Provide crystal field splitting diagrams that clearly show orbital names, orbitalelectron population, and 10Dq (i.e. ∆o) for the following complexes. Use your knowledge of the spectrochemical series and crystal field theory to determine LS vs. HS e. [Ni(CO)4] (hint: In this complex the 4s electrons of the uncomplexedmetal move down to the 3d orbitals when the complex forms. UseValence Bond theory to determine the geometry of this complex, thenapply CFT)f. [Fe(CI)4]g. [Fe(OH)6]- (hint: this complex has a spin quantum number, S = 5/2)h. [Co(ETOH)4]* (where EtOH = ethanol, CH:CH2OH)

CFSE is used to determine the stability of the complex

Answered: Provide crystal field splitting…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 73QRT

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Provide crystal field splitting diagrams that clearly show orbital names, orbitalelectron population, and 10Dq (i.e. ∆o) for the following complexes. Use your knowledge of the spectrochemical series and crystal field theory to determine LS vs. HS

e. [Ni(CO)4] (hint: In this complex the 4s electrons of the uncomplexed
metal move down to the 3d orbitals when the complex forms. Use
Valence Bond theory to determine the geometry of this complex, then
apply CFT)
f. [Fe(CI)4]
g. [Fe(OH)6]- (hint: this complex has a spin quantum number, S = 5/2)
h. [Co(ETOH)4]* (where EtOH = ethanol, CH:CH2OH)

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