Virial state equation of real gases is expressed as Z = (PV / nRT) = 1 + (nB / V) + (n2C / V2). Derive the second virial coefficient B and the relation expressing the 3. virial coefficient C depending on the constants a and b in the van der Waals equation.
Virial state equation of real gases is expressed as Z = (PV / nRT) = 1 + (nB / V) + (n2C / V2). Derive the second virial coefficient B and the relation expressing the 3. virial coefficient C depending on the constants a and b in the van der Waals equation.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.48E: Use the approximation 1 x-1 1 x x2 to determine an expression for the virial coefficient C in...
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Virial state equation of real gases is expressed as Z = (PV / nRT) = 1 + (nB / V) + (n2C / V2). Derive the second virial coefficient B and the relation expressing the 3. virial coefficient C depending on the constants a and b in the van der Waals equation.
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