods Of Analysis

Section: Chapter Questions

Problem 30.9QAP

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P17D.4 The second- order rate constants for the reaction of oxygen atoms with
aromatic hydrocarbons have been measured (R. Atkinson and J.N. Pitts, J.
Phys. Chem. 79, 295 (1975)). In the reaction with benzene the rate constants
are 1.44 x 10 dm3 mol s at 300.3 K, 3.03 x 10 dm mol s at 341.2 K, and
6.9 x 10 dm3 mols at 392.2K. Find the frequency factor and activation
energy of the reaction.

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