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Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni CN NC CN equatorial For the square base pyramidal complex [Ni(CN)s]³ shown above, of Cav point group, consider the rotation axes: 2C4 and C2. If the axial CN ligand was substituted by CO, forming [Ni(CO)(CN).]?, maintaining the square pyramidal geometry, which symmetry elements would а. be retained: i. Both C4 and C2. ii. Only the C2. iii. Only the C4. iv. None of the above b. Looking at the symmetry planes: 20v, 20a; Wwhat symmetry elements would be retained if the Co substitution would occur on an equatorial CN ligand (forming again [Ni(CO)(CN).]?) instead? The dihedral planes in this case is the mirror plane that bisects the square planar bonds. i. All gv 2.

Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni CN NC CN equatorial For the square base pyramidal complex [Ni(CN)s]³ shown above, of Cav point group, consider the rotation axes: 2C4 and C2. If the axial CN ligand was substituted by CO, forming [Ni(CO)(CN).]?, maintaining the square pyramidal geometry, which symmetry elements would а. be retained: i. Both C4 and C2. ii. Only the C2. iii. Only the C4. iv. None of the above b. Looking at the symmetry planes: 20v, 20a; Wwhat symmetry elements would be retained if the Co substitution would occur on an equatorial CN ligand (forming again [Ni(CO)(CN).]?) instead? The dihedral planes in this case is the mirror plane that bisects the square planar bonds. i. All gv 2.

Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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2. Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni CN CN equatorial NC а. For the square base pyramidal complex [Ni(CN)s]3 shown above, of Cav point group, consider the rotation axes: 2C4 and C2. If the axial CN ligand was substituted by CO, forming [Ni(CO)(CN)4]?, maintaining the square pyramidal geometry, which symmetry elements would be retained: i. Both C4 and C2. ii. Only the C2. iii. Only the C4. iv. None of the above b. Looking at the symmetry planes: 20v, 20d; what symmetry elements would be retained if the Co substitution would occur on an equatorial CN ligand (forming again [Ni(CO)(CN)4]?) instead? The dihedral planes in this case is the mirror plane that bisects the square planar bonds. i. All ov ii. All od iii. At least 1 od iv. At least 1 oy
Transcribed Image Text:2. Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni CN CN equatorial NC а. For the square base pyramidal complex [Ni(CN)s]3 shown above, of Cav point group, consider the rotation axes: 2C4 and C2. If the axial CN ligand was substituted by CO, forming [Ni(CO)(CN)4]?, maintaining the square pyramidal geometry, which symmetry elements would be retained: i. Both C4 and C2. ii. Only the C2. iii. Only the C4. iv. None of the above b. Looking at the symmetry planes: 20v, 20d; what symmetry elements would be retained if the Co substitution would occur on an equatorial CN ligand (forming again [Ni(CO)(CN)4]?) instead? The dihedral planes in this case is the mirror plane that bisects the square planar bonds. i. All ov ii. All od iii. At least 1 od iv. At least 1 oy
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