Using additive rule calculate the total ionic polarizability and ionic polarizability per unit volume for Sta. Ce.TiO, with x= 0.0 and 0.1. The polarizability (a Å') of Sr", Ce", Ti“ and O² are listed below. For x = 0.0 and 0.1 the unit cell volume is 59.6 Å'and 59.0 ų respectively.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter21: Structure And Bonding In Solids
Section: Chapter Questions
Problem 42P
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Using additive rule calculate the total ionic polarizability and ionic polarizability per unit volume for
Sra. Ce.TiO; with x = 0.0 and 0.1. The polarizability (a ų) of Sr", Ce", Ti“ and O² are listed below. For x
= 0.0 and 0.1 the unit cell volume is 59.6 ų and 59.0 ų respectively.
LI
Be
Ne
1.20 0.19
0.05
2.01 1.82
No
Mg
Al
P
1.80 1.32
0.79 0.87
1.22
Ge
Ca
Sc
TI
IV
2.93 2.92 1.45 2.64 2.29 1.65 1.23
Cr
Mn
Fe
II. 1 2.23 i
NI
Cu
12.04
2.11
K
V
Co
Zn
Se
As
1.50 1.63
Go
Br
3.83 3.16 2.81
1.72
Sr
5.29 4.24 3.81 3.25 3.97
Rb
Zr
Nb
Mo
Tc
Ag
Cd
In
Sn
Te
IV
4.27 5.23
BI
6.12
Sb
3.40 2.62 2.83
Cs
Ba
La
Hf
Ta
Re
Au
Hg
TI
Pb
7.43 6.40 6.07
4.73
7.28 6.58
Ce
Nd
Sm
Yb
Pr
16.15
IV3.94
Pm
Dy
4.74 4.83 4.37 4.25 4.07 3.97 3.81 3.02 3.50 3.64
Eu
Gd
Tb
Но
Er
Tm
Lu
5.32 5.01
4.53
Th
Pa
4.92
IV
4.45
FIG. 1. Table of ion dielectric polarizabilities given in Å'.
o Jn
Transcribed Image Text:Using additive rule calculate the total ionic polarizability and ionic polarizability per unit volume for Sra. Ce.TiO; with x = 0.0 and 0.1. The polarizability (a ų) of Sr", Ce", Ti“ and O² are listed below. For x = 0.0 and 0.1 the unit cell volume is 59.6 ų and 59.0 ų respectively. LI Be Ne 1.20 0.19 0.05 2.01 1.82 No Mg Al P 1.80 1.32 0.79 0.87 1.22 Ge Ca Sc TI IV 2.93 2.92 1.45 2.64 2.29 1.65 1.23 Cr Mn Fe II. 1 2.23 i NI Cu 12.04 2.11 K V Co Zn Se As 1.50 1.63 Go Br 3.83 3.16 2.81 1.72 Sr 5.29 4.24 3.81 3.25 3.97 Rb Zr Nb Mo Tc Ag Cd In Sn Te IV 4.27 5.23 BI 6.12 Sb 3.40 2.62 2.83 Cs Ba La Hf Ta Re Au Hg TI Pb 7.43 6.40 6.07 4.73 7.28 6.58 Ce Nd Sm Yb Pr 16.15 IV3.94 Pm Dy 4.74 4.83 4.37 4.25 4.07 3.97 3.81 3.02 3.50 3.64 Eu Gd Tb Но Er Tm Lu 5.32 5.01 4.53 Th Pa 4.92 IV 4.45 FIG. 1. Table of ion dielectric polarizabilities given in Å'. o Jn
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