The absorbance values observed during the determination of the complex stoichiometry with the Job method using the spectroscopic method were plotted and the following correct equations were obtained. According to this, what is the n value of the compound formed by Fe + 3 and SCN- ions? 1. Line equation: y = 2.6188x + 0.1608 2. Line equation: y = -2.5963x + 2.7203

The absorbance values observed during the determination of the complex stoichiometry with the Job method using the spectroscopic method were plotted and the following correct equations were obtained. According to this, what is the n value of the compound formed by Fe + 3 and SCN- ions? 1. Line equation: y = 2.6188x + 0.1608 2. Line equation: y = -2.5963x + 2.7203

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.5QAP

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The absorbance values observed during the determination of the complex stoichiometry with the Job method using the spectroscopic method were plotted and the following correct equations were obtained. What is the n value of the compound formed by Fe + 3 and SCN- ions? 1. Line equation: y = 2.6188x + 0.16082. Line equation: y = -2.5963x + 2.7203
The absorbance values observed during the determination of the complex stoichiometry with the Job method using the spectroscopic method were plotted and the following correct equations were obtained. What is the n value of the compound formed by Fe + 3 and SCN- ions? 1. Line equation: y = 2.6188x + 0.1608 2. Line equation: y = -2.5963x + 2.7203 a) 1 b) 3 c) 0.5 d) 2 e) 5
A dual beam UV-visible spectroscopy was used to determine the levels of Fe(II) in the run-off water of a local mine using the ferrozine assay (i) During a check of the instrument a step-like feature at 360 nm was observed in spectrum of the standard. Suggest what may give rise to this with reference to the instrument configuration and comment on how it may be remedied. (ii) The molar absorptivity of the [Fe(Ferrozine)3]2+ complex is 27900 cm−1 M−1 at 562 nm in aqueous solution (pH 5.5). If the EU maximum contaminant level for Fe is 200 ug /L and the contract required detection limit is 100 ug/L, comment on the suitability of the assay for the detection of iron. (iii) Determine the sample range, in terms of concentration and ppm, of Fe(II) that can be confidently analysed by UV-visible spectroscopy using a 1 cm cuvette. Explain with reference to an appropriate equation and solution phenomena, the origin of the limitations that define this range
The molar absorptivity (ε) of the FeSCN2+ complex ion is 4700 M-1 · cm-1 at a wavelength of 450 nm. Using a 1-cm sample tube, you measure the absorbance as (2.0x10-1). What is the concentration of FeSCN2+?
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Furosemide (MM: 330.7 g/mol) is a diuretic derived from anthranilic acid, this diuretic is used in the treatment of kidney disease, hypertension, liver cirrhosis, and others. Furosemide in alkaline dissolution has an absorption spectrum with a maximum peak centered at 271 nm. The analysis of a furosemide tablet was performed by dissolving its content in a 0.1 mol L-1 NaOH solution and this dissolution completed for a volume of 100 mL, with 1.0 mL of this dissolution was transferred to 50.0 ml and made up to volume with the same solvent. It is dissolution has an absorbance value of 0.475 to 271 nm, with a 1.0 cuvette cm of optical path. At this wavelength, a series of dissolutions of a Standard substance of this drug has the following absorbance measurements (1.0 cm bucket): a) Demonstrate whether the experimental data are in accordance with Bee's law (b) Determine absorptivity and molar absorptivity (c) Determine the amount of drug in the tablet in mg and in ppm (d) Determine the…
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Predict whether the following complexes would show Jahn-Teller distortion: Ammonium pentachlorooxidochromate(V), meff = 1.8 mB Potassium hexaiodidomanganate(IV), meff = 3.8 mB Potassium hexachoridocuprate(II), meff = 1.8 mB Hexaaquamanganese(II) chloride, meff = 6.0 mB
The molar absorptivity (ε) of the FeSCN2+ complex ion is 4700 M-1 · cm-1 at a wavelength of 450 nm. Using a 1-cm sample tube, you measure the absorbance as (2.0x10-1). What is the concentration of FeSCN2+? What is your answer? _____________x10^_____