When 50.0 g of oxygen gas (MW = 32.0) react excess diborane gas (B2H6; MW =D27.6), the enthalpy change is -1120 kJ. What is the enthalpy change for the reaction B2H6lg) + 3 O2lg) → B2O3(s) + 3 H20(1) AH° = ? O-2150 kJ -239 kJ -1120 kJ -717kJ Next ► « Previous
Q: AH, = -393.5 kJ AH, = -283.0 kJ (1) C(s) + O2(g) CO2(8) CO2(8) (2) 37 - CO(g) + 02) (3) C(s) +O2g)…
A: We use Hess's law to calculate the enthalpy of the reaction.
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Q: How do you do E4b?
A: Given reactions are :
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- When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?Peanuts and peanut oil are organic materials and bum in air. How many burning peanuts does it take to provide the energy to boil a cup of water (250 mL of water)? To solve this problem, we assume each peanut, with an average mass of 0.73 g, is 49% peanut oil and 21% starch; the remainder is noncombustible We further assume peanut oil is palmitic acid, C16H32O2, with an enthalpy of formation of 848.4 kJ/mol. Starch is a long chain of C6H10O5 units, each unit having an enthalpy of formation of 960 kJ.Magnesium sulfate is often used in first-aid hot packs, giving off heat when dissolved in water. A coffee-cup calorimeter at 25C contains 15.0 mL of water at 25C. A 2.00-g sample of MgSO4 is dissolved in the water and 1.51 kJ of heat are evolved. (You can make the following assumptions about the solution: volume=15.0 mL, density=1.00 g/mL, specific heat=4.18J/gC.) (a) Write a balanced equation for the solution process. (b) Is the process exothermic? (c) What is qH2O? (d) What is the final temperature of the solution? (e) What are the initial and final temperatures in F?
- The enthalpy of vaporization for water is 40.65 kJ mol-1. As a design engineer for a project in a desert climate, you are exploring the option of using evaporative cooling. (a) If the air has an average volumetric heat capacity of 0.00130 J cm-3 K-1, what is the minimum mass of water that would need to evaporate in order to cool a 5 m? 5 m room with a 3 m ceiling by 5°F using this method? (b) Is this a spontaneous or nonspontaneous process?In the 1880s, Frederick Trouton noted that the enthalpy of vaporization of 1 mol pure liquid is approximately 88 times the boiling point, Tb, of the liquid on the Kelvin scale. This relationship is called Troutons rule and is represented by the thermochemical equation liquid gas H = 88 Tb, joules Combined with an empirical formula from chemical analysis, Troutons rule can be used to find the molecular formula of a compound, as illustrated here. A compound that contains only carbon and hydrogen is 85.6% C and 14.4% H. Its enthalpy of vaporization is 389 J/g, and it boils at a temperature of 322 K. (a) What is the empirical formula of this compound? (b) Use Troutons rule to calculate the approximate enthalpy or vaporization or one mole of the compound. Combine the enthalpy of vaporization per mole with that same quantity per gram to obtain an approximate molar mass of the compound. (c) Use the results of parts (a) and (b) to find the molecular formula of this compound. Remember that the molecular mass must be exactly a whole-number multiple of the empirical formula mass, so considerable rounding may be needed.In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both solutions were originally at 24.6C. After the reaction, the final temperature is 31.3C. Assuming that all the solutions have a density of 1.0 g/cm3 and a specific heat capacity of 4.18 J/Cg, calculate the enthalpy change for the neutralization of HCl by NaOH. Assume that no heat is lost to the surroundings or to the calorimeter.
- The formulas give the enthalpy when Coal and Methane react with oxygen:C+O2->CO2+394 kJ/mol, 12 gram C gives 44 gram of CO2+394 kJCH4+ O2->CO2+2H2O+891 kJ/mol, 16 gram CH4gives 44 gram of CO2+891kJ 1-Calculate the heating value of Coal and Methane in MJ/kg and in kWh/kg.Calculate the lower heating value for Methane. 2-Calculate the amount of CO2 which is produced per kWh for Coal and Methanea) What is the standard enthalpy of reaction per mole of either HCl or NaOH when 50.00 cm3 of 0.1 moldm-3 of hydrochloric acid (HCl) and 50.00 cm3 of 0.1 moldm-3 of sodium hydroxide (NaOH) are mixed? According to your simulation, the temperature rose by 0.68 oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1) b) What is the standard enthalpy of reaction per mole of KOH when 50.00 cm3 of 1.0 moldm-3 of Nitric Acid (HNO3) and 50.00 cm3 of 1.0 moldm-3 of Potassium Hydroxide (KOH) are mixed? According to your simulation, the temperature rose by __6.81__ oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1)a) What is the standard enthalpy of reaction per mole of either HCl or NaOH when 50.00 cm3 of 0.1 moldm-3 of hydrochloric acid (HCl) and 50.00 cm3 of 0.1 moldm-3 of sodium hydroxide (NaOH) are mixed? According to your simulation, the temperature rose by 0.68 oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1) Show your working below:
- At constant pressure and 25°C, what is ΔH° for the following reaction2C2H6(g) + 7O2(g) → 4CO2(g) + H2O(l)if the complete consumption of 38.2 g of C2H6 liberates 1981 kJ of heat energy?a. 3120 kJb. 1560 kJc. 5030 kJd. 2510 kJe. 784.05 kJWhat is the standard enthalpy of reaction per mole of either HCl or NaOH when 50.00 cm3 of 0.1 moldm-3 of hydrochloric acid (HCl) and 50.00 cm3 of 0.1 moldm-3 of sodium hydroxide (NaOH) are mixed? According to your simulation, the temperature rose by ___0.68__ oC. (Density of water = 1gcm-3, Specific heat capacity of water = 4.18 J g-1 oC-1) Show your working below: HCl (aq) + NaOH(aq) à NaCl(aq) + H2O(l)A coffee-cup (constant pressure) calorimeter is used to carry out the following reaction in 68.5 mL water (where X is a hypothetical metal): X + 2 HCI ---> XCI2 + H2 In this process, the water temperature rose from 25.0 °C to 33.3 °C. If 0.00629 mol of "X" was consumed during the reaction, what is ?rH of this reaction in kJ mol^-1with respect to "X"? The specific heat of water is 4.184 J g-¹ °C-¹