Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model.

Biology: The Unity and Diversity of Life (MindTap Course List)
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Chapter2: Life's Chemical Basis
Section: Chapter Questions
Problem 4SQ
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Some different views of an octahedral symmetry metal complex
1
1
3
6.
2 1
4
View down a C, axis
View down a C, axis
View down a C,axis
E 8C, 6C, 6C, 3C, i
On
i 6S,
85, 30, 604
A1g
1
1
1
1
1
1
1
1
1
-1
-1
1
Az8
1
1
-1
-1
1
Eg
2
z², x² - y?
-1
0.
-1
-1
-1
1
-1
-1
(xy, xz, yz)
T2g
-1
-1
1
1
-1
-1
A1u
1
1
1
-1
-1
-1
-1
A2u
1
-1
-1
1
-1
-1
-1
1
E
-2
1
-2
-1
2
(x, y, z)
-1
1
-1
-3
-1
1
3
T2u
1
-1
-1
-3
1
-1
The octahedral character table above may be useful for the following questions.
1.
1.
3.
3.
1.
2.
3.
1.
2)
Transcribed Image Text:Some different views of an octahedral symmetry metal complex 1 1 3 6. 2 1 4 View down a C, axis View down a C, axis View down a C,axis E 8C, 6C, 6C, 3C, i On i 6S, 85, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Az8 1 1 -1 -1 1 Eg 2 z², x² - y? -1 0. -1 -1 -1 1 -1 -1 (xy, xz, yz) T2g -1 -1 1 1 -1 -1 A1u 1 1 1 -1 -1 -1 -1 A2u 1 -1 -1 1 -1 -1 -1 1 E -2 1 -2 -1 2 (x, y, z) -1 1 -1 -3 -1 1 3 T2u 1 -1 -1 -3 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 3. 3. 1. 2. 3. 1. 2)
Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta
within the Lewis acid/base model.
(The Generic Octahedral Metal Complex information above may be useful in doing this.)
Eg symmetry SALC (ligand = NH3)
%3D
V [ ChoosN
Pi Base
Sigma Base
Eg symmetry SALC (ligand = 1-)
Pi Acid
Sigma Acid
T2g symmetry SALC (ligand = 1-)
[ Choose ]
T2g symmetry SALC (ligand = CO)
[ Choose ]
Transcribed Image Text:Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) %3D V [ ChoosN Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) [ Choose ]
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